双核磺化酞菁铜(Ⅱ)催化氧化α-萘酚

本文研究了以乙醇为溶剂,CaCl_2为助催化剂,双核磺化酞菁铜(Ⅱ)催化氧化α-萘酚制备α-萘醌的各种因素。提出了可能的反应机理。     

半球蓝宝石整流罩制造技术研究

整流罩在高速飞行中既要对空气进行整流,同时又起光学窗口的作用。蓝宝石材料硬度高,加工非常困难。分别从精磨模、精磨磨料、抛光膜层、抛光辅料、机床速度和压力等方面介绍了一种加工蓝宝石整流罩的工艺方法。     

离轴三反红外双波段景象模拟器光学系统设计

 针对红外双波段成像系统性能测试与评估的应用需求,设计了3 μm～5 μm和8 μm～12 μm红外双波段视景仿真用离轴三反光学系统。在共轴三反光学系统成像理论基础上,分析了孔径光栏远离主镜的离轴三反系统像差特性,研究了大出瞳距、大相对孔径条件下离轴三反光学系统的结构设计和像差平衡方法。系统焦距为330 mm,F#为3,视场为6°×4.5°,出瞳距为750 mm,在空间频率10 lp/mm 处,中波红外MTF>0.65,长波红外MTF>0.4,接近衍射极限。具有大视场、大出瞳距、高分辨率、结构紧凑等特点。     

Degradation behavior of electrical properties of GaInAs (1.0 eV) and GaInAs (0.7 eV) sub-cells of IMM4J solar cells under1-MeV electron irradiation

In this work the degradation effects of the Ga_(0.7)In_(0.3)As(1.0 eV) and Ga_(0.42)In_(0.58)As(0.7 eV) sub-cells for IMM4J solar cells are investigated after 1-MeV electron irradiation by using spectral response and photoluminescence(PL) signal amplitude analysis, as well as electrical property measurements. The results show that, compared with the electrical properties of traditional single junction(SJ) GaAs(1.41 eV) solar cell, the electrical properties(such as Isc, Voc, and Pmax)of the newly sub-cells degrade similarly as a function of log ?, where ? represents the electron fluence. It is found that the degradation of Voc is much more than that of Isc in the irradiated Ga_(0.42)In_(0.58)As(0.7 eV) cells due to the additional intrinsic layer, leading to more serious damage to the space charge region. However, of the three types of SJ cells with the gap widths of 0.7, 1.0, and 1.4 eV, the electric properties of the Ga_(0.7)In_(0.3)As(1.0 eV) cell decrease largest under each irradiation fluence. Analysis on the spectral response indicates that the Jsc of the Ga_(0.7)In_(0.3)As(1.0 eV) cell also shows the most severe damage. The PL amplitude measurements qualitatively confirm that the degradation of the effective minority carrier life-time(τeff) in the SJ Ga_(0.7)In_(0.3)As cells is more drastic than that of SJ GaAs cells during the irradiation. Thus,the output current of Ga_(0.7)In_(0.3)As sub-cell should be controlled in the irradiated IMM4J cells.     

采用树脂透镜的掌纹图像采集光学系统设计

为了获得高分辨率、高对比度和低畸变的掌纹图像,同时实现系统的轻量化和高性价比,本文基于全反射原理,采用树脂材料设计了一款由6片镜构成双远心光路的掌纹采集光学系统。树脂材料的选用减轻了光学系统的总重量;基于光的全反射原理的系统设计增强了掌纹图像的对比度;选择双远心光学结构,便于对倾斜物面所产生的梯形畸变进行矫正。对所设计光学系统的成像质量分析表明,该系统所有视场的光学传递函数（MTF）在Nyquist频率228 lp/mm处均达0.55以上,畸变〈0.14%。设计的光学系统可以采集120 mm×160 mm的手掌区域,实际手掌面上的分辨率达到500dpi,采集的掌纹图像分辨率达到8.0×106 pixel,满足了实际采集的要求。     

Structural and bonding properties of ScSi_n~-(n=2～6) clusters:photoelectron spectroscopy and density functional calculations

Anion ion photoelectron spectroscopy and density functional theory (DFT) are used to investigate the electronic and structural properties of ScSi_n^- (n=2sim6) clusters and their neutrals. We find that the structures of ScSi_n^- are similar to those of Si_n+1^-. The most stable isomers of ScSi_n^- cluster anions and their neutrals are similar for n=2, 3 and 5 but different for n=4 and 6, indicating that the charge effect on geometry is size dependent for small scandium-silicon clusters. The low electron binding energy (EBE) tails observed in the spectra of ScSi_4,6^- can be explained by the existence of less stable isomers. A comparison between ScSi_n^- and VSi_n^- clusters shows the effects of metal size and electron configuration on cluster geometries.     

共形整流罩像差特性分析及校正方法

共形结构不仅具有良好的空气动力学性能,且不存在由于表面不连续造成的热梯度等问题,因而采用该结构的导弹整流罩更有利于导弹系统作战性能的提高。但共形结构中采用的非球面罩曲面使整流罩表现出许多不同于球形结构的动态特性,这给导引头中光学系统的设计带来很多困难。在分析共形结构一阶特性的基础上,利用矢量像差理论详细分析该结构中初级像差产生的原因及特点,并提出通过控制元件的倾斜和偏心来平衡所有观察视场中像差的方法。软件分析结果表明：加入倾斜偏心元件后可适当放大小观察视场中的像差,共形整流罩在各观察视场中具有较为稳定的像差特性,有效地改善了该结构的成像质量。     

大视场红外导引头光学系统消热差设计

为消除温度变化对共形光学导引头像质的影响,利用光学被动消热差理论对具体设计方法进行实际分析.根据消热差条件选择合理的透镜材料组合,利用衍射元件特殊的光热特性采用折/衍混合结构进行消热差设计.采用椭球形共形整流罩结构减小空气阻力,降低导弹头部气动加热效应,利用三片式反远距结构实现短焦大视场系统设计.该系统工作波段为3～5 μm,系统F/#为2,视场角为±90°;凝视结构的导引头光学系统后工作距达22.8 mm,为制冷型探测器留有足够的空间;冷光阑效率为100％;在-40℃～60℃温度变化范围内,15 lp/mm处全视场MTF值均大于0.4,满足高准确度定位导引头系统对成像质量的要求,保证了系统的轻小型设计.     

基于交比不变性的投影仪标定

提出了一种新的投影仪标定方法以提高数字光栅投影三维测量中投影仪标定的准确性.该方法结合二次投影技术和交比不变性进行投影仪标定.采用二次投影技术解决投射图案与标定板图案互相干扰的问题;采用交比不变性以避免引入相机的标定误差.接着进行了对比实验,以验证所提方法的有效性.选取需要相机参数的传统投影仪标定方法以及根据全局单应性...     

玻壳成型过程诱导残余应力的数值预测

建立了玻壳压制成型固化过程中残余应力预测的数值模拟模型,采用平行平板间玻璃熔体的固化问题来描述成型过程中残余应力形成的机理,并假定材料为热流变简单粘弹性材料．基于板壳理论,将产品视为平板单元的组合,并采用有限元法来求解,这种方法可以象全三维计算一样一层层地计算残余应力,非常适合复杂形状的薄压制成型产品．最后通过实验比较验证了所提出的模型和方法．