Synthesis of 2-substituted indoles by palladium-catalyzed heteroannulation with Pd-NaY zeolite catalysts

Various 2-substituted indoles were prepared by heteroannulation of o-iodoanilines and terminal alkynes in a one-pot reaction with a Pd(II)-NaY zeolite catalyst. The product formation largely depended on the solvent, base, and reaction temperature. The recycled catalyst showed good reusability in the heteroannulation reaction.     

Intramolecular energy transferable (2,2‐diphenylvinyl)phenyl substituted poly(p‐phenylenevinylene) derivative with efficient photoluminescence and electroluminescence

A poly(p‐phenylenevinylene) (PPV) derivative containing a bulky (2,2‐diphenylvinyl)phenyl group in the side chain, EHDVP‐PPV, was synthesized by Gilch route. The reduced tolane‐bisbenzyl (TBB) defects, as well as the structure of the polymer, was confirmed by various spectroscopic methods. The intramolecular energy transfer from the (2,2‐diphenylvinyl)phenyl side group to the PPV backbone was studied by UV‐vis and photoluminescence (PL) of the obtained polymer and model compound. The polymer film showed maximum absorption and emission peaks at 454 and 546 nm, respectively, and high PL efficiency of 57%. A yellow electroluminescence (λ_max = 548 nm) was obtained with intensities of 6479 cd/m² when the light‐emitting diodes of ITO/PEDOT/EHDVP‐PPV/LiF/Al were fabricated. The maximum power efficiency of the devices was 0.729 lm/W with a turn‐on voltage of 3.6 V. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5636–5646, 2004     

Fourier transform spectroscopy of CH3OH: rotation-torsion-vibration structure for the CH3-rocking and OH-bending modes

High-resolution Fourier transform spectra of CH₃OH have been investigated in the infrared region from 930 to 1450 cm⁻¹ in order to map the torsion-rotation energy manifolds associated with the ν₇ in-plane CH₃ rock, the ν₁₁ out-of-plane CH₃ rock, and the ν₆ OH bend. Upper-state term values have been determined from the assigned spectral subbands, and have been fitted to power-series expansions to obtain substate origins and effective B-values for the three modes. The substate origins have been grouped into related families according to systematic trends observed in the torsion-vibration energy map, but there are substantial differences from the traditional torsional patterns. There appears to be significant torsion-mediated spectral mixing, and a variety of “forbidden” torsional combination subbands with |Δυ_t|>1 have been observed, where υ_t denotes the torsional quantum number (equivalent to υ₁₂). For example, coupling of the (υ₆,υ_t)=(1,0) OH bend to nearby torsionally excited (υ₇,υ_t)=(1,1) CH₃-rock and (υ₈,υ_t)=(1,1) CO-stretch states introduces (υ₆,υ_t)=(1,0)←(0,1) subbands into the spectrum and makes the ν₇+ν₁₂−ν₁₂ torsional hot band stronger than the ν₇ fundamental. The results suggest a picture of strong coupling among the OH-bending, CH₃-rocking, and CO-stretching modes that significantly modifies the traditional energy structure and raises interesting and provocative questions about the torsion-vibration identity of a number of the observed states.     

Derived Brackets

We survey the many instances of derived bracket construction in differential geometry, Lie algebroid and Courant algebroid theories, and their properties. We recall and compare the constructions of Buttin and of Vinogradov, and we prove that the Vinogradov bracket is the skew-symmetrization of a derived bracket. Odd (resp., even) Poisson brackets on supermanifolds are derived brackets of canonical even (resp., odd) Poisson brackets on their cotangent bundle (resp., parity-reversed cotangent bundle). Lie algebras have analogous properties, and the theory of Lie algebroids unifies the results valid for manifolds on the one hand, and for Lie algebras on the other. We outline the role of derived brackets in the theory of Poisson structures with background'.     

