Production of 89Sr-doped CdSe QDs@PAMAM as the radioanalytical-fluorescent indicator of renal injury and the preliminary application in diabetic nephropathy model

Journal of Radioanalytical and Nuclear Chemistry - An indicator with double tracers has been developed so as to improve the accuracy and stability of quantitative analysis of renal injury. The...     

融合图卷积神经网络和注意力机制的PM2.5小时浓度多步预测

PM_2.5小时浓度多为单步预测。为实现PM_2.5小时浓度的多步预测,基于“编码器-解码器”的序列-序列预测（Seq2Seq）模型,集合图卷积神经网络提取非欧式空间数据特征的能力以及注意力机制自适应关注特征的能力,提出了融合图卷积神经网络和注意力机制的PM_2.5小时浓度多步预测（GCN_Attention_Seq2Seq）模型。并与Seq2Seq模型和使用了图卷积神经网络、未使用注意力机制的GCN_Seq2Seq模型进行了对照,以2015—2016年北京市22个空气质量监测站点的空气质量数据为样本进行实例验证,结果表明,Seq2Seq模型和图卷积神经网络（GCN）可对PM_2.5小时浓度数据的时空依赖进行有效建模,注意力机制有助于减缓多步预测中的预测精度衰减,提升PM_2.5小时浓度多步预测的精度。GCN_Attention_Seq2Seq模型可有效应用于多种长度的PM_2.5浓度预测窗口。     

基于加权流量介数中心性的路网脆弱性分析——以无锡市为例

针对当前路网脆弱性研究中缺乏对真实交通状况考量的问题,在复杂网络理论的基础上,结合交通流量信息,提出了基于加权流量介数中心性的路网脆弱性分析方法。首先计算路网拓扑抽象图中各节点的最短路径介数中心性,然后使用流量数据对相应区域最短路径介数中心性加权,综合得到最终的脆弱性指标结果。以无锡市为例,对其实际交通路网脆弱性进行了计算,结果表明,该方法能综合反映静态全局路网结构与动态局部通行信息和现实交通情景下的路网脆弱性。     

1,8-亚乙基萘在三氟化硼乙醚-聚乙二醇中的电化学聚合

在三氟化硼乙醚(BFEE)-聚乙二醇(分子量400,PEG400)混合电解质溶液中,1,8-亚乙基萘直接阳极氧化聚合可以获得自支撑聚(1,8-亚乙基萘)膜.单体在三氟化硼乙醚+10%PEG400中的起始氧化电位为0.95 Vversus SCE,远低于单体在0.1 mol.L-1四氟化硼四丁基胺-乙腈溶液中的起始氧化电位(1.38 VversusSCE).同时PEG400的加入可以有效改善单体在三氟化硼乙醚中的溶解性.UV-Vis,FTIR和1H-NMR确定了1,8-亚乙基萘在4,5位聚合,荧光光谱表明固态及可溶聚(1,8-亚乙基萘)膜是蓝色发光材料.     

8字形主被动锁模掺Er3+光纤激光器

在理论上分析了利用非线性光学环形镜作为等效可饱和吸收体压缩脉冲进行锁模的物理机制。利用8字形主被动混合锁模的结构在调制频率2．498749GHz下，在1．543μm处获得了12ps的锁模脉冲输出，对应谱宽0．22nm，时间脉宽积0．33。在抽运功率50mW情况下，输出脉冲平均功率3．715mW。在调制频率2．499344GHz、2．499114GHz和2．498999GHz时分别并获得了2～4阶幅度较为均衡的有理数谐波锁模脉冲序列。     

2-阶邻域连通无爪图的Hamilton性

设Ｇ是无爪图．对ｘ∈Ｖ（Ｇ），若Ｇ［Ｎ（ｘ）］不连通，则存在ｙｉ∈Ｖ（Ｇ）－｛ｘ｝（ｉ－１，２），使｜Ｎ（ｙｉ）∩Ｋｉ（ｘ）｜≥２，且｜Ｎ（ｙｉ）∩Ｎ（Ｋｉ＋１（ｘ））｛ｘ｝｜≥２（ｉ模２），那么称无爪图Ｇ是强２－阶邻域连通的，其中Ｋ１（ｘ），Ｋ２（ｘ）分别表示Ｇ［Ｎ（ｘ）］的两个分支．本文证明了：连通且强２－阶邻域连通的无爪图是Ｈａｍｉｌｔｏｎ图．     

Study of the electric capacitance spectra on symmetric quantum-dot pattern

We have calculated the ground-state energy of the symmetric quantum-dot pattern by the ab initio calculation method, i.e. unrestricted Hartree-Fock-Roothaan (UHFR) method based on the Gaussian basis, and studied their electric capacitance spectra, assuming each quantum dot of quantum-dot pattern to be confined in a three-dimensional spherical potential well of finite depth. For the systems in question, our results show that our method and theoretical model not only give the electric capacitance peaks similar to s-shell and p-shell atom-like quantum dot, but also show some new fine-structure of electric capacitance in the symmetric quantum-dot pattern system. This method might be a feasible tool to study few-electron problems on the symmetric quantum-dot pattern system.     

氢气的分析方法研究

介绍了低纯度氢气和高纯度氢气的不同分析检测方法。对于纯度小于99.99%的氢气,其分析方法主要有爆炸法、吸收法、膜分离法和气相色谱法;对于纯度大于99.99%的氢气,其分析方法主要有变温浓缩的热导池气相色谱法、配有光电离子化检测器(DID)的气相色谱法和色谱-质谱联用法。     

Synthesis and characterisation of polymeric materials consisting of {Fe2(CO)5}-unit and their relevance to the diiron sub-unit of [FeFe]-hydrogenase

By using "click" chemistry between a diazide and a diiron model complex armed with two alkynyl groups, two polymeric diiron complexes (Poly-Py and Poly-Ph) were prepared. The two polymeric complexes were investigated using infrared spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermal gravimetric analysis (TGA), M?ssbauer spectroscopy, and cyclic voltammetry (Poly-Py only, due to the insolubility of Poly-Ph). To probe the coordinating mode of the diiron units in the two polymeric complexes, two control complexes (3 and 4) were also synthesised using a monoazide. Complexes 3 and 4 were well characterised and the latter was further crystallographically analysed. It turns out that in both complexes (3 and 4) and the two polymeric diiron complexes, one of the two iron atoms in the diiron unit coordinates with one of the triazole N atoms. Our results revealed that both morphologies and properties of Poly-Py and Poly-Ph are significantly affected by the organic moiety of the diazide. Compared to the protonating behaviour of the complexes 3 and 4, Poly-Py exhibited proton resistance. In electrochemical reduction, potentials for the reduction of the diiron units in Poly-Py and hence its catalytic reduction of proton in acetic acid-DMF shifted by over 400 mV compared to those for complexes 3 and 4. It is likely that the polymeric nature of Poly-Py offers the diiron units a "protective" environment in an acidic medium and more positive reduction potential.     

用Z-scan法研究非线性介质中的热效应

从热传导方程出发,研究了脉冲激光作用下因样品线性和非线性吸收引起热效应而产生的折射率变化.从理论分析得出,当仅存在线性吸收时,非线性折射率的概念在通常情况下并不适合于由热效应产生的非线性,但在所用的激光脉冲很短的情况下,类似于其它非线性的各种效应,对热效应也可定义时间平均非线性折射率,并可用Z-scan法对这两类吸收感生的不同非线性折射率进行测量.所得结论符合实验结果.