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排序方式: 共有129条查询结果,搜索用时 15 毫秒
1.
Najoua Ouerfelli Daniele Mazza Mohamed Faouzi Zid 《Journal of solid state chemistry》2007,180(4):1224-1229
A new solid solution TlFe0.22Al0.78As2O7 has been synthesized by a solid-state reaction. The structure of the title compound has been determined from a single-crystal X-ray diffraction and refined to final values of the reliability factors: R(F2)=0.030 and wR(F2)=0.081 for 1343 independent reflections with I>2σ(I). It crystallizes in the triclinic space group P-1, with a=6.296(2) Å, b=6.397(2) Å, c=8.242(2) Å, α=96.74(2)°, β=103.78(2)°, γ=102.99(3)°, V=309.0(2) Å3 and Z=2. The structure can be described as a three-dimensional framework containing (Fe/Al)O6 octahedra connected through As2O7 groups. The metallic units and diarsenate groups share oxygen corners to form a three-dimensional framework with interconnected tunnels parallel to the a, b and c directions, where Tl+ cations are located. The ionic conductivity measurements are performed on pellets of the polycrystalline powder. At 683 K, The conductivity value is 5.23×10−6 S cm−1 and the ionic jump activation energy is 0.656 eV. The bond valence analysis reveals that the ionic conductivity is ensured by Tl+ along the [001] direction. 相似文献
2.
Amel Souibgui Anne Gaucher Jérôme Marrot Flavien Bourdreux Faouzi Aloui Béchir Ben Hassine Damien Prim 《Tetrahedron》2014
New series of acridines and phenanthrolines have been prepared from β-chlorovinyl aldehydes and various aniline derivatives allowing the installation of valuable substituents, such as ketone, nitro or amino groups at the heterocyclic core. X-ray analyses confirmed the structures of acridines and phenanthrolines as well as the presence of partially hydrogenated rings and their crucial impact on the overall shape of the acridine-based architectures. 1H NMR revealed the helical behaviour of several acridine motives. Comparison of UV data between architectures and influence of number of partially hydrogenated rings is also described. 相似文献
3.
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5.
NaAgPbP2O7 was prepared with a solid-state reaction. The electrical properties were investigated by using impedance measurements in
the frequency range from 200 Hz to 5 MHz with the TEGAM 3550 ALF automatic bridge monitored by a microcomputer between 581 K
and 703 K. The Z′ and Z″ versus frequency plots are well fitted to an equivalent circuit model. The conductivity data obey the universal power law.
The conductivity in the material is due to the hopping of monovalent ions parallel to (001) plane. 相似文献
6.
Nabil Smichi Ahmed Fendri Raja Chaabouni Faouzi Ben Rebah Youssef Gargouri Nabil Miled 《Applied biochemistry and biotechnology》2010,162(5):1483-1496
A lipolytic activity was located in the sardine digestive glands (pyloric caeca), from which a sardine digestive lipase (SaDL)
was purified. Pure SaDL has a molecular mass of 43 kDa as determined by sodium dodecyl sulfate polyacrylamide gel electrophoresis
analysis. The enzyme was found to be more active on short-chain triacylglycerols than on long-chain ones. SaDL does not present
the interfacial activation phenomenon. Control experiments were performed under the same experimental conditions, with dromedary
and turkey pancreatic lipases and showed a positive interfacial activation phenomenon. Sodium deoxycholate (NaDC) has an inhibitory
effect on the lipase activity. The pure enzyme lost 40% of its activity in presence of 8 mM NaDC. SaDL was found to be mostly
stable at low pH values. Interestingly, no colipase was detected in the sardine pyloric caeca. Analogous results were reported
for the scorpion and the crab digestive systems. This is in line with the idea that colipase might has evolved in mammal animals
simultaneously with the appearance of an exocrine pancreas. No similarity was found between the NH2-terminal amino acid residues of SaDL and those of lipases from the digestive tract of other species. Altogether, these results
suggest that SaDL is a member of a new group of lipases belonging to aquatic species. 相似文献
7.