Derived Brackets

We survey the many instances of derived bracket construction in differential geometry, Lie algebroid and Courant algebroid theories, and their properties. We recall and compare the constructions of Buttin and of Vinogradov, and we prove that the Vinogradov bracket is the skew-symmetrization of a derived bracket. Odd (resp., even) Poisson brackets on supermanifolds are derived brackets of canonical even (resp., odd) Poisson brackets on their cotangent bundle (resp., parity-reversed cotangent bundle). Lie algebras have analogous properties, and the theory of Lie algebroids unifies the results valid for manifolds on the one hand, and for Lie algebras on the other. We outline the role of derived brackets in the theory of ‘Poisson structures with background’.     

Effects of metal and “magnetic wall” on the dispersion characteristic of magnetostatic waves

The dispersion relation of magnetostatic waves tangentially magnetized to saturation ferrite film, with a “magnetic wall” condition (tangential component of microwave magnetic field is equal to zero) on one of the film surface and with a metal condition on the opposite surface is analyzed. The dispersion characteristics show that unidirectional magnetostatic waves appear in this structure: they can transfer energy in one direction only and fundamentally cannot transfer energy in the opposite direction. The dispersion-free propagation of magnetostatic waves also is possible in the structure in a wide frequency interval.     

Numerical simulation on an interaction of a vortex street with an elliptical leading edge using an unstructured grid

An algorithm for a time accurate incompressible Navier–Stokes solver on an unstructured grid is presented. The algorithm uses a second order, three‐point, backward difference formula for the physical time marching. For each time step, a divergence free flow field is obtained based on an artificial compressibility method. An implicit method with a local time step is used to accelerate the convergence for the pseudotime iteration. To validate the code, an unsteady laminar flow over a circular cylinder at a Reynolds number of 200 is calculated. The results are compared with available experimental and numerical data and good agreements are achieved. Using the developed unsteady code, an interaction of a Karman vortex street with an elliptical leading edge is simulated. The incident Karman vortex street is generated by a circular cylinder located upstream. A clustering to the path of the vortices is achieved easily due to flexibility of an unstructured grid. Details of the interaction mechanism are analysed by investigating evolutions of vortices. Characteristics of the interactions are compared for large‐ and small‐scale vortex streets. Different patterns of the interaction are observed for those two vortex streets and the observation is in agreement with experiment. Copyright © 2004 John Wiley & Sons, Ltd.     

Spectral mapping theorems for exponentially bounded c-semigroups in Banach spaces

LetZ be a generator of an exponentially boundedC-semigroup {S _t } _t≥0 in a Banach space and letT _t =C ⁻¹ S _t . We show that the spectral mapping theorems such as exp(tσ(Z)) ⊂ σ(T _t ) and exp(tσ _p (Z)) ⊂ tσ _p (T _t ) ⊂ exp(tσ _p (Z)) ⋃ {0} for everyt≥0 hold. The present studies were supported by the Basic Science Research Institute Program, Ministry of Education, 1987.     

Submanifolds of complex space forms admitting an almost contact metric compound structure

Summary Real hypersurfaces of an almost Hermitian manifold naturally admit an almost contact metric structure and the (f, g, u, v, w, , , )-structure is defined on submanifolds of codimension 3 of an almost Hermitian manifold. We study the so-called semi-invariant submanifolds of a complex space form with almost contact metric compound structure which is a general notion of (f, g, u, v, w, , , )-structure.Dedicated to professor Eulyong Pak on his 60th birthdayThis research was partially supported by Korean Science and Engineering Foundation Grant.     

Synthesis and antifolate activity of 8,10-dideazaminopterin

A synthesis of 8,10-dideazaminopterin, using 2,4-diamino-6-bromomethyl-8-deazapteridine ( 2 ) as a key intermediate, is described. Condensation of the triphenylphosphinylide derived from 2 with p-formylbenzoyl-L-glutamate afforded a 9,10-dehydro-8,10-dideazaminopterin ester intermediate 5 . Hydrogenation of the olefinic linkage and subsequent hydrolysis of the glutamate ester gave the title compound. 8,10-Dideazaminopterin was a potent growth inhibitor of folate dependent bacteria. It was 16 times more potent then methotrexate as an inhibitor of dihydrofolate reductase derived from L1210 leukemia cells, and showed strong activity against L1210 in mice.