关于模拟法描会聚点电场的讨论

本文论证了“ＱＥ－２”型静电场描迹中模拟聚焦电场的电极在设计上有误的观点。     

Large-scale separation of metallic and semiconducting single-walled carbon nanotubes

In the applications of single-walled carbon nanotubes (SWNTs), it is extremely important to separate semiconducting and metallic SWNTs. Although several methods have been reported for the separation, only low yields have been achieved at great expense. We show a separation method involving a dispersion-centrifugation process in a tetrahydrofuran solution of amine, which makes metallic SWNTs highly concentrated to 87% in a simple way.     

Encapsulations of La@C82 and La2@C80 inside single-walled boron nitride nanotubes

Possibility of encapsulations of metallofullerenes inside single-walled boron nitride nanotubes (BNNTs) is studied by using first-principles calculations. We find that both La@C₈₂ and La₂@C₈₀ can be exothermically encapsulated inside the (17, 0) and (14, 7) BNNTs. The minimum diameters of exothermically encapsulating both La@C₈₂ and La₂@C₈₀ inside BNNTs are predicated to be about 13.4 Å.     

铝－5＇－硝基水杨基荧光酮－溴化十六烷基吡啶显色反应的研究及应用

本文研究了铝－５＇－硝基水杨基荧光酮（５＇－ＮＳＦ）－溴化十六烷基吡啶（ＣＰＢ）体系的显色条件。试验结果表明，在ｐＨ４．５～６．０范围内，铝与５＇－ＮＳＦ及ＣＰＢ形成紫红色的三元配合物，其最大吸收波长为５５８ｎｍ，摩尔吸光系数为１．３×１０￣５，配合物的组成为Ａｌ：５＇－ＮＳＦ：ＣＰＢ＝１：２：２。铝浓度在０～４μｇ／２５ｍＬ范围内符合比耳定律。方法用于石灰石、石英沙、石膏中铝的测定，结果令人满意。     

A study of the interaction between enantiomers of zolmitriptan and hydroxypropyl-beta-cyclodextrin by capillary electrophoresis

The enantioresolution of zolmitriptan was performed using cyclodextrin (CD)-modified capillary zone electrophoresis (CZE) with hydroxypropyl-β-CD (HP-β-CD) as the chiral selector. The influence of experimental conditions on the enantioseparation of zolmitriptan, such as pH, temperature, applied voltage, and concentrations of running electrolyte and CD, was systematically investigated, obtaining a baseline separation of two enantiomers by the use of a 25 mM sodium dihydrogen phosphate (SDPH) running electrolyte (pH 2.4) containing 30 mM HP-β-CD at 15 °C. Binding constants for each enantiomer–HP-β-CD pair at different temperatures, as well as thermodynamic parameters for binding, were calculated. A nonlinear van’t Hoff plot was obtained, indicating that the thermodynamic parameters of complexation were temperature-dependent for zolmitriptan enantiomers. The significant contribution of the enthalpy difference to the Gibbs free energy change suggested a stereomeric barrier mechanism for chiral recognition. Figure Resolution of zolmitriptan enantiomers was achieved by using CD-modified CZE Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

液相色谱-串联质谱法测定蔬菜和水果中6种新型酰胺类杀菌剂的残留量

建立了蔬菜、水果中啶酰菌胺、氟啶酰菌胺、环氟菌胺、嘧菌胺、双炔酰菌胺和硅噻菌胺6种新型酰胺类杀菌剂残留量的液相色谱-串联质谱(liquid chromatography-tandem mass spectrometry, LC-MS/MS)检测方法。试样经乙腈提取、Florisil固相萃取柱净化、以乙腈和水为流动相梯度洗脱、结合新型核壳型填料色谱柱(Poroshell 120 EC-C₁₈)分离,采用电喷雾正离子扫描、多反应监测模式质谱检测,外标法定量。结果表明:固相萃取结合新型色谱柱分离解决了酰胺类农药分析中基质效应强的难点问题。6种杀菌剂在0.5~100 μg/L范围内线性关系良好,相关系数(r)≥0.9990;对7种蔬菜及3种水果进行0.5、5和50 μg/kg 3个加标水平的回收试验,回收率为65%~124%,相对标准偏差(RSD, n=5)为1%~18%; 6种杀菌剂的方法检出限(S/N≥3)为0.10~0.17 μg/kg。该净化、分离模式显著降低了蔬菜、水果中6种新型酰胺类农药的基质效应,方法简单准确,可满足蔬菜和水果中啶酰菌胺等6种新型酰胺类杀菌剂残留检测的要求。     

直接观测磁通密度分布和运动的磁光图像技术

阐述了应用法拉第磁光旋转效应将磁通密度分布转换为亮度分布的图像，介绍了用微机采集和处理这种磁光图像，直接观测和研究磁通密度分布和运动，研究超导体的磁通动力学和磁性材料的磁性结构，叙述了目前应用磁光图像技术研究高温超导体性质和实用高温超导带材方面的最新进展．     

Synthesis of silylcyclopropanes via arsonium ylides

Silylcyclopropanes were synthesized from trimethylsilylmethylenetriphenylarsorane and substituted chalcones.     

Extracting and analyzing sub-signals in heart rate variability

A new statistical signal processing method, which was called independent component analysis (ICA) was used to extract sub-signals of heart rate variability (HRV). Ten healthy volunteers (4F, 6M) were involved in this study. Electrocardiogram (ECG) recording was consisted of 6min when the volunteer was lying and another 6min when the volunteer was standing. HRV was extracted from ECG. According to time-delay, HRV was divided into five groups as mixed signals. Five signals were reconstructed into two groups by ICA and the rebuilt two signals were transformed by Fourier transformation. Results showed that one group signal component centralized in low frequency (called IC1); the other did in high frequency (called IC2). The power of IC1 was significantly increased (P<0.05) while that of IC2 had no significant change (P>0.05) and the ratio of IC1 to total power was significantly increased (P<0.01) from lying to standing. Comparing the two postural results, it shows that IC1 may express sympathetic activity, and IC2 represents parasympathetic activity. Sympathetic and parasympathetic nervous function can be evaluated respectively and quantificationally by data and graphs from the two decomposed components. As an electro-physiological method, it can assist the investigation about the tension of autonomic nervous, myocardial bioelectricity activity, as well as myocardial cell membrane characters.     

Detection of subsurface defects of fused silica optics by confocal scattering microscopy

<正>A non-destructive technique for subsurface measurements is proposed by combining light scattering method with laser confocal scanning tomography.The depth and distribution of subsurface defect layers are represented in term of scattered light intensity pattern,and three types of fused silica specimens are fabricated by different grinding and polishing processes to verify the validity and effectiveness.By using the direct measurement method with such technique,micron-scale cracks and scratches can be easily distinguished,and the instructional subsurface defect depths of 55,15,and 4μm are given in real time allowing for an in-process observation and detection.