全文获取类型
收费全文 | 3147篇 |
免费 | 572篇 |
国内免费 | 353篇 |
专业分类
化学 | 2323篇 |
晶体学 | 37篇 |
力学 | 212篇 |
综合类 | 18篇 |
数学 | 307篇 |
物理学 | 1175篇 |
出版年
2024年 | 12篇 |
2023年 | 97篇 |
2022年 | 110篇 |
2021年 | 141篇 |
2020年 | 174篇 |
2019年 | 149篇 |
2018年 | 145篇 |
2017年 | 91篇 |
2016年 | 192篇 |
2015年 | 158篇 |
2014年 | 194篇 |
2013年 | 209篇 |
2012年 | 292篇 |
2011年 | 324篇 |
2010年 | 188篇 |
2009年 | 221篇 |
2008年 | 211篇 |
2007年 | 161篇 |
2006年 | 144篇 |
2005年 | 117篇 |
2004年 | 94篇 |
2003年 | 79篇 |
2002年 | 75篇 |
2001年 | 58篇 |
2000年 | 53篇 |
1999年 | 57篇 |
1998年 | 51篇 |
1997年 | 39篇 |
1996年 | 55篇 |
1995年 | 36篇 |
1994年 | 38篇 |
1993年 | 16篇 |
1992年 | 19篇 |
1991年 | 15篇 |
1990年 | 15篇 |
1989年 | 11篇 |
1988年 | 9篇 |
1987年 | 3篇 |
1986年 | 4篇 |
1985年 | 3篇 |
1984年 | 4篇 |
1983年 | 3篇 |
1982年 | 1篇 |
1974年 | 1篇 |
1957年 | 3篇 |
排序方式: 共有4072条查询结果,搜索用时 12 毫秒
1.
Polypyrrole Shell@3D‐Ni Metal Core Structured Electrodes for High‐Performance Supercapacitors
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Gao‐Feng Chen Yu‐Zhi Su Pan‐Yong Kuang Zhao‐Qing Liu Dao‐Yi Chen Xu Wu Nan Li Prof. Shi‐Zhang Qiao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(12):4614-4621
Three‐dimensional (3D) nanometal films serving as current collectors have attracted much interest recently owing to their promising application in high‐performance supercapacitors. In the process of the electrochemical reaction, the 3D structure can provide a short diffusion path for fast ion transport, and the highly conductive nanometal may serve as a backbone for facile electron transfer. In this work, a novel polypyrrole (PPy) shell@3D‐Ni‐core composite is developed to enhance the electrochemical performance of conventional PPy. With the introduction of a Ni metal core, the as‐prepared material exhibits a high specific capacitance (726 F g?1 at a charge/discharge rate of 1 A g?1), good rate capability (a decay of 33 % in Csp with charge/discharge rates increasing from 1 to 20 A g?1), and high cycle stability (only a small decrease of 4.2 % in Csp after 1000 cycles at a scan rate of 100 mV s?1). Furthermore, an aqueous symmetric supercapacitor device is fabricated by using the as‐prepared composite as electrodes; the device demonstrates a high energy density (≈21.2 Wh kg?1) and superior long‐term cycle ability (only 4.4 % and 18.6 % loss in Csp after 2000 and 5000 cycles, respectively). 相似文献
2.
3.
Yimei Wang Yi Qiao Xiaomin Xu Xiaohong Ding Weiwei Li Bo Yuan Haiyan Xu 《Biomedical chromatography : BMC》2019,33(8)
A sensitive and reliable LC–MS/MS method was developed and validated for simultaneous quantification of the major components of Huangqi–Honghua extact in rat plasma, including hydroxysafflor yellow A (HSYA), astragaloside IV (ASIV), calycosin‐7‐O‐β‐d ‐glucoside (CAG), calycosin, calycosin‐3′‐O‐glucuronide (C‐3′‐G) and calycosin‐3′‐O‐sulfate (C‐3′‐S). After extraction by protein precipitation with acetonitrile and methanol from plasma, the analytes were separated on a Hypersil BDS C18 column by gradient elution with acetonitrile and 5 mM ammonium acetate. The detection was carried out on a triple quadrupole tandem mass spectrometer equipped with electrospray ionization source switched between negative and positive modes. HSYA was monitored in negative ionization mode from 0 to 4.9 min, and ASIV, CAG, calycosin, C‐3′‐G and C‐3′‐S were determined in positive ionization mode from 4.9 to 10 min. The lower limits of quantification of the analytes were 6.25 ng/mL for HSYA, 0.781 ng/mL for CAG and 1.56 ng/mL for ASIV and calycosin. The intra‐ and inter‐assay precision (RSD) values were within 13.43%, and accuracy (RE) ranged from ?8.75 to 9.92%. The validated method was then applied to the pharmacokinetic study of HSYA, ASIV, CAG, calycosin, C‐3′‐G and C‐3′‐S in rat after an oral administration of Huangqi–Honghua extract. 相似文献
4.
