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3-Keto-derivatives of the cardenolides digitoxigenin and cardiogenin were prepared with subsequent conversion to new ketoimines (1–19, 24–44), the oxime (23), and for the first time to pure cardiogenin (14,16-dianhydrogitoxigenin, 20), its acetate (21), and cardiogenone (22). Their physicochemical properties were described.__________Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 42–45, January–February, 2005. 相似文献
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I. F. Makarevich N. V. Kovganko Yu. I. Gubin K. V. Zhernoklev T. V. Slyusarskaya G. N. Yarmolenko 《Chemistry of Natural Compounds》1994,29(5):642-646
17-Strophadogenin, which is 3,5,14,16-tetrahydroxy-19-oxo-5,14-card-17H-20(22)-enolide has been obtained in the pure form for the first time and has been studied.State Scientific Center for Drugs, Khar'kov. Institute of Bioorganic Chemistry, Academy of Sciences of the Republic of Belarus. G. S. Skovorod Khar'kov State Pedagogic Institute. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 724–729, September–October, 1993. 相似文献
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A.A. Koridze P.V. Petrovskii S.P. Gubin V.I. Sokolov A.I. Mokhov 《Journal of organometallic chemistry》1977,136(1):65-71
The 13C NMR spectra ofthe series of α,α’ -dideuterated ferrocenylcarbenium ions and their precursors, ferrocenylcarbinols as well as other ferrocene derivatives have been measured. The structures of ferrocenylcarbenium ions is discussed. 相似文献
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Extraction of phenol- and naphtholsulfonic acids from aqueous salt solutions in the presence of a surfactant, N-cetylpyridinium chloride, with hexane, ethylbenzene, and acetone-diacetone alcohol is studied.__________Translated from Zhurnal Prikladnoi Khimii, Vol. 78, No. 1, 2005, pp. 79–82.Original Russian Text Copyright © 2005 by Korenman, Gubin, Sukhanov. 相似文献
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T. N. Rostovshchikova M. S. Korobov D. A. Pankratov G. Yu. Yurkov S. P. Gubin 《Russian Chemical Bulletin》2005,54(6):1425-1432
Nanosized iron oxides stabilized on the surface of ultradispersed poly(tetrafluoroethylene) (UPTFE) granules were synthesized
by the thermal destruction of iron formate in boiling bed of UPTFE on the surface of heated mineral oil. The particle size
of nanoparticles (∼6 nm) containing 5, 10, and 16 wt.% Fe depends weakly on the temperature of synthesis and iron to polymer
ratio. The metal state is determined by the synthesis conditions. The nanoparticles synthesized at 280 °C consist mainly of
the Fe3O4 and Fe2O3 phases. The samples obtained at 320 °C also contain iron(II) oxide. The catalytic properties of the obtained samples were tested in dichlorobutene isomerization. Unlike isomerization
on the iron oxide nanoparticles supported on silica gel, reaction over the UPTFE supports proceeds without an induction period.
The sample with 10 wt.% Fe containing magnetically ordered γ-Fe2O3 nanoparticles possesses the highest catalytic activity. Fast electron exchange between the iron ions in different oxidation
states and high defectiveness of the nanoparticles contribute, most likely, to the catalytic activity.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1383–1390, June, 2005. 相似文献
8.
M. A. Zaporozhets S. V. Savilov O. M. Zhigalina S. N. Sul’yanov V. V. Volkov V. I. Nikolaichik S. P. Gubin A. S. Avilov 《Crystallography Reports》2012,57(3):426-433
Methods for obtaining cadmium selenide and gold nanoparticles have been developed. The sizes of the nanoparticles are determined and the morphology, structure, and chemical composition of these nanoparticles and their ensembles are studied by a complex of structural methods: electron diffraction, X-ray diffraction, energy-dispersive X-ray analysis, high-resolution transmission electron microscopy, and small-angle X-ray scattering. Gold nanoparticles are mainly spherical and have an average size of 10 nm. They are single-phase and have an fcc crystal structure. Samples of synthesized CdSe nanoparticles contain monodisperse spherical particles 12 nm in size with a wurtzite structure. The deposition of nanoparticles on a carbon substrate is accompanied by their self-organization into a closely packed two-dimensional structure with a pronounced texture in which all nanoparticles are oriented in the [001] direction perpendicularly to the carbon substrate plane. 相似文献
9.
Ya. R. Arustamov P. T. Sukhanov A. S. Gubin Yu. S. Peregudov E. V. Churilina G. V. Shatalov E. V. Koroleva 《Russian Journal of Applied Chemistry》2013,86(8):1292-1297
New cross-linked copolymers based on N-vinylpyrrolidone and N-vinylcaprolactam were proposed for preconcentration of carbaryl and naphthols from aqueous media. The influence of pH, nature of salting-out agent, surfactant, and temperature on the recovery of the analytes was examined. The most efficient sorption systems for recovery of carbaryl and naphthols from aqueous solutions were developed. 相似文献
10.
A. Ya. Shalyapina A. Yu. Solov’eva M. A. Zaporozhets E. M. Khokhlov V. G. Plotnichenko S. V. Savilov A. V. Egorov V. I. Nikolaichik E. Yu. Buslaeva E. G. Rustamova A. S. Avilov S. P. Gubin 《Russian Journal of Inorganic Chemistry》2013,58(3):354-360
Interactions of ZnO nanoparticles with graphene oxide in isopropanol were studied; graphene oxide was shown to perform as an efficient substrate to immobilize zinc oxide nanoparticles on its surface. Interactions of nanocomposites consisting of graphene oxide-zinc oxide nanoparticles with supercritical isopropanol were studied. The conversion of graphene oxide into graphene does not appreciably changes the composition, morphology, or structure of ZnO nanoparticles. 相似文献