Synthesis of mixed cyclotriveratrylenes

Cyclotriveratrylenes containing one benzene ring and two indole rings linked through N1 and C2 can be prepared by acid-catalysed reactions of formaldehyde and aryl aldehydes with 1,2-di-(1-indolylmethyl)benzene compounds.     

Room-temperature ferromagnetism of Cu-doped ZnO films probed by soft X-ray magnetic circular dichroism

We report direct evidence of room-temperature ferromagnetic ordering in O-deficient ZnO:Cu films by using soft x-ray magnetic circular dichroism and x-ray absorption. Our measurements have revealed unambiguously two distinct features of Cu atoms associated with (i) magnetically ordered Cu ions present only in the oxygen-deficient samples and (ii) magnetically disordered regular Cu2+ ions present in all the samples. We find that a sufficient amount of both oxygen vacancies (V(O)) and Cu impurities is essential to the observed ferromagnetism, and a non-negligible portion of Cu impurities is uninvolved in the magnetic order. Based on first-principles calculations, we propose a microscopic "indirect double-exchange" model, in which alignments of localized large moments of Cu in the vicinity of the V(O) are mediated by the large-sized vacancy orbitals.     

Tailoring pore size and pore size distribution of kidney dialysis hollow fiber membranes via dual-bath coagulation approach

Polyethersulfone (PES) hollow fiber membranes for kidney dialysis application were prepared by the dry-jet wet-spinning method. A dual-coagulation bath technology was first time employed for fabricating the kidney dialysis membranes with a tight inner skin and loose outer supporting layer structure. A weak coagulant isopropanol (IPA) was served as the first external coagulation bath, while water as the second bath. Experiments demonstrate their advantages of better controlling both inner and outer skin morphology. The as-spun fibers have a higher mean effective pore size (μ_p), pure water permeation flux (PWP) and molecular weight cut-off (MWCO) with an increase in N-methyl-2-pyrrolidone (NMP) percentage in bore fluid (i.e., internal coagulant). After being treated in 8000 ppm NaOCl solution for 1 day, fibers show larger pore sizes and porosity in both inner and outer surfaces, and thinner inner and outer layers than their as-spun counterparts. Among them, the bleached fibers spun with 50 wt.% NMP in bore fluid have the MWCO (43 kDa) and PWP (40 × 10⁻⁵ L m⁻² Pa⁻¹ h⁻¹) suitable for kidney dialysis application. Based on SEM observations and solute rejection performance, the further heat treated fibers in an aqueous solution is found to be an effective way to fine tune membranes morphology and MWCO for kidney dialysis application. The solute rejection performance data of the hollow fiber membranes spun with 55 wt.% NMP in bore fluid after heat treated at 90 °C in water for 2 h were found to be very appropriate for the kidney dialysis application.     

Thermal behavior of partially hydrogenated polydienes by <Emphasis Type="Italic">p</Emphasis>-toluenesulfonylhydrazide

The hydrogenation of natural rubber (NR), polybutadiene (BR), and styrene-butadiene (SBR) rubbers with different microstructures was performed by a diimide hydrogenation agent generated in situ by a non-catalytic method [1–3]. Many properties of the material depend considerably on variables such as degree of hydrogenation and proportions of vinyl or phenyl units. The mobility of the hydrogenated chain was investigated by differential scanning calorimetry (DSC) and the results confirm the relationship between the degree of hydrogenation and chain flexibility. The flexibility of a high cis-1,4 BR hydrogenated sample, was significantly changed and a melting point (T _m) was detected after a certain degree of hydrogenation. Thermal stability was investigated by thermogravimetric analysis (TG) and an increase was found, but, the thermal resistance was influenced by the presence of the byproduct p-toluenesulfinic acid. Oxidation stability was investigated by chemiluminescence analysis and it improved with hydrogenation.     

An adaptive model with joint chance constraints for a hybrid wind-conventional generator system

We analyze scheduling a hybrid wind-conventional generator system to make it dispatchable, with the aim of profit maximization. Our models ensure that with high probability we satisfy the day-ahead power promised by the model, using combined output of the conventional and wind generators. We consider two scenarios, which differ in whether the conventional generator must commit to its schedule prior to observing the wind-power realizations or has the flexibility to adapt in near real-time to these realizations. We investigate the synergy between the conventional generator and wind farm in these two scenarios. Computationally, the non-adaptive model is relatively tractable, benefiting from a strong extended-variable formulation as an integer program. The adaptive model is a two-stage stochastic integer program with joint chance constraints. Such models have seen limited attention in the literature because of the computational challenges they pose. However, we develop an iterative regularization scheme in which we solve a sequence of sample average approximations under a growing sample size. This reduces computational effort dramatically, and our empirical results suggest that it heuristically achieves high-quality solutions. Using data from a wind farm in Texas, we demonstrate that the adaptive model significantly outperforms the non-adaptive model in terms of synergy between the conventional generator and the wind farm, with expected profit more than doubled.     

