铜负载量对LNT催化剂CuO-K2CO3/TiO2结构与性能的影响

采用连续浸渍法制备了一系列非贵金属稀燃NO_x阱(LNT)催化剂CuO-K₂CO₃/TiO₂,考察了Cu负载量对催化剂结构和NO_x储存还原性能的影响.发现8% (w) CuO-K₂CO₃/TiO₂催化剂的催化性能最佳,其对NO_x的储存量达到1.559 mmol·g^-1,对NO_x的还原效率高达99%,且在NO_x还原过程中无副产物N₂O产生.应用粉末X射线衍射(XRD),高分辩透射电子显微镜(HR-TEM), CO₂程序升温脱附(CO₂-TPD),扩展X射线吸收精细结构(EXAFS),氢气程序升温还原(H₂-TPR)和原位漫反射红外光谱(in-situ DRIFTS)等技术详细表征了催化剂的结构.结果表明,不同Cu负载量的催化剂中,铜物种均主要以CuO相存在.铜的负载量直接影响铜物种、钾物种的存在状态,高分散的CuO相与表面K₂CO₃之间存在较强相互作用,这种相互作用不仅有利于NO_x的储存,而且有利于增强催化剂的稳定性. in-situ DRIFTS结果表明, NO_x储存过程中产生的两个负峰(1436和1563 cm^-1)缘于碳酸盐的分解,这间接证明了碳酸盐作为储存介质参与到NO_x储存反应中. EXAFS结果表明,经过15个稀燃/富燃循环测试,催化剂中的CuO相仍保持稳定.基于以上表征结果,提出了CuO和K₂CO₃在催化剂表面的分布模型,并探讨了NO_x储存还原的可能机理.     

K促进的纳米片状水滑石衍生CoAlO金属氧化物催化碳烟燃烧

采用水热法合成了负载K的纳米片状水滑石衍生CoAlO金属氧化物,其表现出优异的催化碳烟燃烧活性.氢气-程序升温还原（H₂-TPR）实验结果表明,K与Co之间的相互作用提高了催化剂的氧化还原性能.X射线光电子能谱（XPS）分析结果表明,K的负载增大了表面Co²⁺/Co³⁺的比例,促进了氧空位的产生,提高了催化剂对气相氧的吸附能力.碳烟-程序升温还原（Soot-TPR）实验结果表明,K的负载增加了表面吸附氧数量.动力学实验结果表明,K的负载增加了单位质量催化剂上的活性氧数量、反应速率和转化频率（TOF）,从而提高了催化剂的本征活性.另外,碳烟颗粒可以分散在纳米片的层间,与活性位点的接触效率得到提高,也有利于提高催化碳烟燃烧活性.     

Investigations of ionization-induced injection of laser wake field acceleration using phenomenological model

We develop a phenomenological model to investigate dynamics of ionization-induced injection. In the ＂bubble＂ regime of laser wakefield acceleration （LWFA）, it is found that there is an upper limit for laser intensity of ionization-induced injection. In the plane perpendicular to the laser polarization, when the laser pulse is linearly polarized, ionization-induced injected electrons exhibit a filamented structure and semi-coherent betatron oscillation.     

关于椭圆曲线E_D:y~2=x~3-D~2x的BSD猜想

本文证明了形如ｙ~２＝ｘ~３－ｐ-１~２…ｐ-ｎ~２ｘ的一类椭圆曲线的Ⅲ群２-分支在一定条件下同构于 Ｚ／２Ｚ × Ｚ／２Ｚ,其阶为 ４,与Ｌ函数部分的相应结果和 Ｒｕｂｉｎ Ｋ．关于有复乘的椭圆曲线的重要结果一起,我们知道ＢＳＤ猜想对本文定理中的椭圆曲线成立．     

数控裁剪机切割刀壳体振动噪声预测分析

高频往复式切割刀是柔性材料数控裁剪机的核心部件.该文对切割刀壳体的振动噪声改进措施进行研究.首先对切割刀进行刚体动力学分析,获取其所受动载荷情况,并通过数值计算验证了切割刀刚体动力学模型的可靠性.其次,基于有限元法获取切割刀壳体模态特性,并通过锤击激振实验验证了有限元模型的准确性.然后基于模态仿真结果进行谐响应分析,将...     

Influence of laser mode on splitting beam illumination effect of Dammann grating

The influences of various laser modes on the splitting beam effect of Dammann grating are studied in theory and by numerical simulation. The results show that fundamental mode laser resembles plane wave while high order mode laser differs from plane wave in the splitting beam effect by Dammann grating. Therefore, the fundamental mode laser is more suitable to be the light source to improve the energy efficiency in far-distance image detecting systems, such as laser image ladar, which use Dammann grating in the ilhlmination svstem.     

Nb/Al-AlOx/Nb junctions with controllable critical current density for qubit application

Nb/Al-AlOx/Nb tunnel junctions with controllable critical current density Jc are fabricated using the standard selective Nb etching process.Tunnel barriers are formed in different oxygen exposure conditions (oxygen pressure P and oxidation time t),giving rise to Jc ranging from 100 A/cm2 to above 2000 A/cm2.Jc shows a familiar linear dependence on P × t in logarithmic scales.We calculate the energy levels of the phaseand flux-type qubits using the achievable junction parameters and show that the fabricated Nb/Al-AlOx/Nb tunnel junctions can be used conveniently for quantum computation applications in the future.     

A new nonlinear oscillator with infinite number of coexisting hidden and self-excited attractors

In this paper,we introduce a new two-dimensional nonlinear oscillator with an infinite number of coexisting limit cycles.These limit cycles form a layer-by-layer structure which is very unusual.Forty percent of these limit cycles are self-excited attractors while sixty percent of them are hidden attractors.Changing this new system to its forced version,we introduce a new chaotic system with an infinite number of coexisting strange attractors.We implement this system through field programmable gate arrays.     

Co掺杂对钙钛矿锰氧化物La0.8Sr0.2MnO3磁性的影响

采用传统的高温固相反应法制备La0.8Sr0.2Mn1-xCoxO3（x=0,0.1）系列多晶样品,采用X射线衍射（XRD）测量样品的结构,并用物性测量系统（PPMS）探究样品的磁化强度随温度的变化曲线（M-T）,以及在不同的温度下磁化强度随外加磁场的变化曲线（M-H）。结果表明：当温度高于TG时,样品呈现出纯顺磁态,当TG相似文献   

Fabrication of rhenium Josephson junctions

Rhenium is a superconductor with a relatively weak tendency to oxidize, which is advantageous in superconducting quantum circuit and qubit applications. In this work, Re/A1-A1Ox/Re Josephson tunnel junctions were fabricated using a selective film-etching process similar to that developed in Nb trilayer technology. The Re films had a superconducting transition temperature of 4.8 K and a transition width of 0.2 K. The junctions were found to be highly reproducible using the fabrication process and their characteristics had good quality with a low leakage current and showed a superconducting gap of 0.55 meV.