全文获取类型
收费全文 | 645篇 |
免费 | 49篇 |
国内免费 | 2篇 |
专业分类
化学 | 494篇 |
晶体学 | 8篇 |
力学 | 14篇 |
数学 | 41篇 |
物理学 | 139篇 |
出版年
2024年 | 4篇 |
2023年 | 7篇 |
2022年 | 16篇 |
2021年 | 23篇 |
2020年 | 29篇 |
2019年 | 30篇 |
2018年 | 27篇 |
2017年 | 22篇 |
2016年 | 39篇 |
2015年 | 23篇 |
2014年 | 21篇 |
2013年 | 37篇 |
2012年 | 52篇 |
2011年 | 43篇 |
2010年 | 41篇 |
2009年 | 26篇 |
2008年 | 36篇 |
2007年 | 30篇 |
2006年 | 21篇 |
2005年 | 23篇 |
2004年 | 14篇 |
2003年 | 17篇 |
2002年 | 10篇 |
2001年 | 3篇 |
2000年 | 8篇 |
1999年 | 3篇 |
1998年 | 4篇 |
1997年 | 4篇 |
1996年 | 4篇 |
1995年 | 2篇 |
1994年 | 7篇 |
1993年 | 6篇 |
1992年 | 8篇 |
1991年 | 12篇 |
1990年 | 4篇 |
1989年 | 9篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 4篇 |
1983年 | 6篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1979年 | 3篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有696条查询结果,搜索用时 15 毫秒
1.
2.
3.
We present a characterization of confluence for term rewriting systems, which is then refined for special classes of rewriting systems. The refined characterization is used to obtain a polynomial time algorithm for deciding the confluence of ground term rewrite systems. The same approach also shows the decidability of confluence for shallow and linear term rewriting systems. The decision procedure has a polynomial time complexity under the assumption that the maximum arity of a function symbol in the signature is a constant. 相似文献
4.
The ferromagnetic shape memory alloy with nominal composition Ni54Fe19Ga27 is investigated by Ac susceptibility and resistivity measurements. The alloy shows long-range ferromagnetic order below 290 K. The anomaly due to the martensitic transition is observed in the susceptibility and resistivity data in the temperature range around 220 K, which is associated with clear thermal hysteresis. Minor hysteresis loop technique was used to investigate the phase coexistence across the martensitic transition, and our analysis indicate that both martensite and austenite phases mutually coexist in the region of hysteresis. 相似文献
5.
A nanoscale
multivalent platinum drug based on a poly(amidoamine) [PAMAM] dendrimer (generation
4.5, carboxylate surface) has been synthesized and fully characterized using
a variety of spectroscopic, chromatographic and thermal methods. Treatment
of the dendrimer with an aqueous solution containing an excess diaquo(cis-1,2-diaminocyclohexane)platinum(II) produces
a conjugate containing approximately forty (diaminocyclohexane)platinum(II)
moieties at the surface of the dendrimer. This material undergoes smooth two-stage
thermal decomposition to provide residual platinum oxide reflecting the platinum
loading in the drug. 相似文献
6.
Vijay K. Goyal Rakesh K. Kapania 《International Journal of Solids and Structures》2008,45(10):2799-2817
Because of the inherent complexity of fiber-reinforced laminated composites, it can be challenging to manufacture composite structures according to their exact design specifications, resulting in unwanted material and geometric uncertainties. Thus the understanding of the effect of uncertainties in laminated structures on their static and dynamic responses is highly important for a reliable design of such structures. In this research, we focus on the probabilistic stability analysis of laminated structures subject to subtangential loading, a combination of conservative and nonconservative tangential loads, using the dynamic criterion. In order to study the dynamic behavior by including uncertainties into the problem, three models were developed: exact Monte Carlo simulation, sensitivity-based Monte Carlo simulation, and probabilistic FEA. These methods were integrated into the existing finite element analysis. Also, perturbation and sensitivity analysis have been used to study nonconservative problems to study the stability analysis using the dynamic criterion. 相似文献
7.
8.
INDUCIBLE POSTREPLICATION REPAIR IS RESPONSIBLE FOR MINIMAL MEDIUM RECOVERY IN UV-IRRADIATED Escherichia coliK–12 总被引:1,自引:0,他引:1
Abstract— Ultraviolet (UV)-irradiated Escherichia coli K–12 uvrA cells showed higher survival if plated on minimal growth medium rather than on rich growth medium, i.e., they showed minimal medium recovery (MMR). A 2-hour treatment of UV-irradiated cells with rifampicin inhibited the subsequent expression of MMR, and produced a large reduction in survival. We have recently isolated a new mutant ( mmrA1 ) that does not show MMR. The mmrA mutation protected UV-irradiated uvrA cells from the effect of rich growth medium on survival, but not from the effect of rifampicin on survival. DNA daughter-strand gap (DSG) repair in UV-irradiated (4 J/m2 ) uvrA cells was inhibited to the same degree whether rich growth medium was added immediately after irradiation or after 10 min of postirradiation incubation in minimal growth medium. However, chloramphenicol added immediately after irradiation greatly reduced this repair; there was less reduction if it was added 10 min after UV irradiation. These findings suggest that MMR is an inducible repair phenomenon, and that rich growth medium inhibits this repair process itself rather than its induction. 相似文献
9.
Bhagwan?S.?GargEmail author Rakesh?K.?Sharma Ekta?Kundra 《Transition Metal Chemistry》2005,30(5):552-559
Complexes of copper(II), nickel(II), cobalt(II), and zinc(II) with 2-[2-(6-methylbenzothiazolyl)azo]-5-dimethylaminobenzoic acid have been prepared and characterized by elemental analysis, vibrational spectra, magnetic susceptibility measurements, conductance measurements and e.p.r. spectra. Stability constants have been evaluated potentiometrically. Electronic spectra, magnetic susceptibility measurements and molecular modeling studies support a distorted square planar geometry around the metal ions. Vibrational spectra indicate the coordination of the azo group, nitrogen of benzothiazole, the carboxylate anion and the acetate ion on complexation with the metal ion. All complexes are found to be monomers. The stability of the complexes follow the order: copper(II) > nickel(II) > cobalt(II) > zinc(II). 相似文献
10.
Bivas Mondal Rakesh Maiti Xing Yang Jun Xu Weiyi Tian Jia-Lei Yan Xiangyang Li Yonggui Robin Chi 《Chemical science》2021,12(25):8778
4,5-Dihydropyridazinones bearing an aryl substituent at the C6-position are important motifs in drug molecules. Herein, we developed an efficient protocol to access aryl-dihydropyridazinone molecules via carbene-catalyzed asymmetric annulation between dinucleophilic arylidene hydrazones and bromoenals. Key steps in this reaction include polarity-inversion of aryl aldehyde-derived hydrazones followed by chemo-selective reaction with enal-derived α,β-unsaturated acyl azolium intermediates. The aryl-dihydropyridazinone products accessed by our protocol can be readily transformed into drugs and bioactive molecules.Polarity inversion of arylidene hydrazones to react with bromoenals via carbene organic catalysis is disclosed. The reaction enantioselectively affords 6-aryl-4,5-dihydropyridazinones and related drugs with proven commercial applications. 相似文献