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1.
G.J. Babonas A. Reza I. Simkiene M. Baran U.O. Karlsson 《Applied Surface Science》2006,252(15):5391-5394
Optical properties of Fe-doped silica films on Si were investigated by ellipsometric technique in the region 1-5 eV. Samples were produced by sol-gel method. Precursors were prepared by mixing tetraethoxysilane (TEOS) solution in ethanol and water with aqueous solution of Fe-chloride or Fe-acetate. The coating solution was deposited on Si substrates by spin on technique. The size of Fe-containing nanometric-sized particles depended on technology and varied from 20 to 100 nm. Optical response of complex hybrid samples SiO2:Fe/Si was interpreted in a multi-layer model. In the inverse problem, the Maxwell equations were solved by transfer matrix technique. Dielectric function of Fe-doped silica layers was calculated in the model of effective media. Analysis of optical data has shown that various Fe-oxides formed. Experimental data for films obtained from precursors with Fe-acetate and annealed in hydrogen were well described by the model calculations taking into account a small contribution 1-5% of metal Fe imbedded in silica. The Fe/Fe-O contribution to optical response increased for samples grown from FeCl3-precursor. Ellipsometric data for Fe-doped silica films on Si were interpreted taking into account the structural AFM studies as well as the results of magnetic measurements. 相似文献
2.
Jilly James Chidambaram Ramalechume Asit Baran Mandal 《Journal of Polymer Science.Polymer Physics》2007,45(17):2410-2420
The shape, size, aggregation, hydration, and correlation times of water insoluble PEO‐PPO‐PEO triblock copolymer micelles with sodium dodecylsulfate (SDS) micelles were investigated using transport studies and dynamic light scattering technique. From the conductance of micellar solutions of the polymer in 25 mM SDS and 5 mM NaCl, the hydration of polymer micelles were determined using the principle of obstruction of electrolyte migration by the polymer. The asymmetry of the micellar particles of polymer and polymer‐SDS mixed micellar systems in 5 mM NaCl and their average axial ratios were calculated using intrinsic viscosity and hydration data obeying Simha–Einstein equation. Hydration number and micellar sizes were variable with temperature. The shape of the polymer micelles has been ellipsoidal rather than spherical. The micellar volume, hydrodynamic radius, radius of gyration, diffusional coefficients as well as translational, rotational and effective correlation times have been calculated from the absolute values of the axes. The partial molal volume of polymer micelles has also been determined and its comparison with the molar volume of pure polymer suggested a volume contraction due to immobilization of the water phase by the hydrophilic head groups of the polymer. The thermodynamic activation parameters for viscous flow favor a more ordered water structure around polymer micelles at higher temperatures. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2410–2420, 2007 相似文献
3.
Enrique J. Baran 《Monatshefte für Chemie / Chemical Monthly》1991,122(6-7):479-481
Summary Mean amplitudes of vibration for OTeF
5
–
have been calculated from known spectroscopic and structural data in a wide temperature range. The results are briefly discussed in comparison with those of related species. 相似文献
4.
5.
6.
N. V. Gaponenko A. V. Mudryi O. V. Sergeev M. Stepikhova L. Palmetshofer W. Jantsch J. C. Pivin B. Hamilton A. S. Baran A. I. Rat''ko 《Journal of luminescence》1998,80(1-4):399-403
Sol–gel derived Fe2O3 films containing about 10 wt% of Er2O3 were deposited on porous silicon by dipping or by a spin-on technique followed by thermal processing at 1073 K for 15 min. The samples were characterized by means of PL, SEM and X-ray diffraction analyses. They exhibit strong room-temperature luminescence at 1.5 μm related to erbium in the sol–gel derived host. The luminescence intensity increases by a factor of 1000 when the samples are cooled from 300 to 4.2 K. After complete removal of the erbium-doped film by etching and partial etching the porous silicon, the erbium-related luminescence disappears. Following this, luminescence at 1.5 μm originating from optically active dislocations (“D-lines”) in porous silicon was detected. The influence of the conditions of synthesis on luminescence at 1.5 μm is discussed. 相似文献
7.
J. Baran A. J. Barnes M. K. Marchewka A. Pietraszko H. Ratajczak 《Journal of Molecular Structure》1997,416(1-3):33-42
The crystal structure of bis(betaine)-selenic acid has been determined by X-ray diffraction as orthorhombic, space group Pbca, with a = 11.591(2), b = 22.930(5), c = 12.045(2) Å and Z = 8. The crystal comprises hydrogen selenate ions, HSeO−4, and two distinct betaine molecules, which are held together into a complex by short hydrogen bonds. One of the betaine molecules is present as the zwitterion form (CH3)3N+---CH2---COO− and the second occurs as the protonated form (CH3)3N+---CH2---COOH. Powder FTIR and Raman spectra were measured. An assignment of the observed bands to vibrations of the hydrogen bonds and internal vibrations of the hydrogen selenate ion and the betaine molecules is proposed. 相似文献
8.
E. J. Baran 《Monatshefte für Chemie / Chemical Monthly》1973,104(6):1653-1659
The mean amplitudes of vibration of ICl2
–, IBr2
–, BrCl2
– and ClF2
– have been calculated, from known spectroscopic data, in the temperature range between O° and 1000°K. Also generalized mean-square amplitudes and values for theBastiansen—Morino shrinkage effect are reported. The results are briefly discussed.
Mit 1 Abbildung 相似文献
Mit 1 Abbildung 相似文献
9.
Adcock W Baran Y Filippi A Speranza M Trout NA 《The Journal of organic chemistry》2005,70(3):1029-1034
Experimental gas-phase acidities are reported for a series of 3-substituted (X) bicyclo [1.1.1]pent-1-yl carboxylic acids (1, Y = COOH). A comparison with available calculated data (MP2/6-311++G**// B3LYP/6-311+G**) reveals good agreement. The relative substituent effects are shown to be adequately described by a much lower level of theory (B3LYP/6-31+G*). Various correlations are presented which clearly point to polar field effects as being the origin of the relative acidities. 相似文献
10.
Baran EJ Weil M 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2005,61(4):707-710
The infrared and Raman spectra of the crystalline hexaoxotellurates Hg3TeO6 and Hg2TeO5 were recorded and discussed on the basis of a site symmetry analysis derived from known structural data. Approximate values for the Te-O bond force constants are reported and some comparisons with related species are made. 相似文献