Densitometric TLC Analysis of Histamine in Fish and Fishery Products

JPC – Journal of Planar Chromatography – Modern TLC - A simple and rapid densitometric thin-layer chromatographic method, suitable for monitoring the histamine content of fish and...     

Crystal growth, defect structure and magnetism of new Li3N-derived lithium nitridocobaltates

New nitridocobaltates Li(3-x-y)Co(x)N are revealed to contain significant Li(+) vacancies (y approximately 0.45) disordered within lithium-nitrogen planes and to exist as partially delocalised spin systems as a result of increased covalency through infinite -N-(Li,Co)-N- chains.     

Arsenic speciation patterns in freshwater fish

Muscle of 16 freshwater fish (9 different species belonging to 4 different families) was analysed for arsenic species using HPLC separation (anion and cation exchange) followed by on-line UV-decomposition, hydride generation and AFS detection. The main arsenic compounds found in the extracts were arsenobetaine (AsB), which accounted for 92–100% of extractable arsenic in species of salmonids (Salmo marmoratus, Oncorhynchus mykiss, Salmo trutta m. fario), and dimethylarsinic acid (DMAA), which accounted for 75% of extractable arsenic in burbot (Lota lota). AsB was also found in lower concentrations in almost all other fish species analysed (Silurus glanis, L. lota, Barbus barbus, Rutilus pigus virgo, Chondrostoma nasus). Arsenite (As(III)) and trimethylarsine oxide (TMAO) were detected in low concentrations in some representatives of Cyprinidae only (R. pigus virgo, C. nasus). Except in salmonids, an unknown cationic compound was present in most of the samples in relatively low concentrations. Cluster analysis of the generated data seems to indicate that there is a correlation between fish family and the arsenic speciation pattern. This is especially clear for the salmonids which show a completely separate cluster and thus a very distinct arsenic speciation pattern.     

Ionic conductivity in the crystalline polymer electrolytes PEO6:LiXF6, X = P,As, Sb

Ionically conducting polymers (salts dissolved in a polymer matrix) are of great interest because they uniquely exhibit ionic conductivity in a soft but solid membrane. As such, they are critical to the development of devices such as all-solid-state lithium batteries. The established view of ionic conductivity in polymer electrolytes is that this occurs in amorphous materials above their glass transition temperature and that crystalline polymer electrolytes are insulators. In contrast, we show that three crystalline polymer electrolytes, poly(ethylene oxide)(6):LiXF(6), X = P, As, Sb, not only conduct but do so better than the analogous amorphous phases! It is also shown that the conductivities of all three 6:1 complexes are similar, consistent with the dimension of the bottlenecks to conduction derived from their crystal structures. An increase in ionic conductivity with reduction of molecular weight of the crystalline polymer electrolyte (from 2000 to 1000) is reported and shown to relate to the increase in crystallite size on reducing molecular weight.     

Hadamard 2-(63,31,15) designs invariant under the dihedral group of order 10

All Hadamard 2-(63,31,15) designs invariant under the dihedral group of order 10 are constructed and classified up to isomorphism together with related Hadamard matrices of order 64. Affine 2-(64,16,5) designs can be obtained from Hadamard 2-(63,31,15) designs having line spreads by Rahilly’s construction [A. Rahilly, On the line structure of designs, Discrete Math. 92 (1991) 291-303]. The parameter set 2-(64,16,5) is one of two known sets when there exists several nonisomorphic designs with the same parameters and p-rank as the design obtained from the points and subspaces of a given dimension in affine geometry AG(n,p^m) (p a prime). It is established that an affine 2-(64,16,5) design of 2-rank 16 that is associated with a Hadamard 2-(63,31,15) design invariant under the dihedral group of order 10 is either isomorphic to the classical design of the points and hyperplanes in AG(3,4), or is one of the two exceptional designs found by Harada, Lam and Tonchev [M. Harada, C. Lam, V.D. Tonchev, Symmetric (4, 4)-nets and generalized Hadamard matrices over groups of order 4, Designs Codes Cryptogr. 34 (2005) 71-87].     

Structure, stoichiometry and transport properties of lithium copper nitride battery materials: combined NMR and powder neutron diffraction studies

A combined NMR and neutron diffraction study has been carried out on three Li(3-x-y)Cu(x)N materials with x=0.17, x=0.29 and x=0.36. Neutron diffraction indicates that the samples retain the P6/mmm space group of the parent Li(3)N with Cu located only on Li(1) sites. The lattice parameters vary smoothly with x in a similar fashion to Li(3-x-y)Ni(x)N, but the Li(2) vacancy concentration for the Cu-substituted materials is negligible. This structural model is confirmed by wideline (7)Li NMR spectra at 193 K which show three different local environments for the Li(1) site, resulting from the substitution of neighbouring Li atoms in the Li(1) layer by Cu. Since the Cu-substituted materials are only very weakly paramagnetic, variable temperature (7)Li wideline NMR spectra can be used to measure diffusion coefficients and activation energies. These indicate anisotropic Li(+) diffusion similar to the parent Li(3)N with transport confined to the [Li(2)N] plane at low temperature and exchange between Li(1) and Li(2) sites dominant at high temperature. For the intra-layer process the diffusion coefficients at room temperature are comparable to Li(3)N and Li(3-x-y) Ni(x)N, while E(a) decreases as x increases in contrast to the opposite trend in Ni-substituted materials. For the inter-layer process E(a) decreases only slightly as x increases, but the diffusion coefficients at room temperature increase rapidly with x.     

Crystal chemistry and electronic structure of the metallic lithium ion conductor, LiNiN

The layered ternary nitride LiNiN shows an interesting combination of fast Li+ ion diffusion and metallic behavior, properties which suggest potential applications as an electrode material in lithium ion batteries. A detailed investigation of the structure and properties of LiNiN using powder neutron diffraction, ab initio calculations, SQUID magnetometry, and solid-state NMR is described. Variable-temperature neutron diffraction demonstrates that LiNiN forms a variant of the parent Li3N structure in which Li+ ion vacancies are ordered within the [LiN] planes and with Ni exclusively occupying interlayer positions (at 280 K: hexagonal space group Pm2, a = 3.74304(5) A, c = 3.52542(6) A, Z = 1). Calculations suggest that LiNiN is a one-dimensional metal, as a result of the mixed pi- and sigma-bonding interactions between Ni and N along the c-axis. Solid-state 7Li NMR spectra are consistent with both fast Li+ motion and metallic behavior.     

Line spreads of PG(5, 2)

All line spreads of PG(5, 2) are constructed and classified up to equivalence by exhaustive generation considering the specific properties of the automorphism group, and the participation of the spread lines in the subspaces of dimension 3. There are 131,044 inequivalent spreads. The orders of the automorphism groups preserving the spreads, and the 2‐ranks of the related by Rahilly's construction affine 2‐(64,16,5) designs are also computed. © 2008 Wiley Periodicals, Inc. J Combin Designs 17: 90–102, 2009