Complex formation equilibria between 1-hydroxy-7-sulpho-2-naphthoic or 1-hydroxy-4,7-disulpho-2-naphthoic acid and iron(III) in 0.1M NaClO4 medium

The equilibria for formation of iron(III) complexes with 1-hydroxy-7-sulpho-2-naphthoic and 1-hydroxy-4,7-disulpho-2-naphthoic acids in aqueous 0.1M sodium perchlorate medium at 25 degrees have been studied by spectrophotometric and potentiometric methods. The data are well described in terms of a series of stepwise complexes, FeL((3-rn)+)(r) in both systems (L(n-) denotes the unprotonated ligand anion).     

On oscillatory third order difference equations

In this paper, sufficient conditions have been obtained for oscillation/nonoscillation of a class of homogeneous/nonhomogeneous linear difference equations of third order.     

Oscillation of Forced Nonlinear Neutral Delay Difference Equations of First Order

Necessary and sufficient conditions are obtained for every solution of

On oscillation and asymptotic behaviour of solutions of forced first order neutral differential equations

In this paper, sufficient conditions have been obtained under which every solution of

OSCILLATORY AND ASYMPTOTIC BEHMIOUR OF A CLASS OF NONLINEAR DIFFERENTIALEQUATIONS OF THIRD ORDER

1IntroductionInthispaperwedealwithoscillatoryandnonoscillatorybehaviourofsolutionsofnonlinearthirdorderdifferentialequationsoftheformwherea,b,cEC([er,co),R),rrER,fEC(R,R)suchthatac2P>0fory/0and7>0isaquotientofoddintegers.From"Theoryofequations"tsee[1],itfollowsthattheequationwithconstantcoefficientsMoreover,allnonoscillatorysolutionsof(1.3)tendtozeroifandonlyifequatioll(l.3)hasanoscillatorysolution.Theseobservationsarefoundtobetruetoalargeextentformoregeneralequationsoftheformwherealb,cE…     

Liapunov-type inequality for delay-differential equations of third order

A Liapunov-type inequality for a class of third order delay-differential equations is derived.     

On the Behaviour of Solutions of a Class of Third Order Difference Equations

In this paper, the structure of the solution space of y n +3 + ry n +2 + qy n +1 + py n =0, n S 0, is studied, keeping oscillatory/nonoscillatory behaviour of solutions of the equation in view, where p , q and r are constants. Some of these results are generalized partially to hold for y n +3 + r n y n +2 + q n y n +1 + p n y n =0, n S 0, where { p n }, { q n } and { r n } are sequences of real numbers.     

Mechanochemical metathesis synthesis and characterization of nano-structured MnV2O6·xH2O (x=2, 4)

A solid-state metathesis approach for the synthesis of hydrated MnV₂O₆·xH₂O (x=2, 4) materials driven by mechanochemical activation energy has been demonstrated. The metathesis pathway of forming the desired product is confirmed by the presence of high lattice energy by-product such as NaCl. The structural, optical, and chemical properties of the synthesized materials are examined by powder X-ray diffraction, X-ray photoelectron spectroscopy, thermo gravimetric analysis, scanning electron microscopy, transmission electron microscopy, and diffused reflectance measurements in the UV–vis range. The valence state of Mn and V was determined to be +2 and +5, respectively, for the title compounds and the bandgap values determined showed these materials are likely to be semiconductors.     

Synthesis of the mixed acetal segment of S-glyceroplasmalopsychosine

In this report the concept of converting carbohydrate to non-carbohydrate asymmetric molecules has been successfully exploited. The mixed acetal segment of glyceroplasmalopsychosine, a novel glycolipid, has been synthesized in a stereospecific manner using two simple sugar units. The glycosidation reaction between these two monosaccharides ensured the correct acetal stereocenter of the target molecule. Either olefin metathesis or heterogeneous Wittig reactions were used for constructing the long aliphatic chain of glyceroplasmalopsychosine.     

Synthesis of fluorescent probes based on stilbenes and diphenylacetylenes targeting β-amyloid plaques

Three fluorescent probes were synthesized aiming for optical imaging to detect amyloid plaques present in the patients with Alzheimer’s disease (AD). These compounds were prepared via Sonogashira coupling of a well-defined fluorophore (4-bora-3a,4a-diaza-s-indacene, BODIPY) with the pharmacophore possessing either a stilbene or a diphenylacetylene moiety. Different polyethylene glycol chain lengths were used as linkers between the fluorophore and the pharmacophore to adjust the lipophilicity of these probes. These compounds exhibit strong fluorescence emission between 665 and 680 nm and have very high extinction coefficients comparable to the parent fluorophore, BODIPY dye.