全文获取类型
收费全文 | 81篇 |
免费 | 4篇 |
专业分类
化学 | 70篇 |
数学 | 9篇 |
物理学 | 6篇 |
出版年
2023年 | 3篇 |
2022年 | 1篇 |
2021年 | 2篇 |
2018年 | 1篇 |
2016年 | 1篇 |
2014年 | 6篇 |
2013年 | 6篇 |
2012年 | 5篇 |
2011年 | 8篇 |
2010年 | 2篇 |
2008年 | 4篇 |
2007年 | 4篇 |
2006年 | 5篇 |
2005年 | 2篇 |
2004年 | 1篇 |
2003年 | 3篇 |
2002年 | 3篇 |
2001年 | 1篇 |
2000年 | 2篇 |
1999年 | 1篇 |
1994年 | 3篇 |
1992年 | 1篇 |
1989年 | 1篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1976年 | 5篇 |
1975年 | 1篇 |
排序方式: 共有85条查询结果,搜索用时 15 毫秒
1.
2.
3.
Tripathi S Armstrong DS Christy ME Clark JH Gorringe TP Hasinoff MD Kovash MA Wright DH Zołnierczuk PA 《Physical review letters》2002,89(25):252501
We report the first observation of double radiative capture on pionic hydrogen. The experiment was conducted at the TRIUMF cyclotron using the RMC spectrometer and detected gamma-ray coincidences following pi(-) stops in liquid hydrogen. We found the branching ratio for double radiative capture to be [3.05+/-0.27(stat)+/-0.31(syst)]x10(-5). The measured branching ratio and angle-energy distributions support the theoretical prediction of a dominant contribution from the pipi-->gammagamma annihilation mechanism. 相似文献
4.
The 298 K heat of formation for the propionyl cation (C2H5CO+) has been measured previously by dissociative photoionization mass spectrometry. However, recent theoretical and experimental studies involving methylketene suggest that this may be significantly underestimated, resulting in a methylketene proton affinity that is too high by ∼30 kJ mol−1. In this study, the previous m/z 57 appearance energies were carefully re-evaluated, with various possible sources of error being investigated. These include factors such as sample purity, carbon-13 contamination from lower energy m/z 56 processes, kinetic and/or competitive shifts, reverse activation energies, ionizing energy calibration errors and the availability of accurate supplementary thermochemical data. In addition, high-level ab initio calculations are used to model the relevant unimolecular fragmentation processes for each of the ionized precursor molecules. As a result, it is found that only the 2-butanone appearance energy can be used to provide a reliable value for the propionyl cation heat of formation. From the 298 K m/z 57 appearance energy of 10.199 ± 0.003 eV for 2-butanone measured here, a value of 617.8 ± 0.9 kJ mol−1 is derived for , which corresponds to 845.4 ± 4.8 kJ mol−1 for the proton affinity of methylketene. This is in good agreement with previous theoretical calculations and thermokinetic proton affinity measurements, indicating that a significant upward revision to the propionyl cation heat of formation is warranted. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
5.
6.
7.
8.
Prytherch Z Job C Marshall H Oreffo V Foster M BéruBé K 《Macromolecular bioscience》2011,11(11):1467-1477
The respiratory tract is the primary site of exposure to airborne compounds, with the bronchial epithelium providing one of the first lines of defence. A growing need exists for an accurate in vitro model of the bronchial epithelium. Here, normal human bronchial epithelial (NHBE) cells cultured at an air/liquid interface create a fully differentiated, in-vivo-like model of the human bronchial epithelium. Developmental characterisation includes (i) trans-epithelial electrical resistance, (ii) morphology and (iii) bronchial cell specific stains/markers. It is concluded that the basal/progenitor cells create a pseudo-stratified, mucociliary NHBE model containing basal, serous, Clara, goblet and ciliated cells, reflective of the normal human bronchial epithelium (days 24-33 ALI culture). 相似文献
9.
Oxo-15 dihydro-15,20S catharanthine,nouvel intermédiaire dans l'hémisynthèse de l'anhydrovinblastine
15-Oxo-15,20S-dihydrocatharanthine 4a has been converted stereospecifically into 15R-acetoxy-15,20S-dihydrocatharanthine 10a. The coupling reaction of the corresponding Nb-oxide 11 with vindoline 14 afforded the pivotal anti-tumour alkaloid anhydrovinblastine 1. 相似文献
10.
Various β-dicarbonyl compounds can be hydroxylated as their silyl enol ethers by -chloroperbenzoic acid (MCPBA). 相似文献