全文获取类型
收费全文 | 260篇 |
免费 | 32篇 |
国内免费 | 34篇 |
专业分类
化学 | 208篇 |
晶体学 | 3篇 |
力学 | 28篇 |
综合类 | 5篇 |
数学 | 18篇 |
物理学 | 64篇 |
出版年
2024年 | 3篇 |
2023年 | 18篇 |
2022年 | 22篇 |
2021年 | 25篇 |
2020年 | 18篇 |
2019年 | 21篇 |
2018年 | 8篇 |
2017年 | 7篇 |
2016年 | 12篇 |
2015年 | 12篇 |
2014年 | 10篇 |
2013年 | 9篇 |
2012年 | 15篇 |
2011年 | 15篇 |
2010年 | 5篇 |
2009年 | 11篇 |
2008年 | 9篇 |
2007年 | 6篇 |
2006年 | 9篇 |
2005年 | 11篇 |
2004年 | 10篇 |
2003年 | 4篇 |
2002年 | 9篇 |
2001年 | 4篇 |
2000年 | 4篇 |
1999年 | 13篇 |
1998年 | 10篇 |
1997年 | 6篇 |
1996年 | 4篇 |
1995年 | 4篇 |
1994年 | 2篇 |
1993年 | 4篇 |
1992年 | 1篇 |
1990年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1980年 | 1篇 |
1959年 | 1篇 |
排序方式: 共有326条查询结果,搜索用时 31 毫秒
1.
LiuYuqi LiZhigang YahYakun 《Acta Mechanica Solida Sinica》2004,17(1):58-64
By using the Finite Element Inverse Approach based on the Hill quadratic anisotrop-ically yield criterion and the quadrilateral element, a fast analyzing software-FASTAMP for the sheet metal forming is developed. The blank shapes of three typical stampings are simulated and compared with numerical results given by the AUTOFORM software and experimental results, respectively. The comparison shows that the FASTAMP can predict blank shape and strain distribution of the stamping more precisely and quickly than those given by the traditional methods and the AUTOFORM. 相似文献
2.
Fabrication of hexaphenylsilole nanowires and their morphology-tunable photoluminescence. 总被引:1,自引:0,他引:1
Liping Heng Jin Zhai Anjun Qin Yuqi Zhang Yongqiang Dong Ben Zhong Tang Lei Jiang 《Chemphyschem》2007,8(10):1513-1518
Immersion of nanoporous alumina membranes into saturated solutions of hexaphenylsilole with subsequent solvent evaporation affords aligned organic nanowires. The luminescent properties of the hexaphenylsilole nanowires can be manipulated by varying their morphologies, which were controlled by changing the channel sizes of the alumina templates. 相似文献
3.
用原子吸收法或极谱法测定了对例慢性肾炎病人(A组)和24例慢性肾衰病人(B组)及40名健康人(对照组,C组)全血中的Fe、Zn、Cu、Mn、Se、Pb和Ga含量。结果表明,A组与C组比较.血中Fe的含量A组明显低于C组(P<0.05),Zn、Mn和Se的含量A组均非常明显低于C组(P<0.01),Pb含量A组非常明显高于C组(P<0.01),Cu和Ca含量两组间均无明显差异(P>0.05);B组与C组比较,Fe含量B组明显低于C组(P<0.06),Se含量则B组明显高于C组(P<0.05);Zn、Mn、Cu、Ga含量B组均非常明显低于C组(P<0.01),而Pb含量则B组非常明显高于C组(P<0.01)。 相似文献
4.
Direct band gap copper indium chalcogenides are of great technological importance in part because of their high photovoltaic conversion efficiency. Covalent superlattices constructed from copper indium chalcogenide clusters are of particular interest because they may combine open framework architecture with semiconducting properties. Here two photoluminescent covalent superlattices built from core-shell type copper indium sulfide supertetrahedral clusters are reported. Each cluster consists of 35 metal cations and is so far the largest known supertetrahedral cluster with a metal-to-metal distance of 1.6 nm. In addition, this is the first example of supertetrahedral clusters in heterometallic copper indium chalcogenides. The preparation of these large clusters has narrowed down the size gap between colloidal nanoclusters and small supertetrahedral clusters and revealed new possibilities in the construction of nanoporous semiconducting superlattices with tunable pore size. Through the combination of metal ions with different oxidation states to provide both overall and local charge neutrality, an effective approach has been demonstrated in the rational synthesis of chalcogenide open framework materials with large and unprecedented supertetrahedral clusters. 相似文献
5.
A new zirconia-based stationary phase (DPZ) was prepared by modifying zirconia with dodecylamine-N,N-dimethylenephosphonic acid (DDPA). DDPA was adsorbed on zirconia with only one phosphonic group, with the other being free.
Besides the hydrophobic interaction provided by nonpolar dodecyl, DPZ also has dipolar interaction, ion-exchange or electrostatic
repellent interaction provided by the free phosphonic group and amino group at different conditions. Separation of bases on
this stationary phase was achieved with satisfaction owing to the various retention mechanisms. The influence of methanol
content, pH value, ion types, and ionic strength of mobile phase are studied in detail.
Translated from Chinese Journal of Chromatography, 2005, 23(1) (in Chinese) 相似文献
6.
