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Gyula Záray Tibor Kántor Gerhard Wolff Zdravka Zadgorska Hubertus Nickel 《Mikrochimica acta》1992,107(3-6):345-358
The analytical capability of high-temperature halogenation with carbon tetrachloride vapour in a graphite furnace was investigated for silicon carbide powder with known chemical composition and particle size. Intensity vs heating time curves were determined for analytical lines of Al, B, Ba, Ca, Cr, Cu, Fe, Mg, Mn, Ti, V and Si constituents, volatilized with and without the presence of CCl4 vapour in the furnace atmosphere. Igniting 10 mg SiC at 2100 °C for 60 s in chlorinating atmosphere, the evaporated fraction of most of the constituents was higher than 90% (for Al about 50%). The line intensity vs sample mass (4–26 mg) relationships were linear for all impurities studied, while the intensity of silicon line showed a relatively small change with the sample mass. BEC (background equivalent concentration) values for this solid sampling technique (10 mg loaded sample) were 2–20 fold lower than those calculated for the conventional solution sample introduction method. 相似文献
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Experimental analysis of floc size distributions in a 1-L jar under different hydrodynamics and physicochemical conditions 总被引:1,自引:0,他引:1
This study focuses on the relation among hydrodynamics, physicochemical conditions, and floc size. During ortho-kinetic flocculation, the floc size is controlled by a balance between hydrodynamic stress and aggregate strength. Special attention was paid to the influence of a hydrodynamic sequencing on both the aggregate strength and the flocculation processes. Experimental research was conducted in a 1-L jar for two different pH values. The hydrodynamic sequencing was made up of successive slow and rapid mixing periods, and different slow mixing intensities were studied. First, the large floc size was shown to decrease with increasing velocity gradient (G), with an expected trend (d proportional variant epsilon(-1/4)). Then, the aggregate strength was shown to depend on two main factors: the flocculation history and the physicochemical conditions, which control the cohesion forces between primary particles. Finally, flocculation processes are discussed in terms of aggregation and breakup phenomena, with relation to local hydrodynamics and physicochemical conditions. 相似文献
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Dolashka P Moshtanska V Dolashki A Velkova L Rao GS Angelova M Betzel C Voelter W Atanasov B 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,83(1):67-73
The native form of Cu/Zn-superoxide dismutase, isolated from fungal strain Humicola lutea 103 is a homodimer that coordinates one Cu(2+) and one Zn(2+) per monomer. Cu(2+) and Zn(2+) ions play crucial roles in enzyme activity and structural stability, respectively. It was established that HLSOD shows high pH and temperature stability. Thermostability of the glycosylated enzyme Cu/Zn-SOD, isolated from fungal strain H. lutea 103, was determined by CD spectroscopy. Determination of reversibility toward thermal denaturation for HLSOD allowed several thermodynamic parameters to be calculated. In this communication we report the conditions under which reversible denaturation of HLSOD exists. The narrow range over which the system is reversible has been determined using the strongest test of two important thermodynamic independent variables (T and pH). Combining both these variables, the "phase diagram" was determined, as a result of which the real thermodynamic parameters (ΔC(p), ΔH(exp)°, and ΔG(exp)°) was established. Because very narrow pH-interval of transitions we assume they are as result of overlapping of two simple transitions. It was found that ΔH(o) is independent from pH with a value of 1.3 kcal/mol and 2.8 kcal/mol for the first and the second transition, respectively. ΔG(o) was pH-dependent in all studied pH-interval. This means that the transitions are entropically driven, these. Based on this, these processes can be described as hydrophobic rearrangement of the quaternary structure. It was also found that glycosylation does not influence the stability of the enzyme because the carbohydrate chain is exposed on the surface of the molecule. 相似文献
