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去氢枞酸类成核剂改性聚丙烯的非等温结晶动力学研究 总被引:7,自引:0,他引:7
对以去氢枞酸盐为成核剂的聚丙烯非等温结晶动力学进行了研究,用修正Avrami方程的Jexiorny法和莫志深法进行处理。结果表明:修正Avrami方程的Jeziorny方法和莫志深法都适用于去氢枞酸类成核剂改性的聚丙烯的非等温结晶动力学。在同样的降温速率下纯聚丙烯的t1/2比成核聚丙烯的t1/2要长,当降温速率为20K/min时,纯聚丙烯和成核聚丙烯的t1/2分别为0.78min和0.51min。同时从莫志深法得到的F(T)结果可以看出,达到相同的结晶度时纯聚丙烯所需的降温速率要大于成核聚丙烯所需的降温速率,说明成核剂的加入提高了聚丙烯的结晶速率。从Jeziorny法求出的纯聚丙烯和成核聚丙烯的Avrami指数分别为4.46和2.77,表明成核剂改变了聚丙烯的结晶成核和生长方式。 相似文献
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作为最重要的第三代半导体材料之一,纳米氮化镓(Ga N)也引起了人们的广泛关注与重视.本文采用微波等离子体化学气相沉积(microwave plasma chemical vapor deposition, MPCVD)系统,成功地制备出了四方截面的Ga N纳米线,其纳米线半径为300—500 nm,长度为15—20μm.研究发现,通过调控掺杂Mg的比例,可以实现其截面结构从三方向四方转变.通过进一步地研究Mg掺杂调控其截面结构的物理机制,提出其三方-四方截面结构的转变应该来源于其纳米线的气-液-固(VLS)生长向自催化气-固(VS)生长模式的转变.对所制备的纳米线进行了光致发光(photoluminescence, PL)光谱分析,结果表明四方结构Mg掺杂Ga N纳米线发光峰红移至386 nm.采用所制备的纳米线进行了场发射性能研究,结果表明四方结构Mg掺杂Ga N纳米线开启电场为5.2 V/μm,并能保持较高电流密度,相较于三方结构未掺杂Ga N纳米线场发射性能有一定提高,进而分析掺杂以及形貌结构对Ga N纳米线场发射的影响机制.研究结果不仅给出了一种四方结构Ga N纳米线的制备方... 相似文献
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Local thermal conductivity of polycrystalline AlN ceramics measured by scanning thermal microscopy and complementary scanning electron microscopy techniques 下载免费PDF全文
The local thermal conductivity of polycrystalline aluminum nitride (AlN) ceramics is measured and imaged by using a scanning thermal microscope (SThM) and complementary scanning electron microscope (SEM) based techniques at room temperature.The quantitative thermal conductivity for the AlN sample is gained by using a SThM with a spatial resolution of sub-micrometer scale through using the 3ω method.A thermal conductivity of 308 W/m·K within grains corresponding to that of high-purity single crystal AlN is obtained.The slight differences in thermal conduction between the adjacent grains are found to result from crystallographic misorientations,as demonstrated in the electron backscattered diffraction.A much lower thermal conductivity at the grain boundary is due to impurities and defects enriched in these sites,as indicated by energy dispersive X-ray spectroscopy. 相似文献
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Local thermal conductivity of polycrystalline AlN ceramics measured by scanning thermal microscopy and complementary scanning electron microscopy techniques 下载免费PDF全文
The local thermal conductivity of polycrystalline aluminum nitride (AlN) ceramics is measured and imaged by using a scanning thermal microscope (SThM) and complementary scanning electron microscope (SEM) based techniques at room temperature. The quantitative thermal conductivity for the AlN sample is gained by using a SThM with a spatial resolution of sub-micrometer scale through using the 3ω method. A thermal conductivity of 308 W/m·K within grains corresponding to that of high-purity single crystal AlN is obtained. The slight differences in thermal conduction between the adjacent grains are found to result from crystallographic misorientations, as demonstrated in the electron backscattered diffraction. A much lower thermal conductivity at the grain boundary is due to impurities and defects enriched in these sites, as indicated by energy dispersive X-ray spectroscopy. 相似文献
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为研究爆炸条件下土中应力波的时空分布,基于黄土中接触爆炸和半埋爆炸试验,验证了ANSYS/AUTODYN软件建立的计算模型,并在此基础上开展了土中爆炸地冲击效应研究。结果表明:随着土介质深度的增加,感生地冲击峰值减小,而直接地冲击峰值增大,最终,压力和竖向应力时程曲线中的2个峰值减少为1个峰值,据此特征可将土中应力波场分为3个区域,即地表区、近地表区和中心区;当装药比例埋深为-0.05~0.075 m/kg1/3时,随着装药比例埋深的增大,中心区迅速扩大,地表区迅速缩小,近地表区逐渐扩大;当装药比例埋深为0.1~0.4 m/kg1/3时,地冲击作用区的分布趋于稳定;爆炸耦合进入空气和土介质中的动能受炸药类型影响,但在一定范围内,地冲击作用区角度与地面空气冲击波超压冲量和直接地冲击应力冲量之比呈线性相关关系。 相似文献
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利用介质阻挡放电等离子体化学气相沉积技术,在蒸镀有25nm Ni催化剂层的Si基片上,以CH4和H2作为反应气体,在973K下制备了碳纳米管,并研究了微量水的引入对碳纳米管形貌的影响.场发射扫描电子显微镜结果表明,不加水时,制备出的碳纳米管直径不均匀,分布在40—90nm之间,呈链节状的结构;加入少量水时,制备出的碳纳米管直径比较均匀,集中在70nm左右,表面为瘤状结构;当水的流量进一步增加时,得到的碳纳米管表面光滑,出现了枝状结构.原位测量了加水前后等离子体区的发射光谱,分析了微量水的引入对于碳纳米管形貌变化的影响机理.
关键词:
碳纳米管
介质阻挡放电
水
发射光谱 相似文献
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从作业功能、作业类型、作业设计、作业评价等4个方面介绍了近年来国内中学化学作业的研究情况,希望有助于促进中学化学作业的设计与布置,促进化学教学的有效性。 相似文献
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