全文获取类型
收费全文 | 2389篇 |
免费 | 95篇 |
国内免费 | 9篇 |
专业分类
化学 | 1715篇 |
晶体学 | 20篇 |
力学 | 28篇 |
综合类 | 1篇 |
数学 | 171篇 |
物理学 | 558篇 |
出版年
2023年 | 24篇 |
2022年 | 23篇 |
2021年 | 28篇 |
2020年 | 27篇 |
2019年 | 40篇 |
2018年 | 27篇 |
2017年 | 16篇 |
2016年 | 57篇 |
2015年 | 53篇 |
2014年 | 60篇 |
2013年 | 109篇 |
2012年 | 123篇 |
2011年 | 147篇 |
2010年 | 82篇 |
2009年 | 85篇 |
2008年 | 147篇 |
2007年 | 150篇 |
2006年 | 158篇 |
2005年 | 142篇 |
2004年 | 105篇 |
2003年 | 93篇 |
2002年 | 68篇 |
2001年 | 48篇 |
2000年 | 52篇 |
1999年 | 34篇 |
1998年 | 27篇 |
1997年 | 26篇 |
1996年 | 38篇 |
1995年 | 12篇 |
1994年 | 22篇 |
1993年 | 24篇 |
1992年 | 28篇 |
1991年 | 19篇 |
1990年 | 25篇 |
1989年 | 32篇 |
1988年 | 29篇 |
1987年 | 24篇 |
1986年 | 27篇 |
1985年 | 31篇 |
1984年 | 36篇 |
1983年 | 15篇 |
1982年 | 17篇 |
1981年 | 25篇 |
1980年 | 15篇 |
1978年 | 19篇 |
1977年 | 11篇 |
1976年 | 15篇 |
1975年 | 16篇 |
1974年 | 10篇 |
1973年 | 15篇 |
排序方式: 共有2493条查询结果,搜索用时 15 毫秒
1.
Tomoyuki Nakatsuka 《Mathematische Nachrichten》2021,294(1):98-117
We study the existence of a time‐periodic solution with pointwise decay properties to the Navier–Stokes equation in the whole space. We show that if the time‐periodic external force is sufficiently small in an appropriate sense, then there exists a time‐periodic solution of the Navier–Stokes equation such that and uniformly in as . Our solution decays faster than the time‐periodic Stokes fundamental solution and the faster decay of its spatial derivatives of higher order is also described. 相似文献
2.
3.
Hiroyuki Saimoto Tomoyuki Onitsuka Satoko Okabe Minoru Morimoto 《Tetrahedron letters》2004,45(48):8777-8780
Treatment of 1,3-dihydroxyacetone and acrolein with aqueous KOH gave a tetrahydrofuran derivative, 1,4-dihydroxy-3,7-dioxabicyclo[3.3.0]octane, in 80% yield. Similarly, 6-alkyl substituted 1,4-dihydroxy-3,7-dioxabicyclo[3.3.0]octanes were obtained by reaction of 1,3-dihydroxyacetone with various α,β-unsaturated aldehydes. In the cases of long chain alkenals, the reaction was effectively accelerated in the presence of organic co-solvent. On the other hand, the corresponding tricyclic products were synthesized by reaction of 1,3-dihydroxyacetone with cyclic enones, such as 2-cyclopentenone and 2-cyclohexenone. This method was successfully applied to the reaction of a tetrulose in the absence of any protecting groups. 相似文献
4.
Yasuyuki Agari Kiyofumi Sakai Yosikazu Kano Ryoki Nomura 《Journal of Polymer Science.Polymer Physics》2007,45(21):2972-2981
We prepared biodegradable poly(ethylene oxide) (PEO)/poly(L ‐lactic acid) (PLLA) graded blends by the dissolution–diffusion process, and discussed the biodegradability and tensile strength of the graded blends by comparing isotropic blend and PLLA only. All the graded blends were degraded more largely than the PLLA only and isotropic blend (PEO: 37.5 wt %), which had the same content as the total content of those graded blends. The graded blend having most excellent wide compositional gradient was degraded most largely with the enzyme. Thus, graded structure of the blends promoted their biodegradabilities large. It was considered that the dissolution of PEO with water increased the surface area attacked by the enzyme, while PEO caught PLLA oligomers to promote the biodegradation of PLLA. Then, the biodegradabilities of the graded blends were suppressed by the increasing crystallinity of PLLA. Furthermore, the strengths of all the graded blends were larger than those of the isotropic blend. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2972–2981, 2007 相似文献
5.
