Microstructure,Tribological Behavior,and Corrosion-Resistant Performance of Bonded MoS2 Solid Lubricating Film Filled with Nano-LaF3

The anti-friction and wear-resistant performances of bonded MoS₂ solid lubricating films filled with nano-LaF₃ filler were investigated under in drying wear conditions, the corrosion-resistant performances of bonded lubricating films was evaluated according to ASTM-B117, and the characteristics of the bonded lubricating films were examined by TEM and elemental x-ray map. The wear-resistant performance of the bonded lubricating films filled with nano-LaF₃ filler increases with increasing content of nano-LaF₃ filler within a content range between 0 and 5 wt%, whereas the bonded lubricating films filled with 0.5–1 wt% micro-LaF₃ filler exhibit the better wear-resistant performances. The incorporation of both nano-LaF₃ and micro-LaF₃ filler leads the increase of the coefficient of friction of the bonded lubricating films. The LaF₃ filler can improve the corrosion-resistant performance of the bonded MoS₂ solid lubricating films, whereas the incorporation of nano-LaF₃ filler is more effective to improve the corrosion-resistant performance of the bonded lubricating films than micro-LaF₃ filler. The improvement in the wear-resistant and corrosion-resistant performances of the bonded lubricating films by the incorporation of the nano-LaF₃ filler is attributed to the strengthened interfacial bonding among the nano-LaF₃ and the MoS₂ lubricant and the polymeric matrix. However, a too high mass fraction of the nano-LaF₃ filler in the bonded lubricating films will increase surface and interface defects, and lead the worsening of corrosion-resistant performance of the bonded lubricating films.     

Surface-Modified Sb2S3 Nanoparticles and Their Tribological Behaviors in Liquid Paraffin

Sb₂S₃ nanoparticles surface-modified with S-tetradecyl N, N-dihydroxyethyl dithiocarbamate (C₁₄DTC-Sb₂S₃) have been synthesized via extraction of Sb₂S₃ colloidal particles from ethylene glycol into toluene in the presence of C₁₄DTC. The obtained products were characterized by high-resolution transmission electron microscope (HRTEM) and Fourier transformation infrared (FTIR), and their tribological behaviors as an additive in liquid paraffin were investigated using a four-ball tribometer. The results show that C₁₄DTC-Sb₂S₃ nanoparticles can significantly improve the friction reduction, anti-wear, and load-carrying properties of base oils. The preliminary lubrication mechanism was discussed based on the SEM and XPS investigation of the rubbed surfaces.     

温州地区维持性血液透析患者矿物质代谢紊乱情况调查

目的 了解温州地区维持性血液透析患者矿物质代谢紊乱情况及相关影响因素。方法 收集2013 年在温州地区长期维持性血液透析患者血钙、血磷、全段甲状旁腺激素（iPTH）的资料,并根据美国肾脏病协会指南（KDOQI）及中华医学会肾脏病学分会（CSN）制订的《慢性肾脏病矿物质和骨异常诊治指导》计算患者的血钙、血磷、iPTH 的达标率,并对相关影响因素进行分析。结果 共收集2 227 例2013 年在温州地区各家透析中心维持性血液透析患者的资料。按KDOQI 指南标准,患者血钙、血磷、iPTH 的达标率分别为44.90%、46.30%、27.64%,3 项均达标者占6.29%;按《慢性肾脏病矿物质和骨异常诊治指导》建议,患者血钙、血磷、iPTH 的达标率分别为57.66%、46.30%、61.14%,3 项均达标者占16.97%。此外,三级医院维持性血液透析患者的平均血磷水平为（1.67±0.51）mmol/L,血磷达标率49.10%,二级医院患者的平均血磷水平为（1.79±0.53）mmol/L,达标率为43.22%,三级医院维持性血液透析患者的血磷达标率情况优于二级医院。血白蛋白、含钙磷结合剂的使用及透析频率是影响血钙达标的独立相关因素。患者的性别、年龄、活性维生素D 的使用、透析龄及透析频率是影响血磷达标的独立相关因素。患者活性维生素D的使用是影响iPTH 达标的独立相关因素。结论 温州地区维持性血液透析患者矿物质代谢紊乱纠正情况与有关指南的要求仍然存在较大差距;患者性别、营养状态、透析频率、含钙磷结合剂的服用、活性维生素D 的使用等是影响维持性血液透析患者矿物质代谢紊乱纠正的主要相关因素。     

Phase composition and tribological properties of Ti-Al coatings produced on pure Ti by laser cladding

Ti-Al coatings with ∼14.7, 18.1, 25.2 and 29.7 at.% Al contents were fabricated on pure Ti substrate by laser cladding. The laser cladding Ti-Al coatings were analyzed with X-ray diffraction (XRD), scanning electron microscope (SEM) and X-ray energy dispersive spectroscopy (EDS). It was found that with the increase of Al content, the diffraction peaks shifted gradually to higher 2θ values. The laser cladding Ti-Al coatings with 14.7 and 18.1 at.% Al were composed of α-Ti and α₂-Ti₃Al phases, while those with 25.2 and 29.7 at.% Al were composed of α₂-Ti₃Al phase. With the increase of Al content, the cross-sectional hardness increased, while the fracture toughness decreased. For the laser cladding Ti-Al coatings, when the Al content was ≤18.1 at.%, the wear mechanism was adhesive wear and abrasive wear; while when the Al content ≥25.2 at.%, the wear mechanism was adhesive wear, abrasive wear and microfracture. With the increase of Al content, the wear rate of laser cladding Ti-Al coatings decreased under 1 N normal load, while the wear rate firstly decreased and then increased under a normal load of 3 N. Due to its optimized combination of high hardness and high fracture toughness, the laser cladding Ti-Al coating with 18.1 at.% Al showed the best anti-wear properties at higher normal load.     

