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1.
Yu. V. Belovitskaya I. V. Pekov E. R. Gobechiya N. A. Yamnova Yu. K. Kabalov N. V. Chukanov J. Schneider 《Crystallography Reports》2002,47(2):223-228
The crystal structures of two ancylite specimens from Khibiny massif (the Kola Peninsula, Russia)—ancylite-(Ce) from alkali hydrothermalites (Sr1.01Ca0.02Ba0.01)Σ1.04(Ce0.52La0.28Nd0.11Pr0.04 Sm0.01)Σ0.96(CO3)2(OH0.83F0.13)Σ0.96 · 0.9H2O and ancylite-(Ce) from carbonatites—have (Sr0.80Ca0.05Ba0.01)Σ0.86(Ce0.62La0.40Nd0.09Pr0.03) Σ1.14(CO3)2(OH0.99F0.15)Σ1.14 · 1.0H2O been refined by the Rietveld method. A focusing STOE-STADIP diffractometer with a bent Ge(111) primary monochromator was used (λ MoK α 1 radiation, 2.16° < 2θ < 54.98°; reflection number 237–437). All the computations for ancylite from alkali hydrothermalites were performed within the sp. gr. Pmc21, a = 5.0634(1) Å, b = 8.5898(1) Å, c = 7.2781(1) Å, V = 316.55(1) Å3, R wp = 1.90; the computations for ancylite from carbonatites were performed within the sp. gr. Pmcn, a = 5.0577(1) Å, b = 8.5665(2) Å, c = 7.3151(2) Å, V = 316.94(1) Å3, R wp = 2.38 in the anisotropic approximation of thermal vibrations of cations and oxygen atoms. 相似文献
2.
Yu. V. Belovitskaya I. V. Pekov E. R. Gobechiya Yu. K. Kabalov 《Crystallography Reports》2013,58(2):216-219
The crystal structure of calcioancylite-(Ce) of the (Ca0.30Sr0.22)Σ0.52(Ce0.78La0.47Nd0.16Pr0.05Sm0.02)Σ1.48(CO3)2((OH)1.20F0.28)Σ1.48 · 1.97H2O composition from alkali hydrothermalites of Mont Saint-Hilaire, Canada, has been refined by the Rietveld method. The refinement details are as follows: ADP-2 diffractometer, λCuK α radiation, Ni filter, 10.50° < 2θ < 140.00°, and the number of reflections (α1 + α2) 652. All calculations have been performed within the sp. gr. Pmcn (a = 5.0095(1) Å, b = 8.5006(1) Å, c = 7.2670(1) Å, V = 309.46(1) Å3, R wp = 3.45) in the anisotropic approximation of thermal vibrations for cations. 相似文献
3.
Rastsvetaeva R. K. Chukanov N. V. Pekov I. V. Varlamov D. A. Kazheva O. N. 《Crystallography Reports》2022,67(2):166-171
Crystallography Reports - The crystal structure and crystallochemical features of a Fe-deficient zirconium-rich analog of eudialyte from the Lovozero alkaline massif (Kola peninsula) have been... 相似文献
4.
Panikorovskii T. L. Pekov I. V. Krzhizhanovskaya M. G. Yakovenchuk V. N. Britvin S. N. Gurzhiy V. V. Bocharov V. N. Yapaskurt V. O. Krivovichev S. V. 《Crystallography Reports》2021,66(1):76-85
Crystallography Reports - Microporous silicate tiettaite from the Khibiny alkaline massif (Kola Peninsula, Russia) has been studied using X-ray diffraction analysis, electron probe microanalysis,... 相似文献
5.
Stanislav I. Pekov Evgeny S. Zhvansky Vasily A. Eliferov Anatoly A. Sorokin Daniil G. Ivanov Eugene N. Nikolaev Igor A. Popov 《Molecules (Basel, Switzerland)》2022,27(8)
Ex-vivo molecular profiling has recently emerged as a promising method for intraoperative tissue identification, especially in neurosurgery. The short-term storage of resected samples at room temperature is proposed to have negligible influence on the lipid molecular profiles. However, a detailed investigation of short-term molecular profile stability is required to implement molecular profiling in a clinic. This study evaluates the effect of storage media, temperature, and washing solution to determine conditions that provide stable and reproducible molecular profiles, with the help of ambient ionization mass spectrometry using rat cerebral cortex as model brain tissue samples. Utilizing normal saline for sample storage and washing media shows a positive effect on the reproducibility of the spectra; however, the refrigeration shows a negligible effect on the spectral similarity. Thus, it was demonstrated that up to hour-long storage in normal saline, even at room temperature, ensures the acquisition of representative molecular profiles using ambient ionization mass spectrometry. 相似文献
6.
