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1.
张芷芬  李承治 《数学进展》1997,26(5):445-460
本文研究了一类具有两个鞍点和一个中心的通用二次哈密尔顿向量场在二次扰动下的三参数开折,证明极限环的最小上界为2。  相似文献   
2.
The effect of polystyrene sulfonic acid (PSSA) macromolecules on the polymerization of acrylamide (AM) has been studied. It was found that the rates of polymerization of AM were greatly increased in the presence of PSSA in the polymerization system.The maximum value of the rate of polymerization of AM was obtained when the ratio of [—SO_3H]: [AM] reached 3:1. When the insoluble crosslinked PSSA was used instead of the soluble one, this effect decreased considerably. The interaction between molecules of PSSA and AM was determined by infrared spectroscopy, elementary analysis and X-ray photoelectron spectroscopy. The combination form, —SO_3-NH_3~ CO—, formed between sulfonic group and amide group was found to be existed since the infrared absorption band of —NH_2 shifted from 3400cm~(-1) to 3150 cm~(-1), the binding energy of electron N_(18) changed from 399.7 eV to 401.3 eV, and the atomic ratio of N to S of the products was similar to the ratio of reagents. Based on these experimental results, the mechanism of AM polymerization in the presence of PSSA is proposed. The initial step is the combination of AM with sulfonic group to form —CONH_3~ , then followed by polymerization on the PSSA macromolecule. The role of PSSA on the polymerization of AM is discussed.  相似文献   
3.
本文报告了298.1 K下甲酸钠(C_1), 乙酸钠(C_2)、丙酸钠(C_3)、丁酸钠(C_4)、戊酸钠(C_5)、已酸钠(C_6)和庚酸钠(C_7)七个盐对水溶液中乙醇、丙酮和乙腈三个溶质的活度系数的影响。实验方法是, 固定水溶液中乙醇、丙酮和乙腈的浓度(摩尔分数约为0.05), 用气相色谱法检测不同盐浓度下平衡气相中溶质分压的变化, 从而得出溶质的盐效应活度系数γ。本文给出了一个可以连续取样的气液平衡装置的设计。由实验结果可见, 不同碳链大小的脂肪酸根离子的盐效应作用差别很大。C_1、C_2的盐效应主要由于静电作用; 对C_3、C_4盐, 除静电作用外,它们的疏水基与溶质疏水基的相互作用对盐效应有显著影响; C_5、C_6和C_7的盐效应则反映了疏水离子的特色, 疏水水化、疏水相互作用、疏水离子形成的聚集体与不同官能团的特定相互作用等几项因素, 导致儿个溶质盐效应的差异。  相似文献   
4.
邓妙  刘元伟  张红艳  岑加萍  张治芬 《应用数学》2015,37(11):912-915,930
目的 探讨钙蛋白酶-10 基因(CAPN-10)单核苷酸多态性-19(SNP-19)与多囊卵巢综合征(PCOS)的相关性。 方法 采用聚合酶链反应- 限制性片段长度多态性(PCR-RFLP)技术,对107 例PCOS患者(PCOS 组)及111 例健康体检者(对照组)的CAPN-10 SNP-19 进行分析,并测定其性激素和生化指标。PCOS组再根据BMI与胰岛素抵抗(IR)稳态模型指数(HOMA-IR)分为肥胖组与非肥胖组、IR 组与非IR 组,分析CAPN-10 SNP-19 与其关系。结果 与对照组相比,PCOS 组BMI、空腹血糖(FPG)、TG、TC、LDL、黄体生成素(LH)、黄体生成素/ 卵泡刺激素(LH/FSH)、睾酮(T)均升高(均P<0.01)。PCOS 组CAPN-10 SNP-19 1等位基因及1/2基因型频率均高于对照组(均P<0.05);且CAPN-10 SNP-19 1/2基因型PCOS 发病风险较1/1、2/2 基因型增加约2倍(OR=1.9,95%CI=1.1~3.3,P<0.05)。CAPN-10 SNP-19 1、2等位基因频率PCOS 肥胖组与非肥胖组、IR 组与非IR组比较均无统 计学差异(均P>0.05);PCOS 肥胖组和IR组CAPN-10 SNP-19 1/2基因型频率分别高于非肥胖组和非IR 组,但差异均无统计学意义(均P>0.05)。结论 CAPN-10 SNP-19 与PCOS 遗传易感性有关,可能与PCOS 肥胖及IR 无关。  相似文献   
5.
