Possibility of adjusting photoluminescence spectra of Ca scheelites (CaMoO<Subscript>4</Subscript>: Eu<Superscript>3+</Superscript> and CaWO<Subscript>4</Subscript>: Eu<Superscript>3+</Superscript>) to the emission spectrum of incandescent lamps

The peculiarities of the photoluminescence of compounds CaMoO₄: Eu³⁺ and CaWO₄: Eu³⁺ with the scheelite structure associated with a change in the short- and long-range orders of the crystal lattice upon a change in the activator (Eu³⁺) of the photoluminescence range in the interval 1–4 mol %, in which the photoluminescence of the matrix is preserved in the range 484–557 nm, are investigated using X-ray phase analysis as well as photoluminescence, Raman, and diffuse reflection spectroscopies. The introduction of Eu³⁺ ions leads to the reconstruction of the lattice so that up to 10% of these ions stimulate the formation of centrosymmetric localization upon the substitution of Ca²⁺ ions in the noncentrosymmetric positions. It is found that the spectral radiant emittance of the more effective luminophore CaMoO₄: Eu³⁺ can be adjusted to this parameter for an incandescent lamp for the Eu³⁺ concentration of 1–2 mol %.     

CHEMICAL STRUCTURE AND FUNCTIONAL PROPERTIES OF AMORPHOUS BORON CARBONITRIDE FILMS

Journal of Structural Chemistry - We report a comprehensive study of the effect of the chemical structure of boron carbonitride films on the variability of their functional characteristics. The...     

Investigation of structural features of hexadecafluorinated copper and zinc phthalocyanine films

The structural features of hexadecafluorinated copper and zinc phthalocyanine (MPcF₁₆) films (M = Cu, Zn) obtained by vacuum thermal deposition are investigated. The dependence of structural features of these films on the film thickness is studied by means of optical and Raman spectroscopy. It is shown that an increase in the thickness of MPcF₁₆ films, as well as film annealing under vacuum conditions at a temperature of 220°C, leads to the formation of the phase whose crystalline structure differs from that of the 20-to 50-nm-thick initial films.     

Effect of annealing on the optical absorption spectra of single-walled carbon nanotubes

The thermal stability of initial and purified samples of single-walled carbon nanotubes prepared through gas-phase disproportionation of carbon monoxide CO in the presence of iron particles under high pressure (the HiPCO method) is investigated using optical absorption spectroscopy and thermogravimetry. An analysis of the optical absorption spectra demonstrates that thermal oxidation of the initial material proceeds rather rapidly and uniformly owing to the catalytic effect caused by the presence of iron particles in the sample. The destruction of the carbon nanotubes contained in the as-prepared and purified samples begins at temperatures of ～250 and ～300°C, respectively. It is shown that single-walled metallic nanotubes undergo faster oxidation as compared to the single-walled semiconducting nanotubes.     

Probability of electron emission in photoemission from doped semiconductor

Electron motion is investigated in a strong-field region —in the region of bending of the band close to the surface of a semiconductor. In this region there is a change in the electron distribution function under the action of the electric field and interaction mechanisms leading to energy loss of the hot electrons. The main characteristics of the external photoeffect are determined by the energy lost by the electron in the region of band bending and the size of the barrier at the semiconductor-vacuum interface. The electron-emission probability from a crystal containing a space-charge region is determined from the solution of the Boltzmann kinetic equation. The energy dependence of the energy scattering length of the hot electrons is taken into account in the calculation. The calculation is made for photoemission from GaAs in conditions when the interaction with polar optical phonons is the most effective energy-scattering mechanism. An expression is obtained for the energy distribution function of the emitted electrons for the case of strong electric fields. The position of the distribution-function maximum depends on the electric field and the effective interaction constant with phonons. The current and quantum yield of the photoeffect are calculated.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, pp. 81–87, October, 1978.In conclusion, it remains to extend profound thanks to V. L. Bonch-Bruevich for Ms constant interest in the work.     

Synthesis of Highly Transparent SiCxNyOz:H Films via Plasma-Chemical Decomposition of 1,1,3,3,5,5-Hexamethylcyclotrisilazane,Oxygen, and Nitrogen Gas Mixture

Russian Journal of General Chemistry - Synthesis of silicon oxycarbonitride films highly transparent over a wide spectral region (350–2500 nm) has been developed. The films have been...     

Structure and properties of 4-phenyl-5H-1,2,3-dithiazole-5-thione polyiodide with S−I+−S bridged complex

Structural Chemistry - Treatment of 4-phenyl-5H-1,2,3-dithiazole-5-thione with iodine in acetonitrile yielded crystalline product with thione-iodonium three-center halogen bond and triiodide anion...     

Energy properties and structure of 2- and 8-allylthioquinoline complexes with iodine

The study focuses on the energy and quantum topological properties of substituted 2- and 8-allylthioquinoline complexes with iodine, which are assumed to correspond to prereaction states in the iodocyclization reaction leading to the formation of thiazolo- and tiazinoquinoline systems. The structures of the complexes and the corresponding atomic interactions are modeled considering the different conformational states of allyl-substituted quinolinethiols (thioquinolines). The energy values are analyzed for the interactions between the iodine molecule and different donor centers of the substituted quinoline system: the nitrogen heteroatom, sulfur, and π-system of the allyl group. It is shown that the formation of stable complexes with the nitrogen of the quinoline ring is complicated by steric hindrances posed by the S-allyl group at positions 2 and 8 of the quinoline system, which in turn contributes to the convergence of the cyclization centers.     

The features of iodine loss at high temperatures

Journal of Thermal Analysis and Calorimetry - A series of crystalline thiazoloquinolinium iodides has been studied using a combination of thermal analysis, mass and Raman spectroscopy techniques....     

Correction of the band gap of Y<Subscript>2</Subscript>O<Subscript>3</Subscript>:Eu<Superscript>3+</Superscript> phosphor

Submicron samples of Y₂O₃:Eu³⁺ phosphor with elevated photoluminescence (PL) efficiency and activator concentration of 9 at % obtained by the sol–gel method were investigated by diffuse reflection spectroscopy and PL spectroscopy. It is found that the diffuse reflection spectrum in the vicinity of the fundamental absorption edge (<300 nm) is distorted by the superposition of the PL of Eu³⁺ ions, as a result of which the calculated value of optical band gap E _g of the Y₂O₃ matrix is overestimated. An algorithm for eliminating the PL influence on the absorption edge is proposed, and the correct E _g values are found to be 4.61 ± 0.12 and 4.50 ± 0.12 eV for annealing at 700 and 1300°C, respectively.