Review on recent advances of carbon based adsorbent for methylene blue removal from waste water

The growth in textile and printing industries proven detrimental to the aquatic environment as the industrial waste containing dye seeped into the ecosystem. A high concentration of dye in water possess negative impacts on water ecosystem and harmful to human health. Removal of methylene blue (MB) dye from industrial waste via adsorption pathway has been widely investigated that promised high efficiency of MB removal. This review will summarize researches published from 2008 to 2019 on the removal of MB using carbon adsorbent with focus will be given on the synthesis and modification of carbon-based materials, and the structural properties influencing the performance of MB adsorption. Summary on the type of material used for the synthesis of carbon materials (activated carbon and biochar) will be included from utilization of the naturally occurring carbon sources such as polymers, biomasses and biowastes, and also sucrose and hydrocarbon gases. Modification of carbon materials such as chemical activation and physical activation; surface grafting to form functionalized surfaces; deposition with metal and magnetic nanoparticles via impregnation; and manufacturing of carbon composites will be discussed on the effects to promote MB adsorption and desorption. Another type of carbon adsorbents such as porous carbon; graphitic carbons including graphite, graphene, graphene oxide, and carbon nitride (g-C₃N₄); and finally nanocarbon in the form of nanotube, nanorod and nanofiber; will be included in the review with details on the synthesis method and the correlation between structural properties and adsorption activity. The regeneration process to increase the life cycle of carbon adsorbent will also be discussed based on two regeneration pathway i.e. a thermal degradation and desorption on MB. Finally the thermodynamics, kinetics, and the adsorption models of MB on carbon adsorbent will be discussed in this review.     

Experimental proof of a structural origin for the shadow fermi surface of Bi2Sr2CaCu2O8+delta

By combining surprising new results from a full polarization analysis of nodal angle-resolved photoemission data from pristine and modulation-free Bi(2)Sr(2)CaCu(2)O(8+delta) with structural information from LEED and ab initio one-step photoemission simulations, we prove that the shadow Fermi surface in these systems is of structural origin, being due to orthorhombic distortions from tetragonal symmetry present both in surface and bulk. Consequently, one of the longest standing open issues in the investigation of the Fermi surface of these widely studied systems finally meets its resolution.     

Dark matter in Susy models

Direct detection experiments for neutralino dark matter in the Milky Way are examined within the framework of SUGRA models with R-parity invariance and grand unification at the GUT scale, M _G. Models of this type apply to a large number of phenomena, and all existing bounds on the SUSY parameter space due to current experimental constraints are included. For models with universal soft breaking at M _G (mSUGRA), the Higgs mass and b → sγ constraints imply that the gaugino mass, m _1/2, obeys m _1/2>300–400 GeV, putting most of the parameter space in the coannihilation domain, where there is a relatively narrow band in the m ₀-m _1/2 plane. For μ>0, we find that the neutralino-proton cross section is ?10^?10 pb for m _1/2<1 TeV, making almost all of this parameter space accessible to future planned detectors. For μ<0, however, there will be large regions of parameter space with cross sections <10^?12 pb and, hence, unaccessible experimentally. If, however, the muon magnetic moment anomaly is confirmed, then μ>0 and m _1/2?800 GeV. Models with nonuniversal soft breaking in the third generation and Higgs sector can allow for new effects arising from additional early Universe annihilation through the Z-channel pole. Here, cross sections that will be accessible in the near future to the next generation of detectors can arise, and can even rise to the large values implied by the DAMA data. Thus, dark matter detectors have the possibility of studying the post-GUT physics that control the patterns of soft breaking.     

Scanning white-light interferometry as a novel technique to quantify the surface roughness of micron-sized particles for inhalation

A novel approach of measuring the surface roughness of spherical and flat micron-sized drug particles using scanning white-light interferometry was applied to investigate the surface morphology of micron-sized active pharmaceutical ingredients (APIs) and excipient particles used for inhalation aerosols. Bovine serum albumin (BSA) and alpha-lactose monohydrate particles were chosen as model API and excipient particles, respectively. Both BSA and lactose particles were prepared with different degrees of surface corrugation using either controlled spray drying (four samples of BSA) or decantation (two samples of lactose). Particle size distributions were characterized by laser diffraction, and particles were imaged by scanning electron microscopy (SEM). Surface roughness of the BSA and lactose particles was quantified by white-light optical profilometry using vertical scanning interferometry (VSI) at full resolution using a 50x objective lens with 2.0x and 0.5x fields of view for BSA and lactose, respectively. Data were analyzed using Vision software (version 32, WYKO), and surface roughness values are expressed as root-mean-square roughness ( Rrms). Furthermore, data were compared to topographical measurements made using conventional atomic force microscopy. Analysis of the optical profilometry data showed significant variation in BSA roughness ranging from 18.58 +/- 3.80 nm to 110.90 +/- 13.16 nm for the smoothest and roughest BSA particles, respectively, and from 81.20 +/- 15.90 nm to 229.20 +/- 68.20 nm for decanted and normal lactose, respectively. The Rrms values were in good agreement with the AFM-derived values. The particle morphology was similar to SEM and AFM images. In conclusion, scanning white-light interferometry provides a useful complementary tool for rapid evaluation of surface morphology and roughness in particles used for dry powder inhalation formulation.