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A new metal-organic coordination polymer,[Ce(L 1)(L 2)(H 2 O)]·2H 2 O (1,H 2 L 1=2,6-dimethylpyridine-3,5-dicarboxylic acid,H 2 L 2=(E)-2,6-dimethyl-4-styrylpyridine-3,5-dicer-boxylic acid),has been synthesized and characterized by elemental analysis,IR,and X-ray single-crystal diffraction.Compound 1 crystallizes in triclinic,space group P1 and displays a two-dimensional coordination network structure.In 1,the relatively rare crossed ladders cons-tructed by mixed ligands organize a 2-D grid with the topology of (4 2 6) 2 (4 8 6 6 8),and the layers further build up a 3-D supramolecular architecture via interlaminar hydrogen bonds. 相似文献
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线激光束均匀化整形方法研究 总被引:4,自引:0,他引:4
为解决核物理工程、表面热处理、激光加工、激光通信中传输激光束的均匀性问题,提出采用三角楔柱透镜改善线激光均匀性的新方法,并在ZEMAX开发环境下建立了整形光路系统的理论模型。利用所建立的模型,分析了整形柱透镜在不同半径、斜面夹角、透镜介质折射率等参数下光束的均匀性。研究表明:在远场条件下,通过改变整形柱透镜的参数,能够得到能量分布均匀的线激光。在实际应用中,可以采用1个半圆柱和2个相同三角楔胶合成型的简单工艺。进一步模拟发现,两种整形系统所得到的均匀度和线宽一致。 相似文献
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本文在连续膜假设条件下,建立了新的能描述吊索变形和松弛影响的悬索桥横向振动非线性偏微分方程组.该方程组的不等式定解条件反映出吊索松弛与否情况.在假设吊索不松弛的条件下,对上述方程组进行简化后得到一组只含双侧约束的非线性偏微分方程组.此方程组的定解条件是用等式表示的双侧约束条件.通过Galerkin方法把双侧约束的偏微分方程组离散为时域上非线性常微分方程组.用多尺度法求得了非线性常微分方程组非共振情况下的一次近似解析解.通过比较数值解和解析解发现,解析解有良好的精度.同时数值和解析的结果指出,在非共振情况下悬索桥的加劲梁和主缆的振幅都是有限值并正比于激励的幅值. 相似文献
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A novel metal-organic coordination polymer,[Pb2(NO3)3(Hmppdc)(CH3OH)2]n(1,H2mppdc=2,6-dimethyl-4-phenylpyridine-3,5-dicarboxylic acid),was synthesized from the reaction of H2mppdc,Pb(NO3)2 and CH3OH under solvothermal conditions.X-ray single-crystal diffraction reveals that 1 crystallizes in monoclinic,space group P21/n,with a=10.9883(13),b=7.3603(10),c=31.165(3),β=96.918(2),V=2502.2(5)3,Z=4,Mr=934.75,Dc=2.481 Mg/m3,F(000)=1736,the final R=0.0676 and wR=0.1310(I2σ(I)).Compound 1 contains two distinct 1-D polynuclear metal-oxygen chains((PbO5)n and(PbO6)n),which are bridged by ligands to build up 2-D metal-organic layers,and such layers are further connected to form a 3-D supramolecular network.The new compound exhibits strong photoluminescence in the solid state at room temperature. 相似文献
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A new metal-organic coordination polymer [Pb(mfpdc)(CH3OH)]n (1, mfpdc=2,6-dimethyl-4-(2-furanyl) pyridine-3,5-dicarboxylate) was synthesized and characterized by single-crystal X-ray analyses. The crystal is orthorhombic, space group Pbca, a=15.6297(18), b=9.4803(11), c=18.598(2), V=2755.8(6)3 , Z=8, Mr=498.44, Dc=2.403 Mg/m3 , F(000)=1872, the final R=0.0275 and wR=0.0726 (I>2 (I)). There are interesting polynuclear zigzag (PbO5 ) n chains in the structure of 1, and there have interesting axially chiral S-and R-unit Pb4L units constructed from prochiral organic ligands through C-H···O bonding. The (R/S)-Pb4L units by sharing Pb centers generate a 2-D coordination network, in which there exist rare π65 ···Pb(3.2610 ) interactions. The solid-state photoluminescent emission of compound 1 appears at 487 nm. 相似文献
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One-pot solvothermal reaction of transition metal Cd(Ⅱ) salt with (2E,2’E)-3,3’-((propane-1,3-diylbis(oxy))bis(2,1-phenylene))diacrylic acid (H2ppa) and 1,10-phenanthroline (phen) generates a meso-helicate, [Cd(ppa)(phen)(H2O)]2, and characterized by single-crystal X-ray diffraction, elemental analyses, IR spectroscopy, and photoluminescent property. The complex crys-tallizes in monoclinic, space group P21/c with a = 13.4622(7), b = 24.8452(12), c = 8.9314(4) , β = 97.564(1)o, V = 2961.3(2) 3, C66H56N4O14Cd2, Mr = 1353.97, Dc = 1.518 g/cm3, μ(MoKα) = 0.789 mm-1, F(000) = 1376, Z = 2 , the final R = 0.0248 and wR = 0.0667 for 4673 observed reflections (I > 2σ(I)). The 1-D supramolecular chain is built up from the complex by π-π stacking interactions, and inter-chain hydrogen bonds prompt the 1-D chains into a 2-D layer. The title compound shows strong photoluminescence with emission maximum at λ = 445 nm upon λEx, max = 240 nm. 相似文献
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