ICP-OES分析低钙粉煤灰在NaOH溶液中离子浸出规律

低钙粉煤灰潜在的火山灰活性释放缓慢限制了其大规模利用,通过碱激发提高粉煤灰中Si4+,Al3+和Ca2+等离子浸出率对于加快低钙粉煤灰活性释放具有积极作用。采用电感耦合等离子体发射光谱、傅里叶变换红外光谱、X射线衍射和扫描电子显微镜分别测试和分析了5种浓度NaOH溶液对低钙粉煤灰激发过程中Si4+,Al3+和Ca2+的浸出规律、化学基团变化、水化产物生成及微观形貌演化。结果表明：碱激发作用显著提高了低钙粉煤灰中Si4+,Al3+和Ca2+浸出率,三种离子浸出率大小为：Si4+＞Al3+＞Ca2+,其中Si4+和Al3+浸出率随NaOH浓度增加而增加,随浸出时间延长呈对数规律升高;Ca2+由于在NaOH溶液中生成Ca(OH)₂沉淀,其浸出率大小表现为在水中高,在NaOH溶液中低。红外光谱清晰地表征出低钙粉煤灰受碱激发作用后化学基团在指纹区(波数1 300 cm-1以下)的变化,且随碱激发时间的延长和碱浓度的增加变化愈加明显。水化产物和微观形貌的结果显示出粉煤灰颗粒表面受到碱侵蚀发生解聚,在OH-催化下,硅铝单体分子重新排列形成硅酸盐和铝酸盐低聚络合物,通过亲核取代反应形成铝硅酸盐的低聚态溶胶,并进一步与碱金属阳离子通过配位键或静电键的作用缩聚形成水化凝胶类产物。采用ICP-OES测试粉煤灰中离子浸出率可作为评价粉煤灰火山灰活性的一种快速和准确的方法。     

A NUMERICAL EXPERIMENT FOR EFFECTS OF OZONE HEATING ON GENERAL CIRCULATION

An ozone conservation equation is added to the global nine-layer general circulationmodel to simulate the heating effect on the upper atmosphere due to the absorption of theultraviolet part of solar radiation by ozone and the changes of temperature, pressure andwind fields caused by ozone heating. The experiment shows that the heating rate by ozoneis much larger than that by other elements such as water vapour in stratosphere. Thetemperature distribution and strength of zonal wind in tropopause and above calculated withozone effect are much different from the results simulated without ozone. The ozone heatingaffects not only the zonal wind but also the meridional wind, so that the Walker Circulationand Hadley Cell are all changed accordingly. Besides, it can be seen that the influences ofozone on the meteorological elements are small in troposphere, while it still makes apparentlyresponse near the surface. Especially, it is much larger above the land than above the ocean.     

臭氧加热对大气环流影响的数值试验

本文在一个全球9层大气环流模式中,加入一个臭氧方程来模拟臭氧吸收太阳紫外辐射对高层大气的加热作用以及由此而引起的温、压、风场的变化。试验表明平流层臭氧加热率远大于其它要素,如水汽等引起的加热率。在考虑臭氧加热作用的情况下,计算出的对流层顶以上的温度分布和纬向风强度与不考虑臭氧作用的计算结果有明显差异。臭氧加热作用不仅影响纬向风,同时也影响经向风,因而使Walker环流和Hadley环流都发生相应的变化。试验还表明,臭氧层的存在对各气象要素场的影响在对流层中部已相当小,然而在近地面却还有明显的反应。特别是对陆地上影响比海洋上要强得多。