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1.
G. Basar H-D Kronfeldt S. Kröger 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1996,36(1):35-39
The hyperfine structure of the odd configurations 5d 96p and 5d 86s6p was studied with laser optogalvanic spectroscopy and high resolution interferometry in a platinum hollow cathode. A parametric hyperfine structure analysis for the configurations (5d+6s)96p with 10 excited odd-parity levels was performed for195Pt. We obtained one-electron hfs parameters,a 5d 01 =1160(320) MHz,a 6s 10 =35600(5300) MHz anda 6p 01 =1300(780) MHz for the configuration 5d 86s6p. The corresponding $\left\langle {r^{ - 3} } \right\rangle _{nl}^{k_s k_l } $ values are compared with those known for other 5d-elements. 相似文献
2.
Valerii F. Traven Dmitriy A. Cheptsov Zarina Z. Mamirgova Natalya P. Solovjova Vyacheslav M. Martynenko Sergei M. Dolotov Michail M. Krayushkin Ivan V. Ivanov 《Photochemistry and photobiology》2020,96(4):798-804
Photophysical characteristics of new 3-(1-acyl-5-aryl-3-pyrazolinyl)coumarins have been measured. These coumarin derivatives are found to be effective fluorophores and show high values of quantum yields of fluorescence both in nonpolar and in polar solvents. The 3-(1-acyl-5-aryl-3-pyrazolinyl)coumarins turned to be photosensitive compounds and undergo photolysis under irradiation in the range of 310–465 nm. Photolysis is suggested to include retro-cyclization and retro-condensation steps. The process is accompanied by a sharp drop of fluorescence that can be of interest for the creation of new media in optical recording of information. 相似文献
3.
Lyudmila Kayukova Anna Vologzhanina Pavel Dorovatovskii Gulnur Baitursynova Elmira Yergaliyeva Ayazhan Kurmangaliyeva Zarina Shulgau Sergazy Adekenov Zhanar Shaimerdenova Kydymolla Akatan 《Molecules (Basel, Switzerland)》2022,27(7)
Nitrobenzenesulfochlorination of β-aminopropioamidoximes leads to a set of products depending on the structure of the initial interacting substances and reaction conditions. Amidoximes, functionalized at the terminal C atom with six-membered N-heterocycles (piperidine, morpholine, thiomorpholine and phenylpiperazine), as a result of the spontaneous intramolecular heterocyclization of the intermediate reaction product of an SN2 substitution of a hydrogen atom in the oxime group of the amidoxime fragment by a nitrobenzenesulfonyl group, produce spiropyrazolinium ortho- or para-nitrobenzenesulfonates. An exception is ortho-nitrobenzenesulfochlorination of β-(thiomorpholin-1-yl)propioamidoxime, which is regioselective at room temperature, producing two spiropyrazolinium salts (ortho-nitrobezenesulfonate and chloride), and regiospecific at the boiling point of the solvent, when only chloride is formed. The para-Nitrobezenesulfochlorination of β-(benzimidazol-1-yl)propioamidoxime, due to the reduced nucleophilicity of the aromatic β-amine nitrogen atom, is regiospecific at both temperatures, and produces the O-para-nitrobenzenesulfochlorination product. The antidiabetic screening of the new nitrobezenesulfochlorination amidoximes found promising samples with in vitro α-glucosidase activity higher than the reference drug acarbose. 1H-NMR spectroscopy and X-ray analysis revealed the slow inversion of six-membered heterocycles, and experimentally confirmed the presence of an unfavorable stereoisomer with an axial N–N bond in the pyrazolinium heterocycle. 相似文献
4.
Sainer Siagian Khairul Basar Takashi Sakuma Haruyuki Takahashi Naoki Igawa Yoshinobu Ishii 《Solid State Ionics》2009,180(6-8):480-482
Diffuse neutron scattering from a powder AgCl was measured from 10 to 260 K. The correlation effects among thermal displacements of atoms were obtained from the diffraction data. The values of the correlation effects decrease rapidly with the increase of the inter-atomic distance. The values also decrease with the decrease of temperature. The similar tendency was also obtained in AgBr and CuI. The temperature dependence of the values of correlation effects agrees with the result by a simple Debye model of lattice vibrations. 相似文献
5.
Xianglian T. Sakuma K. Basar H. Takahashi 《Journal of Thermal Analysis and Calorimetry》2010,99(1):65-69
New inorganic compounds having the general formula (Bi2O3)1−x
(Lu2O3)
x
(x ranges from 0.1 to 0.5) displaying orange colours have been synthesized by traditional solid-state route, as viable alternatives
to lead, cadmium and chromium based yellow toxic inorganic pigments. The host lattice of these pigments is Bi2O3 that is doped by Lu3+ ions. The goal was to develop conditions for the synthesis of these compounds and to determine the influence of calcination
temperature and lutetium content on their colouring effects. The simultaneous TG-DTA measurements were used for determination
of the temperature region of the pigment formation and thermal stability of pigments. The pigments were also evaluated from
the standpoint of their structure and particle sizes. 相似文献
6.