A simple solution-immersion process for the fabrication of superhydrophobic cupric stearate surface with easy repairable property

The present work reports a simple and time-saving method to fabricate cupric stearate film on zinc substrate by a solution-immersion process. Superhydrophobic surfaces are conventionally prepared employing two steps: roughening a surface and lowering its surface energy. The fabrication of superhydrophobic cupric stearate surface is reported using a one-step process by immersing a zinc plate coated with copper into the stearic acid solution, simplifying the complexity of two different steps involved in the conventional methods. The surface of the zinc plate coated with copper is found to be covered with low surface energy cupric stearate film providing the water contact angle of 160 ± 1° with the rolling off properties. In addition, the damaged superhydrophobic surface can restore superhydrophobicity property by immersing the surface into the stearic acid solution again.     

球－盘微动摩擦件磨损体积的测量与计算

一般地说，由于微动磨损量很小，测定非常困难，所得结果的误差通常都相当大．尽管几十年来人们对微动磨损进行了好些研究，然而至今却还没有建立起统一而完善的微动磨损量的测量和计算方法，以至很难对试验结果进行定量比较．因此，根据ＳＲＶ微动磨损试验机的工作原理，利用几何和数学分析手段提出了一种能够比较精确地测量和计算球－盘接触型微动摩擦件磨损量的方法，并且利用不同的模型对计算方法进行简化，从而得出了球和盘的磨损体积计算公式。只要借助轮廓仪和读数显微镜测量出有关参数，就可以比较精确地计算出球和盘的微动磨损体积，为了验证这种计算方法的实用性和可靠性，还进行了５２１００钢对不同含钨量的Ｎｉ－Ｗ合金镀层的ＳＲＶ微动磨损试验，测量结果与计算结果具有较好的一致性，由此可见，根据所提计算方法得到的计算结果，不仅可以增强ＳＲＶ试验机测试结果的可比性，也为利用这种试验机深入开展微动磨损研究提供了参照依据。     

Fluorographdiyne: A Metal‐Free Catalyst for Applications in Water Reduction and Oxidation

A highly efficient bifunctional metal‐free catalyst was prepared by growth of three‐dimensional porous fluorographdiyne networks on carbon cloth (p‐FGDY/CC). Our experiments and density functional theory (DFT) calculations show the 3D p‐FGDY/CC network is highly active and it is a high potential metal‐free catalyst for the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), as well as overall water splitting (OWS) under both acidic and alkaline conditions. The experimental and theoretical results show very good consistency; for example, in the HER process, p‐FGDY/CC exhibits small overpotentials of 82 and 92 mV to achieve 10 mA cm^?2 under alkaline and acidic conditions, respectively. This ensures an even higher selectivity for the adsorption/desorption of various O/H intermediate species. The essential key promotion accomplishes a bifunctional H₂O redox performance application under pH‐universal electrochemical conditions.     

Analysis of Chemical Incredients of Angelica Sinnesis——Analysis of Non-Volatile Constituents of Roots

In the present investigation,the non-volatile constituents of Danguei (Tang-Kuei) roots of Gansu origin [Angelica sinensis (Oliv.) Diels] were analyzed and thirty seven organic constituin s were also identified,fifteen of which have not been recorded in literature before,including a new optically active compound named as Angelicide and an antibiotie,Brereldin A.By plasma emission spectrometry,thirteen minor elements were also detecled     

Influence of substrate bias voltage on structure and properties of the CrAlN films deposited by unbalanced magnetron sputtering

The CrAlN films were deposited on silicon and stainless steel substrates by unbalanced magnetron sputtering system. The influence of substrate bias on deposition rate, composition, structure, morphology and properties of the CrAlN films was investigated. The results showed that, with the increase of the substrate bias voltage, the deposition rate decreased accompanied by a change of the preferred orientation of the CrAlN film from (2 2 0) to (2 0 0). The grain size and the average surface roughness of the CrAlN films declined as the bias voltage increases above −100 V. The morphology of the films changed from obviously columnar to dense glass-like structure with the increase of the bias voltage from −50 to −250 V. Meanwhile, the films deposited at moderate bias voltage had better mechanical and tribological properties, while the films deposited at higher bias voltage showed better corrosion resistance. It was found that the corrosion resistance improvement was not only attributed to the low pinhole density of the film, but also to chemical composition of films.