N. V. Zubkova D. Yu. Pushcharovsky G. Giester I. V. Pekov A. G. Turchkova N. V. Chukanov E. Tillmanns 《Crystallography Reports》2005,50(3):367-373
The crystal structures of K-and Cs-exchanged forms of zorite were studied by X-ray diffraction and IR spectroscopy: K4.75Na1.82[Ti(Ti0.79Nb0.20)4Si12O34(O,OH)5.2] × 10.62 H2O (sp. gr. Cmmm, R= 0.0481 for 516 independent reflections) and Cs4.34Na1.90[Ti(Ti0.80Nb0.18)4Si12O34(O,OH)5] × 5.37 H2O (sp. gr. Cmmm, R = 0.0285 for 621 independent reflections). Both structures retain the mixed polyhedral framework of zorite: Na6Ti(Ti,Nb)4(Si6O17)2(O,OH)5 × nH2O, where n ~ 11. It is shown that the positions of the atoms located in the cavities of the frameworks of these compounds differ from those in the structures of zorite and its synthetic analogs. 相似文献
7.
N. V. Zubkova D. Yu. Pushcharovskii G. Giester E. Tillmanns I. V. Pekov O. D. Krotova 《Crystallography Reports》2004,49(6):964-968
The crystal structure of the mineral byelorussite-(Ce) NaMnBa2Ce2Ti2Si8O26(F,OH) · H2O belonging to the joaquinite group was solved and refined to R = 0.033 based on 4813 reflections with I > σ2(I). The parameters of the orthorhombic unit cell are a = 22.301(4) Å, b = 10.514(2) Å, c = 9.669(2) Å, V = 2267.1(8) Å3, sp. gr. Ama2, and Z = 4. The structure is composed of three-layer sheets, which consist of dimers of edge-sharing Ti octahedra located between isolated four-membered [Si4O2] rings. The sheets are linked to each other by Mn 5-vertex polyhedra to form a heteropolyhedral framework. Large cavities in the framework are occupied by Na 6-vertex polyhedra, Ba 11-vertex polyhedra, and REE 9-vertex polyhedra. 相似文献
8.
R. K. Rastsvetaeva I. V. Pekov N. V. Chukanov K. A. Rozenberg L. V. Olysych 《Crystallography Reports》2007,52(5):811-818
The high-sodium variety of cancrinite [Si6.3Al5.7O24][Na2(H2O)2][Na5.7(CO3)0.9(SO4)0.1(H2O)0.6] (Kovdor Massif, Kola Peninsula, Russia) and the calcium-containing variety of cancrisilite [Si6.6Al5.4O24][(Na1.2Ca0.4)(H2O)1.6][Na6(CO3)1.3(H2O)1.2] (Khibiny Massif, Kola Peninsula, Russia) are studied. The trigonal unit cell parameters of the crystal structures under investigation are as follows: a = 12.727(4) Å, c = 5.186(2) Å, and space group P3 for the former mineral and a = 12.607(4) Å, c = 5.111(1) Å, and space group P3 for the latter mineral. The reduced symmetry of the new varieties as compared to the symmetry of typical cancrinite and typical cancrisilite is associated with the specific features in the arrangement of the carbonate groups and water molecules in channels. This inference is confirmed by the IR spectroscopic data. 相似文献
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10.
The mode of retention of methyl red on Sterchamol is studied by the adsorption of compounds containing some of the functional groups active for hydrogen bonding in the methyl red molecule. It is shown that two types of adsorbing centres exist on the Sterchamol surface. An adsorbate with an oxygen or nitrogen electron-donor atom in its molecule deactivates only one type of centre. Both electron donors are present in a methyl red molecule, allowing both types of active sites to be deactivated by this adsorbate. 相似文献