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Solvothermal Synthesis and Structure Characterization of a 3D Hydrogen-bonded Copper Compound [Cu(H_2dhpmc)_2]·2H_2O 总被引:2,自引:0,他引:2
1 INTRODUCTION The controlled assembly of inorganic and coordination polymers from simple building blocks is an important challenge in the design of high- dimensionality systems. In the crystal engineering 'toolbox'[1], hydrogen bonding moieties are perhaps the implements used the most in the design of such supramolecular systems[2], and have been particularly strongly applied towards the synthesis of molecular magnetic materials[3~6]. Copper complexes play an important role in catalyzin… 相似文献
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以巫山县为研究区域,运用GIS技术,以乡镇和行政村为节点单元,采用公路网密度、乡镇间直达性指数、乡镇内直达性指数、居民点道路临近性、乡镇间节点可达性指数、乡镇内节点可达性指数、干线衔接距离、地形位指数8项指标,引入熵权-TOPSIS模型,综合分析和评价巫山县乡村地区公路网通达性及其空间分布格局。研究表明,各项指标对巫山县乡村公路网的影响程度由高到低为:公路网密度>地形位指数>干线衔接距离>居民点临近性>乡镇内直达性指数>乡镇间节点可达性指数>乡镇内节点可达性指数>乡镇间直达性指数;除中心城区外,各乡镇贴近度为0.170 0>0.831 9,区域差异明显,其中铜鼓最高,当阳最低;整体上,巫山县乡村公路通达性以中等、较好等级为主,通达性空间格局总体以铜鼓、建平、三溪为核往外围扩散,与交通干线骨架吻合度较高,呈现“三核、一环、一域”的空间格局。研究成果对巫山县山区乡村公路网建设和优化有一定的指导作用,在一定程度上完善了乡村地区公路网通达性分析和评价方法。 相似文献
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1 INTRODUCTION Studies on the system comprising ions with un-quenched orbital angular moment have been ofinterest for many years in the design of new mole-cular magnetic materials[1~5], among which thecompounds of cobalt (II) ions are especially attrac… 相似文献
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以巫山县为研究区域,运用GIS技术,以乡镇和行政村为节点单元,采用公路网密度、乡镇间直达性指数、乡镇内直达性指数、居民点道路临近性、乡镇间节点可达性指数、乡镇内节点可达性指数、干线衔接距离、地形位指数8项指标,引入熵权-TOPSIS模型,综合分析和评价巫山县乡村地区公路网通达性及其空间分布格局。研究表明,各项指标对巫山县乡村公路网的影响程度由高到低为:公路网密度>地形位指数>干线衔接距离>居民点临近性>乡镇内直达性指数>乡镇间节点可达性指数>乡镇内节点可达性指数>乡镇间直达性指数;除中心城区外,各乡镇贴近度为0.170 0>0.831 9,区域差异明显,其中铜鼓最高,当阳最低;整体上,巫山县乡村公路通达性以中等、较好等级为主,通达性空间格局总体以铜鼓、建平、三溪为核往外围扩散,与交通干线骨架吻合度较高,呈现“三核、一环、一域”的空间格局。研究成果对巫山县山区乡村公路网建设和优化有一定的指导作用,在一定程度上完善了乡村地区公路网通达性分析和评价方法。 相似文献
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A new organic-inorganic hybrid noncentrosymmetric potassium bis(malic acid)-borates KB(L-(-)-C_4H_4O_5)_2·H_2O was synthesized by solution method. It was characterized by elemental analysis, FT-IR, TGA and single-crystal X-ray crystallography. It crystallizes in the monoclinic space group P2_(1/c) with a = 5.546(6), b = 11.985(13), c = 9.952(11) ?, β = 97.522(17)°, V = 655.8(13) ?~3, Z = 2, D_c = 1.682 g/cm~3, μ(MoKa) = 0.46 mm~(–1) and F(000) = 340. 5009 reflections were measured and 2893 independent reflections(R_(int) = 0.051) were used for further refinement. Single-crystal X-ray diffraction reveals that the complex exhibits a threedimensional pseudo tunnel structure consisting of fundamental building block [B(L-(-)-C_4H_4O_5)_2]~– anions. The small cavities are occupied by the H_2O molecules, which stabilize the whole structure by O–H×××O hydrogen bonds. The complex exhibits nonlinear optical effect as high as 1.5 times that of KDP standard. 相似文献
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IntroductionDesignandsynthesesofnovelsupramolecularcom plexeswithunusualandtailorablestructuresarefunda mentalstepsindiscoveryandfabricationofvarioustech nologicallyusefulfunctionalsupramoleculardevices .1 3Recently ,considerableeffortshavebeendevotedtocr… 相似文献
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1INTRODUCTIONCrystalengineeringofone-,two-andthree-dimensionalsupramolecularcomplexesiscurrentlyofgreatinterestowingtothefascinatingstructuraldiversityandpotentialapplicationsinmaterials,suchaselectricconductivity,magnetism,host-guestapplication,molecularrecognitionandcatalysis[1,2].Severaltypesofinteractions,suchascoordinationcovalentbond,hydrogenbond,p-pstackingandelectrostaticinteractionscanbeusedtoconstructextendedsupramolecularframeworks[3~6],butcoordinationbondingandhydrogenbondingin… 相似文献
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The title compound {[Cu4(OH)4(2,2'-bpy)4(bqdc)]·2ClO4}n 1 (bqdc = 2,2'-biquino- line-4,4'-dicarboxylic acid) has been synthesized by hydrothermal method. Its crystal structure is of triclinic, space group P1 with a = 7.6561(5), b = 12.4652(8), c = 15.7501(10) , α = 80.0480(10), β = 87.7900(10), γ = 74.0800(1)o, V = 1423.65(16) 3, Z = 2, C30H23ClN5O8Cu2, Mr = 744.06, Dc = 1.736 g/cm3, μ = 1.651 mm─1, F(000) = 754, the final R = 0.0421 and wR = 0.1163 for 4973 observed reflections with I > 2σ(I). In 1, tetra-copper chair-like clusters of [Cu4(OH)4(2,2'-bpy)4]4+ are connected by bqdc ligands to form one-dimensional chains, which are further connected by hydrogen bonds to generate a two-dimensional supramolecular network . 相似文献
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SO_4~(2-)/TiO_2、PO_4~(3-)/TiO_2、BO_3~(3-)/TiO_2系列固体酸的酸性、结构和晶相的研究 总被引:1,自引:0,他引:1
制备了SO42-/TiO2(Ⅰ)、PO43-/TiO2(Ⅱ)、BO33-/TiO2(Ⅲ)系列固体酸。用IR、Raman光谱对该系列固体酸进行结构表征,结果表明SO42-与TiO2表面的结合为螯合式双配位结构和共价硫酸盐共存,PO43-与TiO2表面的结合为桥式三配位结构,BO33-与TiO2表面的结合为单齿单配位结构和螯桥混合式三配位结构共存。用由溶液中正丁胺的吸附等温线测定固体表面酸度的方法测定了样品的酸量,结果表明酸量大小为Ⅰ>Ⅱ>Ⅲ。用XRD技术对该系列固体酸进行考察,衍射图分析提示该系列固体酸主要都为锐钛矿型晶型,但Ⅰ、Ⅱ、Ⅲ中又各自夹杂其它不同的晶型 相似文献