介孔分子筛MCM-41固载多氮杂环席夫碱与醋酸钴共同催化的Henry反应

采用2-苯基-2氢-1,2,3-三唑-4-醛固载改性的MCM-41与醋酸钴共同催化的Henry反应。通过傅里叶变换红外光谱(FT-IR)和X射线多晶衍射(XRD)等技术手段对催化剂进行了表征。在室温下考察了金属盐、溶剂对反应的影响,催化剂循环使用3次后催化活性基本无变化(产率可达80.5%)。     

Graphitic Carbon Nitride (g-C3N4): An Interface Enabler for Solid-State Lithium Metal Batteries

Solid-state Li metal batteries (SSLMBs) have attracted considerable interests due to their promising energy density as well as high safety. However, the realization of a well-matched Li metal/solid-state electrolyte (SSE) interface remains challenging. Herein, we report g-C₃N₄ as a new interface enabler. We discover that introducing g-C₃N₄ into Li metal can not only convert the Li metal/garnet-type SSE interface from point contact to intimate contact but also greatly enhance the capability to suppress the dendritic Li formation because of the greatly enhanced viscosity, decreased surface tension of molten Li, and the in situ formation of Li₃N at the interface. Thus, the resulting Li-C₃N₄|SSE|Li-C₃N₄ symmetric cell gives a significantly low interfacial resistance of 11 Ω cm² and a high critical current density (CCD) of 1500 μA cm⁻². In contrast, the same symmetric cell configuration with pristine Li metal electrodes has a much larger interfacial resistance (428 Ω cm²) and a much lower CCD (50 μA cm⁻²).     

合成双吲哚甲烷类衍生物的研究进展

双吲哚甲烷类衍生物具有丰富的生物活性和药理活性,在医药领域得到了广泛的应用.近年来,对双吲哚甲烷类衍生物的合成研究引起了人们的热点关注.对双吲哚甲烷类衍生物的合成方法进行了综述,并将催化剂按照不同的类型分为:(1)路易斯酸催化剂,(2)分子碘催化剂,(3)质子酸催化剂,(4)固载催化剂,(5)杂多酸催化剂,(6)有机小分子催化剂,(7)配合物催化剂,(8)离子液体催化剂,(9)其它类型的催化剂.     

亚表面引发原子转移自由基聚合构筑温度响应型纳米纤维油水分离膜

亚表面引发聚合是一种用于制备共价嵌入型聚合物刷的新型改性策略.该方法在发展高稳定性聚合物刷功能化表界面材料方面具有显著的优势.本工作利用亚表面引发原子转移自由基聚合(sSI-ATRP)对静电纺丝聚丙烯腈(PAN)基纳米纤维膜进行亚表面改性,通过接枝聚N-异丙基丙烯酰胺(PNIPAM)制备了温度响应型纳米纤维油水分离膜(...     

水相中磷钼酸催化三组分合成烯丙基胺

以磷钼酸作为催化剂，芳香醛、胺和三丁基烯丙基锡三组分在水作为溶剂，室温下高产率的得到相应的烯丙基胺。     

Parameter estimation of ordinary differential equations

This paper addresses the development of a new algorithm forparameter estimation of ordinary differential equations. Here,we show that (1) the simultaneous approach combined with orthogonalcyclic reduction can be used to reduce the estimation problemto an optimization problem subject to a fixed number of equalityconstraints without the need for structural information to devisea stable embedding in the case of non-trivial dichotomy and(2) the Newton approximation of the Hessian information of theLagrangian function of the estimation problem should be usedin cases where hypothesized models are incorrect or only a limitedamount of sample data is available. A new algorithm is proposedwhich includes the use of the sequential quadratic programming(SQP) Gauss–Newton approximation but also encompassesthe SQP Newton approximation along with tests of when to usethis approximation. This composite approach relaxes the restrictionson the SQP Gauss–Newton approximation that the hypothesizedmodel should be correct and the sample data set large enough.This new algorithm has been tested on two standard problems.     

基于锥模型的一般信赖域算法收敛性分析

本文给出了锥模型信赖域算法的一般模型，它不仅包含通常的信赖域算法一相当于锥模型算法中bk＝0的情形，而且文献[1]的算法也可看作其子类．我们研究这个模型的较强的全局收敛性，并讨论保证算法具有超线性收敛速率的条件，从而推广了文[1]和文[4]中的若干结果．     

3-D object profilometry based on direct fringe displacement analysis

A simple, fast and accurate method for 3-D object profilometry is proposed and verified by simulation and experiment. The profilometry method is based on the principle that the height data of a measured object can be obtained from the relevant fringe displacement, which in turn can be obtained by determining the precise position of the fringe center on the reference plane and on the object's surface. With the aid of a fringe skeleton extraction technique, the 3-D information can be acquired even from those images in which some fringes are squeezed, interrupted or shadowed.     

Ultrathin CuF2-Rich Solid-Electrolyte Interphase Induced by Cation-Tailored Double Electrical Layer toward Durable Sodium Storage

Solid-electrolyte interphase (SEI) seriously affects battery's cycling life, especially for high-capacity anode due to excessive electrolyte decomposition from particle fracture. Herein, we report an ultrathin SEI (3–4 nm) induced by Cu⁺-tailored double electrical layer (EDL) to suppress electrolyte consumption and enhance cycling stability of CuS anode in sodium-ion batteries. Unique EDL with SO₃CF₃-Cu complex absorbing on CuS in NaSO₃CF₃/diglyme electrolyte is demonstrated by in situ surface-enhanced Raman, Cyro-TEM and theoretical calculation, in which SO₃CF₃-Cu could be reduced to CuF₂-rich SEI. Dispersed CuF₂ and F-containing compound can provide good interfacial contact for formation of ultrathin and stable SEI film to minimize electrolyte consumption and reduce activation energy of Na⁺ transport. As a result, the modified CuS delivers high capacity of 402.8 mAh g⁻¹ after 7000 cycles without capacity decay. The insights of SEI construction pave a way for high-stability electrode.     

在代数多重网格法中的新插值公式

推导出代数多重网格法的一个新的插值公式。理论分析和数值计算表明这个公式很有效,且适用性强。推广了原代数多重网格法的应用范围,能够求解一些很病态的代数方程组。