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排序方式: 共有73条查询结果,搜索用时 31 毫秒
1.
I. I. Simentsova L. P. Davydova A. V. Khasin T. M. Yurieva 《Reaction Kinetics and Catalysis Letters》2003,79(1):85-92
Temperature programmed desorption and volumetric methods in static conditions were used to study hydrogen adsorption on the
surface of metallic copper particles produced by the partial reduction of copper chromite CuCr2O4 with hydrogen. In the temperature range 300-573 K and in the range of medium surface coverages by hydrogen, the main state
of adsorbed hydrogen reveals the heat of adsorption q= 78 kJ/mol and activation energy of adsorption E
a = 69 kJ/mol. In the temperature range 77-300 K, an adsorption state with lower heat and activation energy was found, indicating
a non-uniformity of the copper surface within ca. 8% of the total number of surface sites.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
2.
Temperature dependence of the reaction rate of H2 oxidation on nickel oxide and solid solutions of nickel ions in MgO prepared at 573–1373 K, has been studied. The variation of the catalytic properties with temperature is attributed to the presence of nickel ions in different oxidation states simultaneously, i. e. Ni(II) and Ni(III).
H2 MgO, 573–1373 K. — Ni(II) Ni(III).相似文献
3.
T. M. Yurieva 《Reaction Kinetics and Catalysis Letters》1985,29(1):49-54
A method to affect the catalytic properties of low-temperature oxide catalysts by their synthesis through hydroxide compounds of the required composition and structure is suggested.
.相似文献
4.
G. S. Litvak T. P. Minyukova M. P. Demeshkina L. M. Plyasova T. M. Yurieva 《Reaction Kinetics and Catalysis Letters》1986,31(2):403-408
The effect of metal ions on the temperature range for the exstence of anion-modified oxides formed during the formation of Mg and Zn oxides and solid solutions of Cu, Al, Cr and Ni ions in these oxides through thermal decomposition of the respective hydroxo compounds, has been established.
- , Mg Zn, Cu, Al, Cr, Ni .相似文献
5.
N. N. Novikova M. V. Koval’chuk N. D. Stepina O. V. Konovalov E. A. Yurieva E. S. Chukhray 《Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques》2011,5(5):816-821
The X-ray standing wave method has been applied to study the formation of protein-lipid film on the water subphase. The influence
of different toxic reagents (heavy metals and urea) on protein-lipid interaction in an ordered film of glucose oxidase and
behenic acid has been investigated. Analysis of angular dependence of fluorescence yield provided information on molecular
arrangement in bioorganic nanosystems on the water surface, where protein and phospholipid molecules were free to move over
the water subphase. 相似文献
6.
N. A. Sanina S. M. Aldoshin G. V. Shilov E. V. Kurganova E. A. Yurieva N. A. Voloshin V. I. Minkin V. A. Nadtochenko R. B. Morgunov 《Russian Chemical Bulletin》2008,57(7):1451-1460
Paramagnetic (tris)oxalates with the composition (SP)3M(C2O4)3·4H2O (M = Cr (2), Mn (3), Fe (4), and Co (5)) were synthesized for the first time based on the spiropyran salt SP+Br− (1) with the SP+ cation containing the pyridine ring in the aliphatic chain of the benzopyran moiety, which was also prepared in the present
study. According to X-ray diffraction data, the SP+ cations in the starting salt 1 are close-packed thus hindering photochromic transformations. The spin for paramagnet 4 is 5/2, which corresponds to the FeIII atom in the high-spin state, the spin of the system remaining unchanged under UV irradiation. In complex 3, a crossover from ferromagnetic to antiferromagnetic correlations was observed after the replacement of the inorganic cation
with the organic spiropyran cation.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1424–1432, July, 2008. 相似文献
7.
R. N. Pletnev É. I. Yurieva S. V. Verkhovskii G. V. Bazuev 《Journal of Structural Chemistry》2005,46(1):59-66
The 63Cu and 139La NMR spectra of the low-(δ = 0.25) and high-temperature (δ = 0) phases of lanthanum cuprate LACu0.81Ni0.19O2.5+δ have been obtained. Quantum chemical calculations of the electronic structure of the high-temperature phase have been performed. It is found that the observed metal-semiconductor phase transition is attended by changes in the degree of atomic ordering and in the character of electronic conductivity over certain types of “copper” centers. 相似文献
8.
9.
F. B. Mushenok R. B. Morgunov N. A. Sanina S. M. Aldoshin E. A. Yurieva 《Russian Chemical Bulletin》2011,60(7):1387-1393
An increase in the effective magnetic moments and linewidths in ESR spectra caused by the presence of crystallization water
molecules in crystals of tris(oxalato)chromium(III) complexes with spiropyran cations Sp+ was found. Dehydration (rehydration) of crystals causes a reversible decrease (increase) in thermally induced paramagnetism
of Sp+. Thermally induced paramagnetism of crystals appears in the compounds synthesized in oxygen atmosphere but is not found in
the compounds synthesized under argon atmosphere. The contributions of chromium oxalates and thermally excited spiropyran
molecules to the magnetization were separated using ESR spectroscopy. The enthalpies of the biradical states of some types
of spiropyran cations in crystals were determined. 相似文献
10.
O. Yu. Prudnikova O. V. Makarova T. M. Yurieva 《Reaction Kinetics and Catalysis Letters》1980,14(4):413-416
Copper-containing catalysts have been investigated in low-temperature methanol synthesis. It is shown that the active component of the catalyst is the copper ion and not the metallic copper as is supposed previously.
, , , .相似文献