Evaluation on thermal stability and kinetics of 2,2′-azobis(2,4-dimethyl)valeronitrile in aerobic and anaerobic conditions under isothermal process

Journal of Thermal Analysis and Calorimetry - We quantified the thermal stability of 2,2′-azobis(2,4-dimethyl)valeronitrile (ADVN) under isothermal conditions through thermogravimetry (TG),...     

Chaotic oscillations associated with the breakup of polarization entangled coherent states in a microchip solid-state laser

We demonstrate the breakup of spatial-polarization entangled lasing patterns, which possess vector phase singularities, and the resultant dynamic instabilities featuring chaotic oscillations. The frequency splitting between a pair of Ince-Gauss (IG) lasing modes, originally forming a coherent entanglement state, and a self-excited additional nonorthogonal IG mode through a new class of transverse effect of self-injection pattern seeding, is shown to result in modal-interference-induced modulation at the beat frequency, leading to chaotic oscillations.     

Vacuum condensates of QCD

We study the properties of QCD vacuum state in this paper. The values of various local quark vacuum condensates, quark-gluon mixed vacuum condensates, and the structure of non-local quark vacuum condensate are predicted by the solution of Dyson-Schwinger Equations in "rainbow" approximation with three sets of different parameters for effective gluon propagator. The light quark virtuality is also obtained in a consistent way. Our all theoretical results here are in good agreement with the empirical values used widely in literature and many other theoretical calculations.     

A comparative study of gold nanocubes, octahedra, and rhombic dodecahedra as highly sensitive SERS substrates

Gold nanocubes, octahedra, and rhombic dodecahedra with roughly two sets of particle sizes have been successfully synthesized via a seed-mediated growth approach. All six samples were analyzed for comparative surface-enhanced Raman scattering (SERS) activity. All of these Au nanostructures were found to yield strong enhancement at a thiophenol concentration of 10(-7) M and are excellent SERS substrates. Rhombic dodecahedra with a rhombus edge length of 32 nm showed significantly better enhancement than the other samples and can reach a detection limit of 10(-8) M. Simulations of the binding energies of thiophenol on the different faces of gold and electric near-field intensities of these nanocrystals have been performed to evaluate the experimental results. Superior SERS activity of these nanocrystals can be expected toward the detection of many other molecules.     

基于实际换热的ORC亚/跨临界综合评价

本文以有机朗肯循环(ORC)跨临界与亚临界工质换热特性最新研究成果为基础,采用热力学指标热源回收(火用)效率,以及经济学中的净现值(NPV)概念,结合换热面积分析,建立了考虑实际换热情况的热力学及经济性模型,更合理、更全面地对亚临界循环与跨临界循环的热力学性能和经济性进行了统一分析,为工程实际中亚临界和跨临界的选择提供...     

Antiproton-Nucleus Interaction and Coulomb Effect at High Energies

The Coulomb effect in high energy antiproton-nucleus elastic and inelastic scattering from ¹²C and ¹⁶O is studied in the framework of Glauber multiple scattering theory for five kinetic energies ranged from 0.23 to 1.83 GeV. A microscopic shell-model nuclear wave functions, Woods-Saxon single-particle wave functions, and experimental pN amplitudes are used in the calculations. The results show that the Coulomb effect is of paramount importance for filling up the dips of differential cross sections. We claim that the present result for inelastic scattering of antiproton-¹²C is sufficiently reliable to be a guide for measurements in the very near future. We also believe that antiproton nucleus elastic and inelastic scattering may produce new information on both the nuclear structure and the antinucleon-nucleon interaction, in particular the p-neutron interaction.     

Mg~(2+)掺杂锰酸锂的第一性原理研究

利用基于密度泛函理论的第一性原理平面波超软赝势法对Mg~(2+)掺杂锰酸锂的晶格常数与能带结构、态密度、键布居进行计算和分析,计算结果表明:掺杂Mg~(2+)后将会促使Mn、 O原子的电荷重新分布且其相互作用加强,能带带隙减小,费米能级附近的带数增加,费米能由-1.29 eV增加到-1.02 eV, Mn、 O、 Mg在总态密度中贡献比较大,锂离子贡献比较小且峰型尖锐局域化严重,提高了Li~+的扩散效率, Mn—O键变短,共价性增强,形成的共价键较稳定,其相互作用形成的骨架较稳定不易坍塌.从而提高了材料的循环充放电性能和电池使用寿命.     

Non-perturbative Aspects of QCD and Parameterized Quark Propagator

Based on the Global Color Symmetry Model, the non-perturbative Q, CD vacuum is investigated in the parameterized fully dressed quark propagator. Our theoretical predictions for various quantities characterized the QCD vacuum are in agreement with those predicted by many other phenomenologieal QCD inspired models. The successful predictions clearly indicate the extensive validity of our parameterized quark propagator used here. A detailed discussion on the arbitrariness in determining the integration cut-off parameter ofμ in calculating QCD vacuum condensates and a good method, which avoided the dependence of calculating results on the cut-off parameter is also strongly recommended to readers.     

Hyperspherical Analysis of D- in a Quantum Well

By introducing hyperspherical coordinates and assuming the quasiseparability of the hyperradius R from the angular variables Ω in the wavefunctions, we have solved the SchrSdinger equation for a D- center in two dimensions to obtain the low-lying spectrum. The correlation patterns in these states are visualized.``