Seiichi Nishizawa Tomoyuki Kamaishi Tomoyuki Yokobori Ryo Kato Ying-Yu Cui Takeshi Shioya Norio Teramae 《Analytical sciences》2004,20(11):1559-1565
Facilitated SO4(2-) transfers by hydrogen bond-forming ionophores are investigated across the nitrobenzene (NB)-water interface by using polarography with a dropping electrolyte electrode. Bis-thiourea 1, alpha,alpha'-bis(N'-p-nitrophenylthioureylene)-m-xylene, is found to significantly facilitate the transfer of the highly hydrophilic SO4(2-) whereas its counterpart, N-(p-nitrophenyl)-N'-propylthiourea (ionophore 2), cannot. In contrast to the predominant formation of a 1:1 complex with SO4(2-) in the bulk NB phase, the SO4(2-) transfer assisted by 1 is indeed based on the formation of a 1:2 complex between SO4(2-) and ionophore, even under the condition of [SO4(2-)]aq > [1]org. Such an exclusive formation of the 1:2 (SO4(2-) to ionophore) complex at the NB-water interface is not observed with structurally similar bis-thiourea 3, alpha,alpha'-bis(N'-phenylthioureylene)-m-xylene, where p-nitrophenyl moietes of bis-thiourea 1 are simply replaced by phenyl groups. The facilitated transfer of SO4(2-) with bis-thiourea 1 is further compared to that of HPO4(2-) and H2PO4- across the NB-water interface, which was previously shown to be assisted by 1 through the formation of the 1:1 and 2:1 (anion to ionophore) complexes, respectively. On the basis of these examinations, unique binding behaviors of hydrogen bond-forming ionophores at the NB-water interface are discussed, with a view towards development of ionophore-based anion-selective chemical sensors. 相似文献
6.
Let Cld
AW
(X) be the hyperspace of nonempty closed subsets of a normed linear space X with the Attouch–Wets topology. It is shown that the space Cld
AW
(X) and its various subspaces are AR's. Moreover, if X is an infinite-dimensional Banach space with weight w(X) then Cld
AW
(X) is homeomorphic to a Hilbert space with weight 2
w(X). 相似文献
7.
8.
9.
Selective oxidation of an AlInAs layer was investigated for enhancement of magneto-optic effect in an optical isolator. Twelve times nonreciprocal phase shift enhancement was estimated from a measured AlInAs-oxide refractive index. 相似文献
10.
Teruhisa Horita Katsuhiko Yamaji Natsuko Sakai Yueping Xiong Harumi Yokokawa Tatsuya Kawada 《Ionics》2002,8(1-2):108-117
The oxygen reduction active sites were visualized around the O2/SOFC cathode/electrolyte triple phase boundaries (TPB) by the16O/18O exchange techniques and secondary ion mass spectrometry (SIMS) analysis. The higher18O concentration is observed on the cathode top surfaces (La0.9Sr0.1MnO3-mesh, Au-mesh, and Ag-porous), which suggested the promotion of oxygen adsorption and oxygen surface exchange at the cathode.
The oxygen diffusion through the bulk of cathode occurred at the La0.9Sr0.1MnO3-mesh and the Ag-porous cathodes, not at the Au-mesh cathode. On the YSZ surfaces after removing the cathode, the active sites
for oxygen incorporation were analyzed by SIMS. The active sites for oxygen incorporation were at the La0.9Sr0.1MnO3/YSZ interface as well as the TPB. On the other hand, the active sites for oxygen incorporation are limited to the TPB in
the case of the Au-mesh removed YSZ surface. From the SIMS analysis, the expansion of the active sites for oxygen incorporation
is less than a few μm from the TPB lines.
Paper presented at the 8th EuroConference on Ionics, Carvoeiro, Algarve, Portugal, Sept. 16–22, 2001. 相似文献