Fast oxygen ion migration in Cu–In–oxide bulk and its utilization for effective CO2 conversion at lower temperature

Efficient activation of CO₂ at low temperature was achieved by reverse water–gas shift via chemical looping (RWGS-CL) by virtue of fast oxygen ion migration in a Cu–In structured oxide, even at lower temperatures. Results show that a novel Cu–In₂O₃ structured oxide can show a remarkably higher CO₂ splitting rate than ever reported. Various analyses revealed that RWGS-CL on Cu–In₂O₃ is derived from redox between Cu–In₂O₃ and Cu–In alloy. Key factors for high CO₂ splitting rate were fast migration of oxide ions in the alloy and the preferential oxidation of the interface of alloy–In₂O₃ in the bulk of the particles. The findings reported herein can open up new avenues to achieve effective CO₂ conversion at lower temperatures.

Efficient activation of CO₂ at low temperature was achieved by reverse water–gas shift via chemical looping (RWGS-CL) by virtue of fast oxygen ion migration in a Cu–In structured oxide, even at lower temperatures.     

Staggered local density of states around the vortex in underdoped cuprates

We have studied a single vortex with the staggered flux (SF) core based on the SU(2) slave-boson theory of high T(c) superconductors. We find that, whereas the center in the vortex core is a SF state, as one moves away from the core center a correlated staggered modulation of the hopping amplitude chi and pairing amplitude Delta becomes predominant. We predict that in this region the local density of states exhibits staggered modulation when measured on the bonds, which may be directly detected by STM experiments.     

Tuning magnetotransport through a magnetic kink crystal in a chiral helimagnet

We consider magnetotransport properties in a conducting chiral helimagnet, where the magnetic kink crystal (MKC) is formed under weak magnetic field applied perpendicular to the helical axis. The MKC behaves as a magnetic superlattice potential and results in Bragg scattering of conduction electrons. Tuning of the weak magnetic field enables us to control the size of the superlattice Brillouin zone and gives rise to a series of divergent resistivity anomalies originating from resonant Bragg scatterings. We discuss as well a nontrivial magnetic structure in the resonant states realized in the subsystem of the itinerant electrons.     

Interplay of Correlation,Randomness and Dimensionality Effects in Weakly-Coupled Half-Filled Random Hubbard Chains

Abstract

We study interplay of electronic correlation, randomness and dimensionality effects in half-filled random Hubbard chains weakly coupled via an interchain one-particle hopping. Based on the two-loop renormalization-group approach, phase diagrams are given in terms of temperature vs. strengths of the intrachain electron-electron umklapp scattering, the random scattering and the interchain one-particle hopping.     

Certification and uncertainty evaluation of the certified reference materials of poly(ethylene glycol) for molecular mass fractions by using supercritical fluid chromatography

Poly(ethylene glycol) (PEG) is a useful water-soluble polymer that has attracted considerable interest in medical and biological science applications as well as in polymer physics. Through the use of a well-calibrated evaporative light-scattering detector coupled with high performance supercritical fluid chromatography, we are able to determine exactly not only the average mass but also all of the molecular mass fractions of PEG samples needed for certified reference materials issued by the National Metrology Institute of Japan. In addition, experimental uncertainty was determined in accordance with the Guide to the expression of uncertainty in measurement (GUM). This reference material can be used to calibrate measuring instruments, to control measurement precision, and to confirm the validity of measurement methods when determining molecular mass distributions and average molecular masses. Especially, it is suitable for calibration against both masses and intensities for matrix-assisted laser desorption/ionization time-of-flight mass spectrometry. Figure Comparison between the molecular mass fractions of PEG 1000 before calibration (si) (○) and after calibration (wi) (⧫). The error bar shows the expanded uncertainty of k = 2 of each mass fraction     

Charge current driven by spin dynamics in disordered Rashba spin-orbit system

Pumping of charge current by spin dynamics in the presence of the Rashba spin-orbit interaction is theoretically studied. Considering a disordered electron, the exchange coupling and spin-orbit interactions are treated perturbatively. It is found that the dominant current induced by spin dynamics is interpreted as a consequence of the conversion from spin current via the inverse spin Hall effect. We also find that the current has an additional component from a fictitious conservative field. The results are applied to the case of a moving domain wall.     

Chiral magnetic soliton lattice on a chiral helimagnet

Using Lorenz microscopy and small-angle electron diffraction, we directly present that the chiral magnetic soliton lattice (CSL) continuously evolves from a chiral helimagnetic structure in small magnetic fields in Cr(1/3)NbS2. An incommensurate CSL undergoes a phase transition to a commensurate ferromagnetic state at the critical field strength. The period of a CSL, which exerts an effective potential for itinerant spins, is tuned by simply changing the field strength. Chiral magnetic orders observed do not exhibit any structural dislocation, indicating their high stability and robustness in Cr(1/3)NbS2.     

Critical behavior of a monoaxial chiral helimagnet

We analyze the critical behavior of magnetically ordered phases appearing in a monoaxial chiral helimagnet in a weak external magnetic field. Using the formalism of the equations of state in the critical region, we determine the temperature dependence of the order parameters for the conical phase and the soliton-lattice phase. We calculated the critical exponents and show that they coincide with those in the three-dimensional Heisenberg model.     

Color digital holography using a single monochromatic imaging sensor

Color digital holography utilizing the Doppler effect is proposed. The time variation of holograms produced by superposing images at three wavelengths is recorded using a high-speed monochromatic imaging sensor. The complex amplitude at each wavelength can be extracted from frequency information contained in the Fourier transforms of the recorded holograms. An image of the object is reconstructed by the angular spectrum method. Reconstructed monochromatic images at the three wavelengths are combined to produce a color image for display.