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Nickel–indium telluride schottky barriers have been prepared by sequential evaporation, and their electrical characteristics have been studied. Various diode parameters have been obtained through current-voltage and capacitance-voltage characteristics. An equilibrium energy level diagram for the Ni/p–InTe system has been constructed using the experimental results. 相似文献
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Alexander Rousina‐Webb Christophe Lachance‐Brais Felix J. Rizzuto Mohammad S. Askari Hanadi F. Sleiman 《Angewandte Chemie (International ed. in English)》2020,59(10):4091-4098
The double crossover junction (DX) is a fundamental building block for generating complex and varied structures from DNA. However, its implementation in functional devices is limited to the inherent properties of DNA itself. Here, we developed design strategies to generate the first metal–DX DNA tiles (DXM) by site‐specifically functionalizing the tile crossovers with tetrahedral binding pockets that coordinate CuI. These DX junctions bind two CuI ions independently at distinct sites, display greater thermal stability than native DX tiles upon metalation, and melt in a cooperative fashion. In addition, the right‐handed helical chirality of DNA is transferred to the metal centers. Our tiles display high metal ion selectivity, such that CuII is spontaneously reduced to CuI in situ. By modifying our design over three generations of tiles, we elucidated the thermodynamic and geometric requirements for the successful assembly of DXM tiles, which have direct applicability in developing robust, stable DNA‐based materials with electroactive, photoactive, and catalytic properties. 相似文献
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