Baowei Qiao Jie Feng Yun Ling Ting’ao Tang Bomy Chen 《Applied Surface Science》2006,252(24):8404-8409
The effects of Si doping on the structural and electrical properties of Ge2Sb2Te5 film are studied in detail. Electrical properties and thermal stability can be improved by doping small amount of Si in the Ge2Sb2Te5 film. The addition of Si in the Ge2Sb2Te5 film results in the increase of both crystallization temperature and phase-transition temperature from face-centered cubic (fcc) phase to hexagonal (hex) phase, however, decreases the melting point slightly. The crystallization activation energy reaches a maximum at 4.1 at.% and then decreases with increasing dopant concentration. The electrical conduction activation energy increases with the dopant concentration, which may be attributed to the increase of strong covalent bonds in the film. The resistivity of Ge2Sb2Te5 film shows a significant increase with Si doping. When doping 11.8 at.% of Si in the film, the resistivity after 460 °C annealing increases from 1 to 11 mΩ cm compared to the undoped Ge2Sb2Te5 film. Current-voltage (I-V) characteristics show Si doping may increase the dynamic resistance, which is helpful to writing current reduction of phase-change random access memory. 相似文献
5.
明确从地胆草中分离得到的两对牦牛儿内酯型的立体异构体即地胆草种内酯(scabertopin)、异地胆草种内酯(isoscabertopin)、异去氧地胆草内酯(isodeoxyelephantopin)和去氧地胆草内酯(deoxyelephantopin)的C-2相对构型;方法 NOESY技术,并结合这4个化合物的1H NMR,13C NMR,HMQC谱;结果 两对立体异构体的NOESY谱有明显差异;结论 通过分析NOESY谱,找寻H-1相关信息,若发现H-1与H-8,H-9β和14-CH3有NOE相关,可以判断化合物的C-2为α构型,若H-1与H-5,H-7,H-3α及H-9α之间有NOE相关,则化合物的C-2为β构型. 相似文献
6.
Gu De-shan Jing Shi-wei Sang Hai-feng Qiao Shuang Liu Yu-ren Liu Lin-mao 《Journal of Radioanalytical and Nuclear Chemistry》2004,262(2):493-496
This paper introduces the analysis method and principle of pulse fast-thermal neutron analysis (PFTNA). A system for the measurement
of low caloric power of coal by PFTNA is also presented. The 14 MeV pulse neutron generator and BGO detector and 4096 MCA
were applied in this system. A multiple linear regression method applied to the data solved the interferential problem of
multiple elements. The error of low caloric power between chemical analysis and experiment was less than 0.4 MJ/kg.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
7.
8.
AClassofCauchyProblemforQuasilinearHyperbolicSystemswiththeWeaklyDissipativeTerms¥LiuFagui;YangQiao(NorthChinaInstituteofWate... 相似文献
9.
荧光光谱法研究蛋白质构象的电磁-温度协同效应 总被引:1,自引:1,他引:0
长期以来电磁生物效应受到人们普遍关注,近年来从各个角度进行了相关研究。电磁-温度协同效应是当前的热点。本研究通过电磁场及温度协同对蛋白质影响的研究,发现蛋白质在电磁场作用下的不可逆变性,而且这种变性也遵循Arrhenius规律,并进一步得出电磁-温度协同作用的蛋白质变性模型。本文从分子反应动力学的角度解释了电磁-温度协同效应,并对非热效应作了一定的探讨。 相似文献
10.
影响海洋微藻生产麻痹性贝类毒素的重要生态因素 总被引:1,自引:0,他引:1
麻痹性贝类毒素是有害赤潮海洋微藻生产的重要毒素种类,本文综述了影响该类毒素的主要生态因素有光,温度,盐度和营养盐4类;弱光对毒素合成有抑制作用。低温下PSP毒素产量高,通过对营养盐吸收机制的离子效应,盐度可影响毒素的生命合成,不同种类和株系对N、P限制的反应有极大差异。 相似文献