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Direct measurement of the surface dynamics of supercooled liquid-glycerol by optical scanning a film 下载免费PDF全文
The surface dynamics of supercooled liquid-glycerol is studied by
scanning the thickness of the glycerol film with single photon
detection. Measurements are performed at room temperature well above
the glycerol's glass transition temperature. It is shown that the
surface dynamics of the glycerol film is very sensitive to the
temperature. The linear relationship between the thickness of the
film and the viscosity predicted by the Vogel--Fulcher--Tammann--Hesse
(VFTH) law is also presented experimentally. 相似文献
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对室温下染料单分子进行了偶极取向和偶极再取向动力学的实验研究.利用共焦扫描显微镜光学系统与荧光偏振探测分析相结合的方法分别测量了聚合体薄膜中的单分子和无聚合体薄膜的单分子偶极方向变化特性,经采样统计测量镶嵌于聚合体薄膜中的单分子发生偶极再取向的概率约为5%—9%,无聚合体薄膜的单分子发生偶极再取向的概率约为26%.通过测量单分子荧光的偏振度轨迹曲线发现,偶极再取向存在着在多个偏振态之间的量子化跳跃行为.
关键词:
单分子
偶极取向
再取向
量子化跳跃 相似文献
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