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Zdravka Bozikov 《组合设计杂志》2000,8(5):387-390
A new symmetric non‐self‐dual design with parameters (176, 50, 14) is constructed, where its full automorphism group of order 1000 is a faithful extension of the non‐abelian group of order 125 and exponent 5 by the cyclic group of order 8. © 2000 John Wiley & Sons, Inc. J Combin Designs 8: 387–390, 2000 相似文献
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Elena Kostadinova Pavlina Dolashka Stefka Kaloyanova Ludmyla Velkova Todor Deligeorgiev Wolfgang Voelter Ivan Petkov 《Journal of fluorescence》2012,22(6):1609-1615
In this study, an improved, rapid, high yield synthesis of N,N’-4,4’-bis(benzyl-2-boronic acid)-bipyridinium dibromide (o-BBV) is described. The obtained o-BVV is applied in a two-component saccharide sensing system (complex) where it serves as a fluorescence quencher and a saccharide receptor. This system was applied to different natural oligosaccharides isolated from molluscan Rapana venosa (RvH1-a) and arthropodan Carcinus aestuarii (CaeH) hemocyanins (Hcs) and cyclodextrins (CDs). The carbohydrate contents of both Hcs were calculated in our previous work to be 1,6 % and 7 % for CaeH and RvH1-a, respectively. We propose that the difference in fluorescence increase of the native CaeH and RvH1-a when titrating them with the complex is due to the fact that the carbohydrate content of CaeH is lower and the carbohydrate chains are buried in between the structural subunits of the native molecule, while the glycans of the functional unit RvH1-a are exposed on the surface of the molecule leading to a 4-fold fluorescence’s intensity change. 相似文献
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Margarita Stoytcheva Roumen Zlatev Zdravka Velkova Velizar Gochev Alan Ayala Gisela Montero Benjamín Valdez 《Electroanalysis》2021,33(3):695-704
A laponite modified carbon paste electrode was prepared, characterized and applied for the 2,4-dichlorophenol (2,4-DCP) voltammetric determination. It takes advantage of the ability of laponite to adsorb phenols, as well as of its availability and very low cost. Kinetic and equilibrium data for 2,4-DCP adsorption by laponite in aqueous dispersions demonstrated that the adsorption process obeyed a pseudo first order kinetic model and was consistent with the formation of adsorbed multilayers on a surface with heterogeneous pore distribution. The composite paste electrode exhibited a heterogeneous surface with 65 % increased surface area and 27 % enhanced catalytic activity compared to the unmodified one. The adsorptive stripping voltammetric determination of 2,4-DCP at an electrode with an optimized graphite:laponite ratio of 55 : 15 w% using a 3 min accumulation time at pH 5.5 was found to be suitable for its quantification in the linear concentration range extended up to 50 μmol L−1 with a sensitivity of 0.56 μA L μmol−1 and a LOD of 0.2 μmol L−1 (S/N=3).The 2,4-DCP electrochemical response was not affected by the presence of some structurally similar phenols, like catechol and p-nitrophenol, while resorcinol, 2-chlorophenol, and 4-chlorophenol presented interferences. The results were validated by 2,4-DCP determination in spiked tap water. 相似文献
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We study the thermodynamic properties of pure and hydrated samples of SOPC (stearoyl-2-oleoyl-sn-glycero-3-phosphocholine) membrane via Differential Scanning Calorimetry. We estimate the fundamental thermodynamic quantities, such as enthalpy and entropy, of the bilayer phosphatidylcholine. It is found that the gel-liquid crystal phase transition is driven by the van’t Hoff enthalpy, revealing the occurrence of an intermediate phase transition. We discuss the influence of the heating rate on the enthalpy and on the gel ? liquid crystal phase transition temperature by introducing the adequate thermodynamic Gibbs potential. The effect of hydrogen bonding of the water molecules with the polar head and polar-apolar interface on the energetics of the bilayer membrane matrix is analysed. The obtained transition temperature was found to vary between 3 and 4°C depending on the hydration level. A result corroborated by the behaviour of the heat capacity of SOPC computed via Molecular dynamics simulation. 相似文献