全文获取类型
收费全文 | 1788篇 |
免费 | 192篇 |
国内免费 | 245篇 |
专业分类
化学 | 1270篇 |
晶体学 | 13篇 |
力学 | 90篇 |
综合类 | 16篇 |
数学 | 213篇 |
物理学 | 623篇 |
出版年
2024年 | 3篇 |
2023年 | 33篇 |
2022年 | 60篇 |
2021年 | 78篇 |
2020年 | 87篇 |
2019年 | 76篇 |
2018年 | 55篇 |
2017年 | 58篇 |
2016年 | 94篇 |
2015年 | 87篇 |
2014年 | 85篇 |
2013年 | 130篇 |
2012年 | 176篇 |
2011年 | 186篇 |
2010年 | 114篇 |
2009年 | 115篇 |
2008年 | 131篇 |
2007年 | 95篇 |
2006年 | 98篇 |
2005年 | 78篇 |
2004年 | 70篇 |
2003年 | 45篇 |
2002年 | 29篇 |
2001年 | 32篇 |
2000年 | 22篇 |
1999年 | 39篇 |
1998年 | 19篇 |
1997年 | 25篇 |
1996年 | 21篇 |
1995年 | 19篇 |
1994年 | 10篇 |
1993年 | 9篇 |
1992年 | 11篇 |
1991年 | 4篇 |
1990年 | 5篇 |
1989年 | 5篇 |
1988年 | 6篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 1篇 |
1979年 | 1篇 |
1976年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有2225条查询结果,搜索用时 15 毫秒
2.
3.
Shaobo Cheng Vidushi Sharma Altug S. Poyraz Lijun Wu Xing Li Amy C. Marschilok Esther S. Takeuchi Kenneth J. Takeuchi Marivi Fernndez-Serra Yimei Zhu 《Chemical science》2020,11(19):4991
Tunneled metal oxides such as α-Mn8O16 (hollandite) have proven to be compelling candidates for charge-storage materials in high-density batteries. In particular, the tunnels can support one-dimensional chains of K+ ions (which act as structure-stabilizing dopants) and H2O molecules, as these chains are favored by strong H-bonds and electrostatic interactions. In this work, we examine the role of water molecules in enhancing the stability of K+-doped α-Mn8O16 (cryptomelane). The combined experimental and theoretical analyses show that for high enough concentrations of water and tunnel-ions, H2O displaces K+ ions from their natural binding sites. This displacement becomes energetically favorable due to the formation of K2+ dimers, thereby modifying the stoichiometric charge of the system. These findings have potentially significant technological implications for the consideration of cryptomelane as a Li+/Na+ battery electrode. Our work establishes the functional role of water in altering the energetics and structural properties of cryptomelane, an observation that has frequently been overlooked in previous studies.Water displaces potassium ions and initiates the formation of a homonuclear dimer ion (K2+) in the tunnels of hollandite. 相似文献
4.
In this work, the beam splitter with two input ports and two output ports in two-dimensional photonic crystals is studied through the finite-difference time-domain method. The beam splitter consists of two orthogonally cross line defects. The diameter of the two diagonal air holes at the intersection of the two line defects was modified. The input light can be identically divided into the two output ports. The beam splitters can be applied in the photonic crystal Mach-Zehnder interferometers or photonic crystal optical switches. 相似文献
5.
In the present paper, some new almost fixed point theorems and fixed point theorems for lower semicontinuous type multivalued mappings are obtained in metrizable H-spaces. 相似文献
6.
In-time motion adjustment in laser cladding manufacturing process for improving dimensional accuracy and surface finish of the formed part 总被引:2,自引:0,他引:2
This paper presents in-time motion adjustment in laser cladding manufacturing process as a means to improve dimensional accuracy and surface finish of the built part. Defects occurring during laser cladding degrade the part quality such as dimensional accuracy and surface finish. In this paper, in-time motion adjustment strategy was presented to remedy and eliminate defects occurring during laser cladding to improve the dimensional accuracy and surface finish. Based on the relationship between the motion of laser head relative to the growing part and other parameters in effects on clad profile, the laser traverse speed, stand-off distance and laser approach orientation to the existing clad layer were adjusted by instructions from a close-loop control system in real time to remedy and eliminate defects. The results of the experiments verified the effects of in-time motion adjustment on dimensional accuracy and surface finish. 相似文献
7.
脂肪乳剂Intralipid代谢产物的高效液相色谱测定 总被引:2,自引:0,他引:2
本文介绍了利用HPLC色谱柱前衍生化技术简便,正确和灵敏地测定血清中游离脂肪酸的方法。在最佳条件下,一些脂肪酸的最低检知量为0.04μg。方法已用于脂肪乳剂Intralipid在诱发急性坏死性胰腺炎动物体内代谢产物测定。 相似文献
8.
Dendritic nanocrystalline CdS film was deposited at liquid-liquid interface of surfactants and an electrolyte containing 4 mmol L−1 cadmium chloride (CdCl2) and 16 mmol L−1 thioacetamide (CH3CSNH2) with an initial pH value of 5 at 15 °C by electrochemical synthesis. The nanofilm was characterized by transmission electron microscopy (TEM), field emission scanning electron microscope (FE-SEM), atomic force microscopy (AFM), ultraviolet visible (UV-vis) absorption spectroscopy and fluorescence spectroscopy. The surface morphology and particle size of the nanofilm were investigated by AFM, SEM and TEM, and the crystalline size was 30-50 nm. The thickness of the nanofilm calculated by optical absorption spectrum was 80 nm. The microstructure and composition of the nanofilm was investigated by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), showing its polycrystalline structure consisting of CdS and Cd. Optical properties of the nanofilm were investigated systematically by UV-vis absorption and fluorescence spectroscopy. A λonset blue shift compared with bulk CdS was observed in the absorption spectra. Fluorescence spectra of the nanofilm indicated that the CdS nanofilm emitted blue and green light. The nanocomposites film electrode will bring about anodic photocurrent during illumination, showing that the transfer of cavities produces photocurrent. 相似文献
9.
In this paper, by the use of a fixed point theorem, many new necessary and sufficient conditions for the existence of positive solutions in C[0,1]∩C1[0,1]∩C2(0,1) or C[0,1]∩C2(0,1) are presented for singular superlinear and sublinear second-order boundary value problems. Singularities at t=0, t=1 will be discussed. 相似文献
10.