全文获取类型
收费全文 | 761篇 |
免费 | 110篇 |
国内免费 | 125篇 |
专业分类
化学 | 623篇 |
晶体学 | 15篇 |
力学 | 24篇 |
综合类 | 11篇 |
数学 | 88篇 |
物理学 | 235篇 |
出版年
2024年 | 2篇 |
2023年 | 5篇 |
2022年 | 40篇 |
2021年 | 46篇 |
2020年 | 32篇 |
2019年 | 30篇 |
2018年 | 26篇 |
2017年 | 33篇 |
2016年 | 30篇 |
2015年 | 44篇 |
2014年 | 37篇 |
2013年 | 45篇 |
2012年 | 44篇 |
2011年 | 47篇 |
2010年 | 50篇 |
2009年 | 51篇 |
2008年 | 54篇 |
2007年 | 48篇 |
2006年 | 41篇 |
2005年 | 34篇 |
2004年 | 36篇 |
2003年 | 42篇 |
2002年 | 37篇 |
2001年 | 19篇 |
2000年 | 27篇 |
1999年 | 10篇 |
1998年 | 14篇 |
1997年 | 7篇 |
1996年 | 11篇 |
1995年 | 10篇 |
1994年 | 6篇 |
1993年 | 5篇 |
1992年 | 3篇 |
1991年 | 3篇 |
1990年 | 4篇 |
1989年 | 3篇 |
1988年 | 3篇 |
1987年 | 3篇 |
1986年 | 1篇 |
1985年 | 4篇 |
1984年 | 1篇 |
1982年 | 4篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1959年 | 1篇 |
排序方式: 共有996条查询结果,搜索用时 0 毫秒
1.
Gujie Qian S. Baccaro M. Falconieri Jiafang Bei A. Cecilia Guorong Chen 《Journal of Non》2008,354(40-41):4626-4629
Glasses in SiO2–ZnO–BaO system with the different ZnO/BaO ratio were studied. In some cases, BaF2 was introduced to substitute for BaO on the equal base. Photoluminescent spectra showed that ZnO in glass matrices behaved somewhat differently from ZnO crystals. Especially, the introduction of fluorine ions led to dramatic shift of UV emission band of glasses closer to that of ZnO crystals. Raman spectral analysis provided consistent results. In particular, Raman bands in the high frequency region are sensitive to effects of different ZnO/BaO or BaF2/BaO ratio on structure of glasses. 相似文献
2.
用传统的预测效度估计法估计高考预测效度,其估计值往往偏低。为此,本文应用回归分析中混合估计理论提出了高考预测效度的混合估计。这种估计是预测效度的无偏估计,并解决了预测效度估计值偏低的问题。 相似文献
3.
4.
In this article a new technique was developed to fabricate scaffolds with a unique microstructure by solid–liquid separation in combination with particulate-leaching. Firstly, the effects of polymer concentration, quenching temperature on the porous morphology and the mechanical property of obtained scaffolds during solid–liquid separation have been investigated. Then, salt granules as porogen were introduced into the solid–liquid phase separation to produce the unique pore structure of the scaffold. The pore diameter of the scaffold could be controlled with the particulate size and the wall of pores possessed special microstructure, which enhanced the pore interconnectivity. The cell culture results confirmed that a good interconnectivity of the scaffold prepared by the improved solid–liquid separation was useful for nutrition transportation and cell proliferation. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
5.
Three mechanisms to reduce threading dislocations(TDs) in GaN films as the epitaxial films grow thicker are suggested by SEM and TEM 相似文献
6.
Jun Fan Wei‐Guang Zhang Min‐Yu Tan Yu Tang Wei‐Sheng Liu Ning Tang Kai‐Bei Yu 《中国化学》2004,22(6):508-511
The La(III) complex with a new amide‐type tripodal ligand,2,2′.2″‐nitrilotris{[(2′‐benzylaminofomyl)‐phenoxylethyl)amine (L), was synthesized and characterized by X‐ray crystallographic analysis. Crystal data: C48H55.50LaN7O18.75, Mr=1169.40, monoclinic. space group, P21/n, a= 1.0644(3) nm. b=2.3889(5) nm, c= 2.1917(5) nm, β=90.65°, V=5.573(2) nm3, Z=1, Dc=1.394 g°cm?3, R1=0.0487, wR [1>2s?(I)]=0.1266. The results reveal that each La(III) ion binds to 9 oxygen atoms, three of which belong to carbonyl groups from three tripodal ligands and six to three bidentate nitrate groups and a two‐dimensional sheet of 4.82 networks is assembled by metal‐ligand coordination interaction. L, a heptadentate compound, merely acts as a tridentate bridging spacer due to its steric hindrance and links the La(III) ions as three‐connected nodes. 相似文献
7.
8.
本文利用含氢有机硅化合物与含双键的氨基酸酯的加成反应,合成了5种新的有机硅氨基酸衍生物。介绍了一种合成N-烷基取代氨基酸酯的新方法。对新化合物进行了元素和光谱分析鉴定。 相似文献
9.
Three divalent transiton‐metal complexes of 2,3‐pyridinedicarboxylate (2,3‐pda2), [Mn(2,3‐pda)‐(H2O)3]∞ ( 7 ), [Ni(2,3‐pda)(H2O)3]∞ ( 8 ), and [Cd2(2,3‐pda)2(H2O)]∞ ( 9 ) have been hydrothermally synthesized and structurally characterized. X‐ray diffraction analyses reveal that compounds 7 and 8 are zigzag‐ and linear‐type one‐dimension (1D) coordination polymers, respectively, whereas compound 9 is a three‐dimension (3D) coordination polymer. A simple comparison of the coordination geometries with the available neutral analogues {Mx(2,3‐pda)x(H2O)y}∞ containing one or two divalent transition‐metal atoms and equal ligands in the presence or absence of coordinated water molecules is also presented. 相似文献
10.
Most magnetorheological materials, composed of magnetic microparticles in a liquid, require significant amounts of magnetic particles and a large magnetic field to achieve the desired effects. Here, we report on a new type of magnetorheological materials consisting of small amounts of magnetic nanoparticles (0.8 wt %) but exhibiting large rheological change (i.e., a gel-sol transition) upon the application of a small magnetic field. We use self-assembly to create hybrid nanofibers, which consist of supramolecular hydrogelators and magnetic nanoparticles, as the matrices of the hydrogel. Localized in the nanofibers at a distance of 1-2 nm, the magnetic nanoparticles occupy a small volume fraction of the hydrogel, significantly enhancing the magnetic dipole interactions between them, which results in the large magnetoresponse. This strategy generates a hierarchical nanostructure and eliminates several drawbacks of the simple mixture of polymers with nanoparticles, and thus provides a new methodology that uses magnetic force to control the nanostructures and properties of soft materials. 相似文献