全文获取类型
收费全文 | 4533篇 |
免费 | 430篇 |
国内免费 | 914篇 |
专业分类
化学 | 2935篇 |
晶体学 | 83篇 |
力学 | 269篇 |
综合类 | 44篇 |
数学 | 967篇 |
物理学 | 1579篇 |
出版年
2024年 | 37篇 |
2023年 | 106篇 |
2022年 | 155篇 |
2021年 | 134篇 |
2020年 | 144篇 |
2019年 | 141篇 |
2018年 | 100篇 |
2017年 | 63篇 |
2016年 | 101篇 |
2015年 | 127篇 |
2014年 | 255篇 |
2013年 | 255篇 |
2012年 | 173篇 |
2011年 | 147篇 |
2010年 | 168篇 |
2009年 | 138篇 |
2008年 | 230篇 |
2007年 | 322篇 |
2006年 | 468篇 |
2005年 | 363篇 |
2004年 | 230篇 |
2003年 | 195篇 |
2002年 | 170篇 |
2001年 | 207篇 |
2000年 | 273篇 |
1999年 | 312篇 |
1998年 | 166篇 |
1997年 | 114篇 |
1996年 | 103篇 |
1995年 | 107篇 |
1994年 | 87篇 |
1993年 | 53篇 |
1992年 | 33篇 |
1991年 | 35篇 |
1990年 | 26篇 |
1989年 | 17篇 |
1988年 | 23篇 |
1987年 | 11篇 |
1986年 | 13篇 |
1985年 | 22篇 |
1984年 | 8篇 |
1983年 | 8篇 |
1982年 | 5篇 |
1981年 | 10篇 |
1980年 | 11篇 |
1979年 | 3篇 |
1974年 | 1篇 |
1966年 | 1篇 |
1960年 | 2篇 |
1957年 | 1篇 |
排序方式: 共有5877条查询结果,搜索用时 15 毫秒
1.
This minireview describes the strategies for synthesis of fiuorinated surfactants potentially nonbioaccumulable.Various strategies have been focused on(Ⅰ) reducing the length of the perfluorocarbon chain,(Ⅱ) introducing hetero atoms into the fluorocarbon chain,(Ⅲ) introducing branch(herein and after branch means the fluoro-carbon chain section is not straight).In most cases,the surface tensions versus the surfactant concentrations have been assessed.These above strategies led to various highly fiuorinated(perfluorinated or not perfluorinated) surfactants whose chemical changes enabled to obtain novel alternatives to perfluorooctanoic acid(PFOA) and perfluorooctane sulphonate(PFOS). 相似文献
2.
对石英音叉增强型光声光谱(QEPAS)系统中常用的石英音叉进行了有限元模态计算,获得石英音叉前6阶振型与模态频率,认知了第4阶对称摆动振型为有效振动,利用单因素法分析了石英音叉的音臂长度l1、音臂宽度w1、音臂厚度t、音臂切角θ、音臂圆孔直径d及音臂圆孔高度h对低阶有效共振频率(Fre)的影响,敏感度依次为: l1> w1>d>θ>t>h,考虑实际设计情形,筛选出了l1,w1,d与h四个石英音叉设计变量,采用Box-Behnken实验设计方案与RSM(response surface methodology)方法,以Fre为函数目标,建立l1,w1,d与h的二次回归响应面模型,得到了参数之间的交互作用,利用Design-Expert软件对响应面模型进行设计参数反求,结果表明,在15 000 Hz≤Fre≤25 000 Hz计算区域内误差较小,基本满足QEPAS系统的计算需求,所提出的研究与设计方法具有一定通用性,可为QEPAS系统中石英音叉结构参数设计提供参考。 相似文献
3.
WU DeSheng WANG Xia ZHANG Xu YANG ChongLi ZHENG Ping LI PeiGang SHI YouGuo 《中国科学:物理学 力学 天文学(英文版)》2015,(1):139-144
Cd3As2 was recently identified as a novel three-dimensional(3D)topological semimetal hosting the long-pursuing 3D Dirac Fermion.Crystals of Cd3As2 grown preferentially along the[100]and[112]directions were obtained through the modified chemical vapor transfer growth method,thus allowing the examination of transport anisotropy.The resistivity and magnetoresistance(MR)are basically linear with respect to magnetic field(H)in the measured temperature range of 2–300 K irrespective of the directions.The linear resistivity and MR are significantly anisotropic not only along[100]and[112]directions but also with respect to tilt angle between the growth directions and H,thus providing transport signatures of the 3D Dirac Fermion as well as the possible linear and anisotropic change of Weyl Fermi surface in H.Very large MR along the[100]direction is observed,even approaching 3100%at 2 K and 14 k Oe(1 Oe=79.5775 A m-1).The results would be helpful in renewing interest in studying emergent phenomena arising from bulk 3D Dirac Fermion as well as in paving the way for Cd3As2 to be used in magnetoelectronic sensors. 相似文献
4.
