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1.
Synthesis,Electronic Properties and WOLED Devices of Planar Phosphorus‐Containing Polycyclic Aromatic Hydrocarbons
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Dr. François Riobé Rózsa Szűcs Dr. Pierre‐Antoine Bouit Dr. Denis Tondelier Bernard Geffroy Fátima Aparicio Julia Buendía Prof. Luis Sánchez Prof. Régis Réau Prof. László Nyulászi Prof. Muriel Hissler 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(17):6547-6556
We describe the synthesis and the physical properties of polyaromatic hydrocarbons (PAHs) containing a phosphorus atom at the edge. In particular, the impact of the successive addition of aromatic rings on the electronic properties was investigated by experimental (UV/Vis absorption, fluorescence, cyclic voltammetry) and theoretical studies (DFT). The physical properties recorded in solution and in the solid state showed that the P‐containing PAHs exhibit properties expected for an emitter in white organic light‐emitting diodes (WOLEDs). 相似文献
2.
Rossella Bartolo Anna Germinario Miguel Sánchez 《Annals of Global Analysis and Geometry》2002,21(1):63-84
In this paper the problem of the geodesic connectedness and convexity ofincomplete Riemannian manifolds is analyzed. To this aim, a detailedstudy of the notion of convexity for the associated Cauchy boundary iscarried out. In particular, under widely discussed hypotheses,we prove the convexity of open domains (whose boundaries may benondifferentiable) of a complete Riemannian manifold. Variationalmethods are mainly used. Examples and applications are provided,including a result for dynamical systems on the existence oftrajectories with fixed energy. 相似文献
3.
J.-F. Pascual-Sánchez A. San Miguel F. Vicente 《General Relativity and Gravitation》2004,36(9):2075-2083
We analyze the geometry of a rotating disk with a tangential acceleration in the framework of the theory of Special Relativity, using the kinematic linear differential system that verifies the relative position vector of time-like curves in a Fermi reference. A numerical integration of these equations for a generic initial value problem is made up and the results are compared with those obtained in other works. 相似文献
4.
Antonio Guirado Enrique LópezSánchez Raquel Andreu Andrés Zapata 《Tetrahedron letters》2004,45(10):2075-2076
The first method for the synthesis of the title compounds has been established involving a stereoselective electrochemical diacylation process. The cathodic reductions of monothiobenzils in an aprotic medium, under constant potential, in the presence of twofold molecular amounts of aroyl chlorides provide previously unknown (Z)-α-benzoyloxy-β-benzoythiostilbenes in high to quantitative yields. 相似文献
5.
In this paper, we apply a three-stage-DEA model to the Spanish Professional Football League, which means separating the teams’
economic behaviour into three components: operating efficiency—of the offence and defence—athletic or operating effectiveness,
and social effectiveness. The results showed that the technical inefficiency of the defence is greater than that of the offence,
both being caused by aspects linked to the poor management of players’ abilities and by the football team’s size. Teams showed
a favourable evolution of their offensive and defensive efficiency during the 2004/2005 season and to a lesser extent in the
season before. The point system assigned by the professional football league regulations evaluates the teams’ athletic effectiveness,
but we detected that the teams with the most experience perform athletically in a more effective manner. Their social effectiveness
is strongly related to the level of play in itself and to factors linked to their PFL ranking: participation in international
competitions for important football teams; or the struggle of minor football teams to stay in the first division. 相似文献
6.
The effects of chemical heat treatments of a semianthracite char (AC) on the composition of the mineral fraction of the material are investigated. The starting char was first treated with a mixture of LiCl/KCl or LiCl/KCl/CaO at 743, 873 or 1173 K and the products obtained were then washed thoroughly with distilled water. A small fraction of these samples were treated with 10−3 M HCl solution. The composition changes were studied by X-ray diffraction. The predominant mineral components initially present in the starting char are quartz, mullite, muscovite and/or kaolinite and oldhamite. The treatments of AC resulted in significant changes in the mineral fraction of the material, in particular when LiCl/KCl/CaO was used. In this case, spurrite, γ-calcium orthosilicate and gehlenite were formed, which were eliminated by treatment with 10−3 M HCl solution. 相似文献
7.
R. Martínez-Snchez J. A. Matutes-Aquino O. Ayala-Valenzuela S. D. De la Torre 《Physica B: Condensed Matter》2002,320(1-4):285-287
An amorphous phase containing traces of non-transformed Co and Ti powders was obtained by mechanical alloying nominal compositions of Co67Ti33 and Co50Ti50 in a high-energy ball-mill. These alloys were prepared from elemental powders of Co and Ti. The heat treatment of Co67Ti33 at 573, 873 and 1173 K crystallized nanoparticles of Co2Ti and Co3Ti compounds, while the same treatments conducted on Co50Ti50 resulted in the formation of Co2Ti and CoTi nanoparticles. The saturation magnetizations reached a maximum value in the amorphous state and they decreased when the temperatures of the heat treatment rose. Demagnetizing interparticle interaction effects were estimated through hysteresis loops and initial magnetization curves using the Fourier technique. 相似文献
8.
In this note we study uncertainty sequencing situations, i.e., one-machine sequencing situations in which no initial order
is specified. We associate cooperative games with these sequencing situations, study their core, and provide links with the
classic sequencing games introduced by Curiel et al. (Eur J Oper Res 40:344–351, 1989). Moreover, we propose and characterize
two simple cost allocation rules for uncertainty sequencing situations with equal processing times. 相似文献
9.
A. Veiga N. Martínez P. Mendoza Zélis G. A. Pasquevich F. H. Sánchez 《Hyperfine Interactions》2006,167(1-3):905-909
A prototype of a programmable constant-velocity scaler is presented. This instrument allows the acquisition of partial Mössbauer spectra in selected energy regions using standard drivers and transducers. It can be fully operated by a remote application, thus data acquisition can be automated. The instrument consists of a programmable counter and a constant-velocity reference. The reference waveform generator is amplitude modulated with 13-bit resolution, and is programmable in a wide range of frequencies and waveforms in order to optimize the performance of the transducer. The counter is compatible with most standard SCA, and is configured as a rate-meter that provides counts per selectable time slice at the programmed velocity. As a demonstration of the instrument applications, a partial Mössbauer spectrum of a natural iron foil was taken. Only positive energies were studied in 512 channels, accumulating 20 s per channel. A line width of 0.20 mm/s was achieved, performing with an efficiency of 80%. 相似文献
10.
F. D. Saccone C. E. Rodrí guez Torres F. H. S nchez O. Gutfleisch 《Physica B: Condensed Matter》2002,320(1-4):312-315
In the present work, a quantitative analysis of the phase compositions by Mössbauer effect spectroscopy of solid and conventional hydrogen disproportionated Pr13.7Fe80.3B6.0 and Pr13.7Fe63.5Co16.7Zr0.1B6.0 alloys was carried out. Significant amounts of intermediate borides t-Fe3B and Pr(Fe, Co)12B6 were detected after solid hydrogen disproportionation treatment in Pr13.7Fe80.3B6.0 and Pr13.7Fe63.5Co16.7Zr0.1B6.0 alloys, respectively. After conventional hydrogenation–disproportionation–desorption–recombination treatment these phases were not detected and in no case residual Pr2Fe14B-phase was found. It was observed that the amount of intermediate borides after disproportionation can be correlated with the degree of texture after recombination at various temperatures. 相似文献