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1.
Kondakov N. N. Mel´nikova T. M. Chekryzhova T. V. Mel´nikova M. V. Zinin A. I. Torgov V. I. Chizhov A. O. Kononov L. O. 《Russian Chemical Bulletin》2015,64(5):1142-1148
Russian Chemical Bulletin - Terminal disaccharide fragment of phenolic glycolipid from Mycobacterium leprae (PGL-I) was synthesized as a glycoside with 4-(2-aminoethoxy)phenyl aglycon. The obtained... 相似文献
2.
3.
A. I. Zinin V. I. Torgov V. N. Shibaev A. S. Shashkov W. J. Broughton 《Russian Chemical Bulletin》1998,47(3):496-501
Trisaccharide analogs of natural nodulation factors fromRhizobium sp. NGR234, namely, 2-acetamido-2-deoxy-4-O-(2-deoxy-2-hexadecanamido-β-d-glucopyranosyl)-6-O-(2-O-methyl-α-l-fucopyranosyl)-d-glucopyranose and its derivatives containing a 4-O-acetyl or a 3-O-sulfo group at thel-fucose residue, were synthesized. The oligosaccharides synthesized were shown to posses biological activity.
Laboratoire de Biologie Moléculaire des Plantes Supérieures (LBMPS), Université de Genève, 1 ch. de l'Impératrice, 1292 Chambesy-Genève,
Suisse.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya No. 3, pp. 513–518, March, 1998. 相似文献
4.
A. V. Vorogushin M. D. Reshetova N. G. Akhmedov Yu. A. Ustynyuk I. L. Eremenko S. E. Nefedov A. I. Zinin 《Russian Chemical Bulletin》1998,47(4):699-703
The reaction of Cr(CO)6 with 7,7-dichloro-3,4-benzobicyclo[4.1.0]heptane gave the correspondingexo- andendo-chromium tricarbonyl complexes in a ratio of 4.5:1. The structures of the resulting compounds were established by NMR spectroscopy,
mass spectrometry, and X-ray structural analysis. Reduction of dichlorobenzobicycloheptane and its chromium tricarbonyl complexes
with LiAlH4 affordedexo- andendo-7-chloro-3,4-benzobicyclo[4.1.0]heptanes in a 3.5:1 ratio.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 720–724, April, 1998. 相似文献
5.
Nikita M. Podvalnyy Alexander I. Zinin Nelly N. Malysheva Roman A. Kunetskiy 《Journal of carbohydrate chemistry》2013,32(5):213-224
A convenient synthesis and separation of α- and β-anomers of methyl (phenyl 3,5-dideoxy-2-thio-5-trifluoroacetamido-D-glycero-D-galacto-nonulopyranosid)onate (6a and 6b) on a multigram scale was developed. Both α- and β-isomers of 6 were obtained as crystals suitable for safe storage. The β-isomer forms a crystalline solvate with methanol. Fully O-trichloroacetylated and O-trifluoroacetylated N-trifluoroacetyl thiosialosides were synthesized in an efficient manner from the β-tetraol 6b. 相似文献
6.
7.
In this paper we present two algorithms for reducing systems of multivariate polynomial equations over the finite field F 2 to the canonical triangular form called lexicographical Gröbner basis. This triangular form is the most appropriate for finding solutions of the system. On the other hand, the system of polynomials over F 2 whose variables also take values in F 2 (Boolean polynomials) completely describes the unitary matrix generated by a quantum circuit. In particular, the matrix itself can be computed by counting the number of solutions (roots) of the associated polynomial system. Thereby, efficient construction of the lexicographical Gröbner bases over F 2 associated with quantum circuits gives a method for computing their circuit matrices that is alternative to the direct numerical method based on linear algebra. We compare our implementation of both algorithms with some other software packages available for computing Gröbner bases over F 2. 相似文献
8.
Industrial sediments of calcium sulfate semihydrate obtained from industrial extraction phosphoric acid and containing 0.3–4.5 wt % of impurity La?Sm are investigated by energy-dispersive X-ray fluorescence analysis (XRFA) and a procedure for the quantitative determination of cerium lanthanides in the sediments is developed. The use of linear regression analysis of X-ray fluorescence spectra of multielement industrial samples and models of individual compounds NaLn(SO4)2 · H2O (cp grade) allowed us to resolve overlaps of spectral L-series lines for La–Sm, eliminate the background, and perform the regression assessment of line intensities of these elements. On this basis, we developed a procedure for the determination of La, Ce, Pr, Nd, and Sm in CaSO4 · 0.5H2O sediments with limits of detection (wt %): 0.022, 0.013, 0.011, 0.008, and 0.008, respectively. In concentration ranges (wt %) La (0.05–0.99), Ce (0.1–4.9), Pr (0.005–0.49), Nd (0.02–0.99), and Sm (0.005-0.19), the relative standard deviation RSD (n = 10, P = 0.95) was 18?27, 9?18, 20?31, 17?26, and 19?31%, respectively. A comparison of the results of XRFA with the data of inductively coupled plasma mass spectrometry confirms the accuracy of the results obtained according to OST (Branch Standard) 41-08-221-04. 相似文献
9.
V. A. Pustovarov B. V. Shul'gin É. I. Zinin A. Yu. Kuznetsov 《Russian Physics Journal》1996,39(11):1102-1113
Luminescence spectroscopy with subnanosecond time resolution is used to study features of nonequilibrium processes excited
in several broad-zone dielectrics (mainly inorganic scintillators) by pulses of synchrotron radiation (SR). When excitation
density exceeds a certain level, which is different for each material, there is an abrupt change in the kinetics of relaxation
of the nonequilibrium states. This change is accompanied by nonuniform broadening or shortwave shifting of the luminescence
spectrum and a drop in quantum light yield. The decay time for natural luminescence decreases by 1–3 orders, to nanoseconds,
and is independent of temperature within the range 80–450 K. The build-up stage disappears in the kinetics of luminescence
of Ce3+-centers and decay time is reduced by a factor of 2–4. Density effects are found to be independent of the conditions under
which the material is exposed to SR. A model is proposed in which density effects are related to nonradiative energy transfer
from the upper excited states of the luminescence centers to external quenching centers. The contribution of the space charge
induced by SR is also examined.
Ural State Technical University. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 11, pp. 120–135, November,
1996. 相似文献
10.
A. M. Kibardin T. Kh. Gazizov Yu. Ya. Efremov V. N. Zinin R. Z. Musin A. N. Pudovik 《Russian Chemical Bulletin》1980,29(4):656-660
Conclusions Trialkyl phosphites react with 1,1,1-trifluoroacetone to give 2,2,2-trialkoxy-3,5-dimethyl-3,5-bis(trifluoromethyl)-1,4,2-dioxaphospholanes, which slowly isomerize to trialkoxy--trifluoromethyl--(1-methyl-2,2-difluorovinyloxy)ethoxyfluorophosphoranes.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 910–914, April, 1980. 相似文献