Mabrouk Khelifi Imen Mkaouar Faouzi Hlel Abdelhamid Ben Salah Ridha Zouari 《Ionics》2010,16(8):709-715
The crystal structure of (C5N2H7)4.HBi2Cl11 has been determined at room temperature by single crystal X-ray diffraction. The compound crystallizes in the triclinic system with Pī space group. The crystal structure consists of two asymmetric inequivalent molecules of 4-aminopyridinium and anionic HBi2Cl11 chains. The HBi2Cl11 anionic chains stacked along the a-axis are formed with Bi2Cl11 dimers connected to each other via hydrogen atoms. The crystal packing is stabilized with N–H...Cl hydrogen bonds connecting aminopyridinium units to the HBi2Cl11 anionic chains. The title compound exhibits an order–disorder phase transition at 338 K. The AC electrical conductivity properties of (C5N2H7)4.HBi2Cl11 compound have been investigated by means of impedance spectroscopy measurements over wide ranges of frequencies and temperatures, 200 Hz to 5 MHz and 303 to 418 K, respectively. Detailed analysis of the impedance spectrum suggests that the electrical properties of the material are strongly temperature dependent. The frequency-dependent conductivity data were fitted in the Jonscher's law: $ \sigma \left( \omega \right) = \sigma (0) + A{\omega^n} $ . The nature of variation of DC conductivity suggests Arrhenius type of electrical conductivity. 相似文献
8.
Ayari Faouzi Mannei Emna Asedegbega-Nieto Esther Mhamdi Mourad Guerrero-Ruiz Antonio Ricardo Delahay Gérard Ghorbel Abdelhamid 《Journal of Thermal Analysis and Calorimetry》2018,131(2):1295-1306
Journal of Thermal Analysis and Calorimetry - Thermal decomposition (2 K min?1) of ammonium heptamolybdate tetrahydrate, performed between room temperature and... 相似文献
9.
Kamel Landolsi Najoua Belhadj Mbarek Elmkacher Taha Guerfel Faouzi Bouachir 《Comptes Rendus Chimie》2008,11(6-7):752-758
The reaction of benzoylacetone with ortho-substituted aniline derivatives gives the unsymmetrical β-iminoamine ligands (5–8) with high yields. A convenient synthesis is described. These compounds have been characterized by NMR and IR spectroscopies. The structure of the β-iminoamine 5, 3-N-(2,6-diisopropylphenylamino)-1-phenyl-1N-(2,6-diisopropylphenylimino)but-2-ene, was solved by X-ray diffraction methods. 相似文献
10.
Ben Rebah F Smaoui S Frikha F Gargouri Y Miled N 《Applied biochemistry and biotechnology》2008,151(1):71-79
The lipase inhibitory activity of ethanol extracts obtained from some marine algae collected on the Tunisian coast was evaluated.
Caulerpa prolifera extract markedly reduced both dog gastric (DGL) and human pancreatic lipase (HPL) activities. Generally, the inhibition reached
100% after 40 to 60 min of incubation depending on lipase types and on substrates used. Moreover, the inhibitory effect of
C. prolifera extract on lipases appeared to be accelerated by adding bile salts, which likely modified the interface and allowed the inhibitory
compound to inactivate the lipase. The separation of C. prolifera extract by thin-layer chromatography (TLC) resulted in eight fractions showing efficient inhibition rate against DGL, compared
to the crude extract. In the case of HPL, TLC fractionation reduced the inhibitory rates, suggesting that the effect of algal
extract on lipases may be caused by a synergetic action of several compounds within the extract. High-performance liquid chromatograph
separation resulted in isolation of a major compound displaying high inhibition capacity of HPL activity. Caulerpa prolifera extract may therefore be useful in developing antiobesity drugs. 相似文献