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The solid-liquid interface motion of NaBi(WO4)2 (NBWO) melt crystal growth is observed in an in situ system, in which the whole processes of interface transition from fiat interface and cellular to dendrite are visualized. The spacing of the dendrite under smaller temperature gradient turns out to be larger than that under larger temperature gradient, which is found to be sensitive to the temperature distribution. The mechanism of dendrite growth of NBWO is studied based on the model of the growth units of anion coordination polyhedra. The { 001} face has two apex links, so it shows higher stability and has high growth rate and forms the arm of dendrite, whereas the {010} face has only one apex link, and thus shows relative slower growth rate and firstly forms the branches. 相似文献
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In Situ Observation of Skeletal Shape Transition during BaB2O4 Crystal Growth in High-Temperature Solution 下载免费PDF全文
The transition from a fiat solid-liquid interface to a skeletal shape during BaB2O4 (BBO) single crystal growth in Li2B4O7 flux is observed in real time by an optical high-temperature in-situ observation system. The movement of crystal step is also investigated. The observation results demonstrate that the steps propagate along and parallel to the fiat interface when the crystal size is small. Nevertheless, they will ‘bend' close to the face centre if the crystal size becomes greater. Atomic force microscopy reveals that more deposition places near the face centre give rise to the bending of advancing steps and thus the formation of a vicinal interface structure. Measurements of step velocity show that the velocity keeps nearly constant at different moments for one specific step, whereas the step on a newly formed layer advanced faster than that on a previously formed one when the crystal size is larger than 210μm or so. Thus interracial morphological instability occurs and a skeletal interface is obtained. 相似文献
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The formation of macrostep during high-temperature phase of barium meta-borate (α-BaB 2 O 4) single crystal growth has been investigated by both optical in-situ observation system and atomic force microscopy (AFM).The insitu observation results demonstrate that the critical linear size of growing facet exceeding the size that the macrostep generates is significantly anisotropic.The critical linear sizes are around 280 μm and 620 μm for {1010} and {1010} planes,respectively.AFM study illustrates that macrostep train with a height of 150 nm~200 nm is one typical morphological feature of the as-grown crystal surface.The riser of each macrostep consists of several straight and parallel sub-steps,indicating the occurrence of step bunching.Additionally,triangular sub-steps with heights of several nanometers on the treads of the macrosteps are found to be another typical feature of surface morphology,which implies a microscopically competitive bunching of sub-steps between various crystallographic orientations. 相似文献
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微重力条件下晶体生长过程的实时观察 总被引:1,自引:0,他引:1
从材料科学的微重力效应和晶体生长基本过程等两个方面出发,阐明了一种新的生长技术(晶体生长过程的光学实时观察法)的必要性,并介绍了空间高温实时观察装置的基本特性.在我国的科学技术探测卫星上,该装置进行了搭载实验,并首次清楚地观察到了空间溶质扩散效应和高温溶液的表面张力对流图像. 相似文献
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通过光学实时观察法研究了轴向振动对恒温圆柱形容器内液体自由表面流动行为的影响。该地面实验是在一个频率为100赫兹的电磁振动台上进行的,水-甘油的混合溶液作为模型体系。结果发现,小于100mm的振动振幅能够使自由表面产生稳定的流动。这种流动主要是由沿自由表面传播的毛细波与斯托克斯边界层效应的共同作用驱动的。随着振动振幅的变化,稳态流会呈现不同的流动花样。高振幅作用下,稳态流动趋向于周期性流甚至成为湍流,这个过程可以通过临界无量纲雷诺数(Nre)c来表征,实验中得到的(Nre)c值在10-2 ~ 10-1范围内。此外,利用示踪粒子散射技术对自由表面的流动速度进行了测量,结果显示流速随粘度的增大而减小,并且随振幅的增加呈抛物线形增长。 相似文献
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Numerical Modelling of Velocity and Temperature Distributions of the Buoyancy Convection Effect in KNbO3 Melt 下载免费PDF全文
Numerical Modelling of velocity and temperature fields in high-temperature KNbO3 melt of a loop-shaped Pt wire heater is carried out by using the commercial computational code ANSYS for the mathematical solution of the governing equations.Based on the experimental boundary conditions and the Boussinesq approximation,the numerical modelling of a steady and two-dimensional model is applied to study the process under consideration of the buoyancy-driven convection condition.The result is compared with the previous experimental and theoretical data obtained in our laboratory,and the former is in agreement with the latter.Thus a theoretical guide for reasonable growth conditions is provided by studying in depth the real fluid flow effects in the crystal growth from the melt. 相似文献
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