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排序方式: 共有749条查询结果,搜索用时 31 毫秒
1.
Some nickel, copper, and silver salts or complexes are efficient catalysts for the oxidation of benzylic ethers with oxygen in 1,2-dimethoxyethane. Salts of the weakly coordinating anion trifluoroacetate are particularly efficient, approaching (and, in some cases, improving) the yields obtained with cobalt(II) chloride, the best catalyst so far reported. 相似文献
2.
B. Savo P. Romano A. Nigro R. Di Leo 《Physica C: Superconductivity and its Applications》2002,370(4):275-280
The flat voltage noise component of current biased, high-transparency Nb/AlOx/Nb superconducting tunnel junctions has been investigated at frequencies up to 70 kHz. Several aspects of the analyzed phenomena suggest the presence of current noise effects induced by the discreteness of the charge carriers. At subgap voltages, where excess currents occur, a behavior coherent with a multiple Andreev reflection-assisted transport through the tunnel barrier has been found. However, the measured charge values exceed any theoretical prediction. 相似文献
3.
A model for the interaction of near-infrared laser pulses with metal powders in selective laser sintering 总被引:4,自引:0,他引:4
P. Fischer N. Karapatis V. Romano R. Glardon H.P. Weber 《Applied Physics A: Materials Science & Processing》2002,74(4):467-474
A thermal model of the interaction of pulsed near-infrared laser radiation from a Nd:YAG laser was made, taking the measured
powder properties such as reflectance, optical penetration depth and thermal conductivity into account. It allows an estimation
of the evolution of two different temperatures: the average temperature of the powder (taken over the grains in a volume given
by the laser beam diameter and the optical penetration depth) and the temperature distinction within a single grain. It showed
that in pulsed mode consolidation can be achieved at much lower average power as the surface of the powder particles are molten
but their cores remain at nearly room temperature. This leads to a much lower average temperature and therefore a dramatic
decrease in residual thermal stresses in the finished piece. The results of the model were experimentally tested and confirmed.
Received: 26 July 2001 / Accepted: 23 November 2001 / Published online: 23 January 2002 相似文献
4.
Jürgen Kurths M. Carmen Romano Marco Thiel Grigory V. Osipov Mikhail V. Ivanchenko István Z. Kiss John L. Hudson 《Nonlinear dynamics》2006,44(1-4):135-149
We present two different approaches to detect and quantify phase synchronization in the case of coupled non-phase coherent
oscillators. The first one is based on the general idea of curvature of an arbitrary curve. The second one is based on recurrences
of the trajectory in phase space. We illustrate both methods in the paradigmatic example of the R?ssler system in the funnel
regime. We show that the second method is applicable even in the case of noisy data. Furthermore, we extend the second approach
to the application of chains of coupled systems, which allows us to detect easily clusters of synchronized oscillators. In
order to illustrate the applicability of this approach, we show the results of the algorithm applied to experimental data
from a population of 64 electrochemical oscillators. 相似文献
5.
Forward degenerate four-wave mixing (DFWM) processes are investigated with a femtosecond pulsed laser in lithium niobate crystal doubly-doped with magnesium and iron (LiNbO3:Fe, Mg). The pulse energy dependence reveals a pure third-order nonlinear response, and the third-order nonlinear susceptibility x^(3) in the material is evaluated to be 4.96 × 10^-13 esu. The time-resolved DFWM process shows a response time of x^(3) shorter than 100fs, which is due to the nonresonant electronic nonlinearities. Our results indicate that LiNbO3 crystals have potentials for ultrafast real-time optical processing systems, which require a large and fast x^(3) optical nonlinearity. 相似文献
6.
Franco Bellesia Franco Ghelfi Romano Grandi Ugo Maria Pagnoni Adriano Pinetti 《Journal of heterocyclic chemistry》1993,30(3):617-621
Pyrroles are powerful nucleophiles in the reaction with dialkyl sulfoxides and trimethylchlorosilane (TMCS) or trimethylbromosilane (TMBS), affording sulfonium salts or halo derivatives, generally in good yields. 相似文献
7.
Monte Carlo simulation results are reported for clusters consisting of 250 water molecules surrounding serine, both in the neutral form and in two zwitterionic conformers (in order to gain some insight into conformational effects). Calculations were carried out at 300 K and using two-body potentials obtained by means of quantum-mechanical calculations. The spatial dependence of the average interaction energies was investigated. The solvation structure was investigated by means of radial distribution functions and probability density maps, which showed a few water molecules directly solvating the hydrophilic groups and, beyond them, a more or less rich and complex hydrogen-bonded network of solvent molecules. 相似文献
8.
Visintin RF Lapasin R Vignati E D'Antona P Lockhart TP 《Langmuir : the ACS journal of surfaces and colloids》2005,21(14):6240-6249
A waxy crude oil which gels below a threshold temperature has been investigated under static and dynamic conditions, using a combination of rheological methods, optical microscopy, and DSC. Particular attention is given in this work to the influence of the mechanical history on gel strength and to describing the time-dependent rheological behavior. The gels display a strong dependence of the yield stress and moduli on the shear history, cooling rate, and stress loading rate. Of particular interest is the partial recovery of the gel structure after application of small stress or strain (much smaller than the critical values needed for flow onset) during cooling, which can be used to reduce the ultimate strength of the crude oil gel formed below the pour point. A second focus of this study is to further develop the physical interpretation of the mechanism by which wax crystallization produces gelation. Gelation of the waxy crude oil studied is suggested to be the result of the association between wax crystals, which produces an extended network structure, and it is shown that the system displays features common to attractive colloidal gels, for one of which, fumed silica (Aerosil 200) in paraffin oil, rheological data are reported. The colloidal gel model provides a simple and economical basis for explaining the response of the gelled oil to various mechanical perturbations and constitutes a fruitful basis from which to develop technologies for controlling the gelation phenomenon, as suggested by the rheological results reported. 相似文献
9.
Jockusch RA Kroemer RT Talbot FO Snoek LC Carçabal P Simons JP Havenith M Bakker JM Compagnon I Meijer G von Helden G 《Journal of the American Chemical Society》2004,126(18):5709-5714
The beta(1-->4) glycosidic linkage found in lactose is a prevalent structural motif in many carbohydrates and glycoconjugates. Using UV and IR ion-dip spectroscopies to probe benzyl lactoside isolated in the gas phase, we find that the disaccharide unit adopts only a single, rigid structure. Its fully resolved infrared ion-dip spectrum is in excellent agreement with that of the global minimum structure computed ab initio. This has glycosidic torsion angles of phi(H) (H1-C1-O-C4') approximately 180 degrees and psi(H) (C1-O-C4'-H4') approximately 0 degrees which correspond to a rotation of approximately 150 degrees about the glycosidic bond compared to the accepted solution-phase conformation. We discuss the biological implications of this discovery and the generality of the strategies employed in making it. 相似文献
10.
[reaction: see text] Marine diatoms produce alpha,beta,gamma,delta-unsaturated aldehydes that have detrimental effects on the reproduction of their natural predators. The production of these defensive metabolites is suggested to involve enzymatic oxidation of polyunsaturated fatty acids. In this paper, feeding experiments with labeled precursor provide clear evidence in support of the origin of octadienals 1 and 2 from 6,9,12-hexadecatrienoic acid (5), thus proving the involvement of novel lipoxygenase/lyase activity for the oxidation of C(16) fatty acids. 相似文献