WANG Zhong HONG Haitao XIAO Hai SUN Changku MENG Yan YE Shenghua 《Chinese Journal of Lasers》1997,6(5):435-440
1.IntroductionAbsolutedistancemeasurementisfarfromanewtopic.However,itisstillafieldstimulatinggreatinterestsnowadaysduetoitSimportantroleinmanufacturingandassembly['J.SincethegreatsuccessachievedbyMichelsonandBenoitwhentheyfirstdevelopedaninterferometertodeterminethestandardmeterintermsofthemonochromaticredcadmiumline,theopticinterferometerhasbeenprovedtobeoneofthemostpreciseandefficientwayindisplacementmeasurementbecauseofitshighdiscriminationandsimplestructure.However,thetraditionalinterfe… 相似文献
5.
ZHAO Shan-Rong CHEN Kai-Xian JIANG Hua-Liang WANG Qin-Mi JI Ru-YunShanghai Institute of Materia Medica Chinese Academy of Sciences Shanghai China 《中国化学》1997,15(1):84-89
We have used quantum mechanical method to study the transition states(TSs) of uridine phosphorolysis reaction. Comparing the four different reaction pathways and the five transition states obtained, we conclude that enzymatic uridine phosphorolysis takes place mainly according to acid-catalyzed SN2 mechanism. The proposed reaction pathway is consistent with many experimental results. 相似文献
6.
本文用三元相图及坐标变换的单纯优化法安排实验,测定铜(Ⅱ)-邻菲Luo啉(Phen)-铬天菁S(CAS)三元络合物组成。通过两种方法,不同算什么所得结果一致,络合比为3:3:2。 相似文献
7.
WANG Libin 《数学年刊B辑(英文版)》2002,23(4):439-454
The author gets a blow-up result of C1 solution to the Cauchy problem for a first order quasilinear non-strictly hyperbolic system in one space dimension. 相似文献
8.
ZHONG Hui WAN Mingxi JIANG Yifeng WANG Supin 《声学学报:英文版》2006,25(2):104-115
The present study was to investigate the differential imaging method for detecting HIFU (High Intensity Focused Ultrasound)-induced lesions and the estimation of variation of attenuation for lesion evaluation with log spectral difference algorithm. Experiment results of bovine muscle and liver in vitro were acquired. Several algorithms for lesion detection - Absolute Difference (AD), Sum Absolute Differences (SAD) and Sum Squared Differences (SSD) - were analyzed with several window sizes and threshold values. Then three attenuation parameters were compared to evaluate the degree of tissue damage. It was found that variation of the mean attenuation △α was an effective parameter to evaluate lesions. 相似文献
9.
Speech emotion recognition based on statistical pitch model 总被引:1,自引:0,他引:1
WANG Zhiping ZHAO Li ZOU Cairong 《声学学报:英文版》2006,25(1):87-96
A modified Parzen-window method, which keep high resolution in low frequencies and keep smoothness in high frequencies, is proposed to obtain statistical model. Then, a gender classification method utilizing the statistical model is proposed, which have a 98% accuracy of gender classification while long sentence is dealt with. By separation the male voice and female voice, the mean and standard deviation of speech training samples with different emotion are used to create the corresponding emotion models. Then the Bhattacharyya distance between the test sample and statistical models of pitch, are utilized for emotion recognition in speech. The normalization of pitch for the male voice and female voice are also considered, in order to illustrate them into a uniform space. Finally, the speech emotion recognition experiment based on K Nearest Neighbor shows that, the correct rate of 81% is achieved, where it is only 73.85% if the traditional parameters are utilized. 相似文献
10.
1 INTRODUCTION Carbon nanotubes have many potential applica- tions due to their unique structures and properties[1~4]. Physicists have been studying their electrical, me- chanical and other properties since their discove- ries[5, 6]. Recently, chemists are interested in carbon nanotubes because their properties can be altered by chemical functionalization[7~14], and these functiona- lized nanotubes can undergo further chemical trea- tment. So the potential application range of such na- … 相似文献