The essential oils obtained by hydrodistillation of the rhizomes of Alpinia aquatica Rosc. syn. Alpinia melanocarpa and Alpinia malaccensis Roscoe were analysed by capillary gas chromatography and gas chromatography-mass spectrometry. Eighteen compounds, representing 98.4% of the essential oil were identified in A. aquatica rhizome oil, with β-sesquiphellandrene in 36.5% being the major constituent, while 20 compounds representing 99.7% of the rhizome oil of A. malaccensis were identified, among which methyl (E)-cinnamate (78.2%) was the major constituent. 相似文献
7.
T. Basar 《Journal of Optimization Theory and Applications》1973,11(6):655-661
The relative leadership property of Stackelberg strategies has been investigated via a scalar nonzero-sum, two-person differential game problem. It is shown that, depending on the parameters of the game, there exist three different types of solutions for his class of games.This work was partially supported by the National Science Foundation, Grant No. GK-31511, and the U.S. Office of Naval Research under the Joint Services Electronics Program, Contract No. N00014-67-A-0298-0006. The author would like to thank Professor Y. C. Ho for several valuable discussions. 相似文献
8.
In the present paper, we introduce Euler sequence spaces e
0
r
and e
c
r
of nonabsolute type that are BK-spaces including the spaces c
0 and c and prove that the spaces e
0
r
and e
c
r
are linearly isomorphic to the spaces c
0 and c, respectively. Furthermore, some inclusion theorems are presented. Moreover, the α-, β-, γ- and continuous duals of the spaces e
0
r
and e
c
r
are computed and their bases are constructed. Finally, necessary and sufficient conditions on an infinite matrix belonging to the classes
and
are established, and characterizations of some other classes of infinite matrices are also derived by means of a given basic lemma, where 1 ≤ p ≤ ∞.__________Published in Ukrains’kyi Matematychnyi Zhurnal, Vol. 57, No. 1, pp. 3–17, January, 2005. 相似文献
9.
Mohamed E Abdul-Rahman PS Doustjalali SR Chen Y Lim BK Omar SZ Bustam AZ Singh VA Mohd-Taib NA Yip CH Hashim OH 《Electrophoresis》2008,29(12):2645-2650
A 35 kDa glycoprotein whose abundance was previously demonstrated to be enhanced in sera of patients with endometrial adenocarcinoma (n = 12), was isolated from pooled sera of three of the cancer patients using champedak galactose-binding lectin affinity chromatography in the present study. Subjecting it to 2-DE and MS/MS, the glycoprotein was identified as the O-glycosylated fragment of inter-alpha-trypsin inhibitor heavy chain H4 (ITIH4). When compared to control sera (n = 17), expression of the 35 kDa ITIH4 cleavage fragment was demonstrated to be significantly enhanced in sera of patients with breast carcinoma (n = 10), epithelial ovarian carcinoma (n = 10), and germ cell ovarian carcinoma (n = 10) but not in patients with nasopharyngeal carcinoma (n = 13) and osteosarcoma (n = 7). The lectin-based electrophoretic bioanalytical method adopted in the present study may be used to assess the physiological relevance of ITIH4 fragmentation and its correlation with different malignancies, their stages and progression. 相似文献
10.
Ravindranath R Ajikumar PK Bahulayan S Hanafiah NB Baba A Advincula RC Knoll W Valiyaveettil S 《The journal of physical chemistry. B》2007,111(23):6336-6343
Ultrathin films of a cross-linked and chemically distinct conjugated poly(p-phenylene) network via electropolymerization are described. The amphiphilic network precursor was synthesized by incorporating the alkoxy carbazole group (-O(CH2)5Cb) to a poly(p-phenylene) (C6PPPOH) backbone. In order to investigate the combined thin film electrochemical and photophysical properties of poly(p-phenylene)s and polycarbazole conjugated polymers, C6PPPC5Cb was deposited on substrates using the Langmuir Blodgett Kuhn (LBK) method. The monolayer isotherm of the polymer, C6PPPC5Cb, showed a liquid expanded region slightly different from the parent polymer C6PPPOH. Multilayers (up to 30 layers) were transferred to different substrates such as quartz, gold coated LaSFN9 and ITO substrates for analysis. For conversion to a conjugated polymer network (CPN) film, the electroactive carbazole group was electropolymerized using cyclic voltammetry (CV) resulting in polycarbazole linking units. The differences in the film properties and corresponding changes in the electrochemical behavior indicate the importance of film thickness and electron/ion transport process in cross linked network films. From the electrochemical studies, the scan rate was found to have a considerable effect on electropolymerization with higher oxidation and reduction peak values found for the rigid network polymer compared to the uncrosslinked polymers. 相似文献