折光计法测定酱油中可溶性无盐固形物的含量   总被引:2,自引:0,他引:2  
基于可溶性固形物的折射原理,用折光计法测定酱油中可溶性无盐固形物的含量,取得了与重量法基本一致的结果。该方法不需要对样品进行预处理,操作简便、快速,10—20s即可测定1份样品。  相似文献   
6.
Yin  Xiangchen  Lin  Chunchen  Zhou  Zhifen  Chen  Wandong  Zhu  Shourong  Lin  Huakuan  Su  Xuncheng  Chen  Yunti 《Transition Metal Chemistry》1999,24(5):537-540
The hydrolysis kinetics of p-nitrophenyl acetate (NA) catalyzed by CuII, ZnII and CoII complexes of tris(2-benzimidazylmethyl)amine (NBT) have been studied. The hydrolysis rate is first-order in both metal(II) complex and NA. The second-order rate constants, kcat are 0.083, 0.241 and 0.285mol–1Ls–1 (298K, I = 0.10molL–1 KNO3, 0.02molL–1 tris buffer, 40% MeCN aqueous solution) for Zn–NBT, Co–NBT and Cu–NBT complexes, respectively. The result indicates that the hydrolytic metalloenzyme activity of different metal complexes increases with the electrophilicity of the metal ions and that the complexes, in this paper, constitute that most efficient hydrolytic metalloenzyme models reported to date. An increase in MeCN content in the solution greatly reduces the hydrolytic activity of the nucleophiles.  相似文献   
7.
γ‐Glutamyltranspeptidase (GGT) is a tumor biomarker that selectively catalyzes the cleavage of glutamate overexpressed on the plasma membrane of tumor cells. Here, we developed two novel fluorescent in situ targeting (FIST) probes that specifically target GGT in tumor cells, which comprise 1) a GGT‐specific substrate unit (GSH), and 2) a boron–dipyrromethene (BODIPY) moiety for fluorescent signalling. In the presence of GGT, sulfur‐substituted BODIPY was converted to amino‐substituted BODIPY, resulting in dramatic fluorescence variations. By exploiting this enzyme‐triggered photophysical property, we employed these FIST probes to monitor the GGT activity in living cells, which showed remarkable differentiation between ovarian cancer cells and normal cells. These probes represent two first‐generation chemodosimeters featuring enzyme‐mediated rapid, irreversible aromatic hydrocarbon transfer between the sulfur and nitrogen atoms accompanied by switching of photophysical properties.  相似文献   
8.
The essential oil of fresh leaves from Agathis dammara (Lamb.) Rich was extracted using hydro-distillation, and GC-FID and GC–MS were used to analyse the essential oil. Nineteen compounds were identified, among which the major components were limonene (36.81%), β-bisabolene (33.43%) and β-myrcene (25.48%). In the antibacterial test, disc diffusion method and micro-well dilution assay proved that the essential oil had significant antibacterial activities. The inhibition zones against Staphylococcus aureus and Pseudomonas aeruginosa were 23.7 and 23 mm, respectively, which demonstrated that the inhibition effects were greater than positive control (10 μg/disc streptomycin). And the lowest MIC value of the essential oil was found against S. aureus (1.25 mg/mL) and Bacillus subtilis (1.25 mg/mL). This is the first report on the antibacterial activities of A. dammara essential oil.  相似文献   
9.
Fe3O4 magnetic nanoparticles (Fe3O4 MNPs) with much improved peroxidase-like activity were successfully prepared through an advanced reverse co-precipitation method under the assistance of ultrasound irradiation. The characterizations with XRD, BET and SEM indicated that the ultrasound irradiation in the preparation induced the production of Fe3O4 MNPs possessing smaller particle sizes (16.5 nm), greater BET surface area (82.5 m2 g?1) and much higher dispersibility in water. The particle sizes, BET surface area, chemical composition and then catalytic property of the Fe3O4 MNPs could be tailored by adjusting the initial concentration of ammonia water and the molar ratio of Fe2+/Fe3+ during the preparation process. The H2O2-activating ability of Fe3O4 MNPs was evaluated by using Rhodamine B (RhB) as a model compound of organic pollutants to be degraded. At pH 5.4 and temperature 40 °C, the sonochemically synthesized Fe3O4 MNPs were observed to be able to activate H2O2 and remove ca. 90% of RhB (0.02 mmol L?1) in 60 min with a apparent rate constant of 0.034 min?1 for the RhB degradation, being 12.6 folds of that (0.0027 min?1) over the Fe3O4 MNPs prepared via a conventional reverse co-precipitation method. The mechanisms of the peroxidase-like catalysis with Fe3O4 MNPs were discussed to develop more efficient novel catalysts.  相似文献   
10.
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