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排序方式: 共有383条查询结果,搜索用时 15 毫秒
1.
A method leading to the preparation of the free base or zinc meso-ethynyl functionalized octaethylporphyrin has been developed, which will open the access to various meso-ethynyl metalloporphyrins. 相似文献
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Lin Jiang Pauline M.G.van Deursen Hadi Arjmandi-Tash Liubov A.Belyaeva Haoyuan Qi Jiao He Vincent Kofman Longfei Wu Valery Muravev Ute Kaiser Harold Linnartz Emiel J.M.Hensen Jan P.Hofmann Grégory F.Schneider 《中国科学:化学(英文版)》2021,(6):1047-1056
Graphene as a two-dimensional material is prone to hydrocarbon contaminations,which can significantly alter its intrinsic electrical properties.Herein,we implem... 相似文献
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Vasconcelos F Cristol S Paul JF Tricot G Amoureux JP Montagne L Mauri F Delevoye L 《Inorganic chemistry》2008,47(16):7327-7337
The assignment of high-field (18.8 T) (17)O MAS and 3QMAS spectra has been completed by use of first-principles calculations for three crystalline sodium phosphates, Na 3P 3O 9, Na 5P 3O 10, and Na 4P 2O 7. In Na 3P 3O 9, the calculated parameters, quadrupolar constant ( C Q), quadrupolar asymmetry (eta Q), and the isotropic chemical shift (delta cs) correspond to those deduced experimentally, and the calculation is mandatory to achieve a complete assignment. For the sodium tripolyphosphate Na 5P 3O 10, the situation is more complex because of the free rotation of the end-chain phosphate groups. The assignment obtained with ab initio calculations can however be confirmed by the (17)O{ (31)P} MAS-J-HMQC spectrum. Na 4P 2O 7 (17)O MAS and 3QMAS spectra show a complex pattern in agreement with the computed NMR parameters, which indicate that all of the oxygens exhibit very similar values. These results are related to structural data to better understand the influence of the oxygen environment on the NMR parameters. The findings are used to interpret those results observed on a binary sodium phosphate glass. 相似文献
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Alberto Palazzolo Sophie Feuillastre Viktor Pfeifer Sbastien Garcia‐Argote Donia Bouzouita Simon Tricard Cline Chollet Elodie Marcon David‐Alexandre Buisson Sophie Cholet Franois Fenaille Guy Lippens Bruno Chaudret Grgory Pieters 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(15):4945-4949
A general approach for the efficient hydrogen‐isotope exchange of nucleobase derivatives is described. Catalyzed by ruthenium nanoparticles, using mild reaction conditions, and involving either D2 or T2 as isotopic sources, this reaction possesses a wide substrate scope and a high solvent tolerability. This novel method facilitates the access to essential diagnostic tools in drug discovery and development: tritiated pharmaceuticals with high specific activities and deuterated oligonucleotides suitable for use as internal standards during LC‐MS quantification. 相似文献
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Dr. Alberto Palazzolo Dr. Timothée Naret Dr. Marion Daniel-Bertrand David-Alexandre Buisson Dr. Simon Tricard Dr. Philippe Lesot Dr. Yannick Coppel Dr. Bruno Chaudret Dr. Sophie Feuillastre Dr. Grégory Pieters 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(47):21065-21070
We report the dramatic impact of the addition of N-heterocyclic carbenes (NHCs) on the reactivity and selectivity of heterogeneous Ru catalysts in the context of C−H activation reactions. Using a simple and robust method, we prepared a series of new air-stable catalysts starting from commercially available Ru on carbon (Ru/C) and differently substituted NHCs. Associated with C−H deuteration processes, depending on Ru/C-NHC ratios, the chemical outcome can be controlled to a large extent. Indeed, tuning the reactivity of the Ru catalyst with NHC enabled: 1) increased chemoselectivity and the regioselectivity for the deuteration of alcohols in organic media; 2) the synthesis of fragile pharmaceutically relevant deuterated heterocycles (azine, purine) that are otherwise completely reduced using unmodified commercial catalysts; 3) the discovery of a novel reactivity for such heterogeneous Ru catalysts, namely the selective C-1 deuteration of aldehydes. 相似文献
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Oxidative Addition of Haloheteroarenes to Palladium(0): Concerted versus SNAr‐Type Mechanism 下载免费PDF全文
Prof. Bert U. W. Maes Dr. Stefan Verbeeck Dr. Tom Verhelst Audrey Ekomié Niklas von Wolff Dr. Guillaume Lefèvre Dr. Emily A. Mitchell Prof. Anny Jutand 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(21):7858-7865
The kinetics of the oxidative additions of haloheteroarenes HetX (X=I, Br, Cl) to [Pd0(PPh3)2] (generated from [Pd0(PPh3)4]) have been investigated in THF and DMF and the rate constants have been determined. In contrast to the generally accepted concerted mechanism, Hammett plots obtained for substituted 2‐halopyridines and solvent effects reveal a reaction mechanism dependent on the halide X of HetX: an unprecedented SNAr‐type mechanism for X=Br or Cl and a classical concerted mechanism for X=I. These results are supported by DFT studies. 相似文献
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We prove the existence of fast traveling pulse solutions in excitable media with non-local coupling. Existence results had been known, until now, in the case of local, diffusive coupling and in the case of a discrete medium, with finite-range, non-local coupling. Our approach replaces methods from geometric singular perturbation theory, that had been crucial in previous existence proofs, by a PDE oriented approach, relying on exponential weights, Fredholm theory, and commutator estimates. 相似文献