Jing?Zhou Yuqi?Liu Liming?Tang Xinchen?Teng Ning?Tang Zhongxian?HuangEmail author 《中国科学B辑(英文版)》2003,46(1):64-74
Two mutants of the zinc finger protein, ZNF191 (243–368) I323W and R327W, are successfully obtained by site-directed mutagenesis.
The fluorescence spectrum is used to study the interaction between these two mutants and the oligonucleotides. The influence
of the mutation on the interaction has been studied using ethidium bromide (EB) as the fluorescence probe. The binding constants
of the I323W-DNA and R327W-DNA have been calculated and the possible binding models have been discussed. 相似文献
7.
Zhijia Wang Antonio Toffoletti Yuqi Hou Jianzhang Zhao Antonio Barbon Bernhard Dick 《Chemical science》2021,12(8):2829
The triplet state lifetimes of organic chromophores are crucial for fundamental photochemistry studies as well as applications as photosensitizers in photocatalysis, photovoltaics, photodynamic therapy and photon upconversion. It is noteworthy that the triplet state lifetime of a chromophore can vary significantly for its analogues, while the exact reason was rarely studied. Herein with a few exemplars of typical BODIPY derivatives, which show triplet lifetimes varying up to 110-fold (1.4–160 μs), we found that for these derivatives with short triplet state lifetimes (ca. 1–3 μs), the electron spin polarization (ESP) pattern of the time-resolved electron paramagnetic resonance (TREPR) spectra of the triplet state is inverted at a longer delay time after laser pulse excitation, as a consequence of a strong anisotropy in the decay rates of the zero-field state sublevel of the triplet state. For the derivatives showing longer triplet state lifetimes (>50 μs), no such ESP inversion was observed. The observed fast decay of one sublevel is responsible for the short triplet state lifetime; theoretical computations indicate that it is due to a strong coupling between the Tz sublevel and the ground state mediated by the spin–orbit interaction. Another finding is that the heavy atom effect on the shortening of the triplet state lifetime is more significant for the T1 states with lower energy. To the best of our knowledge, this is the first systematic study to rationalize the short triplet state lifetime of visible-light-harvesting organic chromophores. Our results are useful for fundamental photochemistry and the design of photosensitizers showing long-lived triplet states.The electron spin polarization inversion and anisotropic decay of triplet substates explain the short triplet state lifetime of BODIPY derivatives. 相似文献
8.
For this work, europium monosulfide (EuS) powders were prepared by sulfurizing Eu2O3 powder with CS2 gas. The synthesized EuS powders were sintered by SPS at temperatures in the 800–1600 °C range for 0.33–1 h at 50 MPa under vacuum conditions. The influences of Yb doping and sintering conditions on the magnetocaloric and mechanical properties of EuS were investigated systematically. An increase in sintering temperature caused the rise of lattice parameters of EuS, whereas Yb doping caused them to drop. SEM showed that the grain size of the EuS increased with sintering temperatures in the 1000–1400 °C range. Higher sintering temperatures can enlarge the magnetizability and saturation magnetization of EuS compact. On the contrary, Yb doping can weaken the magnetizability and saturation magnetization of EuS compact. All sintered polycrystalline EuS compacts had weaker thermomagnetic irreversibility and lower magnetic anisotropy. 相似文献
9.
咪唑丙酸可以通过哺乳动物雷帕霉素靶蛋白复合物1(mTORC1)路径引起人的胰岛素抵抗,从而导致2型糖尿病(T2D),因此,咪唑丙酸的准确定量可辅助2型糖尿病的诊断。本文利用NiO与咪唑基团之间的配位作用,采用氧化镍沉积硅胶(NiO@SiO2)萃取材料对咪唑丙酸进行选择性富集和萃取。首先对NiO@SiO2固相萃取(SPE)条件进行优化:吸附剂用量为200 mg,上样液为20 mmol/L的磷酸盐缓冲溶液(pH=3. 0),解吸液为1. 0 mL含1%(质量分数) NH3·H2O的水溶液;然后,对萃取液进行高效液相色谱-质谱(HPLC-MS)分离分析,建立了血清中咪唑丙酸的检测方法。结果表明,咪唑丙酸浓度在0. 05~10 ng/mL范围内对质谱响应值具有良好的线性关系(R2≥0. 996),检出限和定量限分别为0. 02和0. 05 ng/mL,加标回收率为84. 0%~119%,相对标准偏差RSD<17. 2%。将该方法用于检测2型糖尿病患者与正常人血清样品中的咪唑丙酸,... 相似文献
10.
Yongjie Zhou Yuqi Mei Tian Luo Wenxue Chen Qiuping Zhong Haiming Chen Weijun Chen 《Molecules (Basel, Switzerland)》2021,26(9)
The contribution of rheological properties and viscoelasticity of the interfacial adsorbed layer to the emulsification mechanism of enzymatic modified sugar beet pectin (SBP) was studied. The component content of each enzymatic modified pectin was lower than that of untreated SBP. Protein and ferulic acid decreased from 5.52% and 1.08% to 0.54% and 0.13%, respectively, resulting in a decrease in thermal stability, apparent viscosity, and molecular weight (Mw). The dynamic interfacial rheological properties showed that the interfacial pressure and modulus (E) decreased significantly with the decrease of functional groups (especially proteins), which also led to the bimodal distribution of particle size. These results indicated that the superior emulsification property of SBP is mainly determined by proteins, followed by ferulic acid, and the existence of other functional groups also promotes the emulsification property of SBP. 相似文献