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排序方式: 共有641条查询结果,搜索用时 46 毫秒
1.
Dr. Yulia Y. Enakieva Dr. Anna A. Sinelshchikova Prof. Mikhail S. Grigoriev Prof. Vladimir V. Chernyshev Dr. Konstantin A. Kovalenko Prof. Irina A. Stenina Prof. Andrey B. Yaroslavtsev Prof. Yulia G. Gorbunova Prof. Aslan Y. Tsivadze 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(45):10552-10556
The design of new solid-state proton-conducting materials is a great challenge for chemistry and materials science. Herein, a new anionic porphyrinylphosphonate-based MOF ( IPCE-1Ni ), which involves dimethylammonium (DMA) cations for charge compensation, is reported. As a result of its unique structure, IPCE-1Ni exhibits one of the highest value of the proton conductivity among reported proton-conducting MOF materials based on porphyrins (1.55×10−3 S cm−1 at 75 °C and 80 % relative humidity). 相似文献
2.
3.
G. Panina 《Central European Journal of Mathematics》2003,1(2):157-168
All 3-dimensional convex polytopes are known to be rigid. Still their Minkowski differences (virtual polytopes) can be flexible
with any finite freedom degree. We derive some sufficient rigidity conditions for virtual polytopes and present some examples
of flexible ones. For example, Bricard's first and second flexible octahedra can be supplied by the structure of a virtual
polytope. 相似文献
4.
Statistical Inference with Fractional Brownian Motion 总被引:3,自引:1,他引:2
Kukush Alexander Mishura Yulia Valkeila Esko 《Statistical Inference for Stochastic Processes》2005,8(1):71-93
We give a test between two complex hypothesis; namely we test whether a fractional Brownian motion (fBm) has a linear trend against a certain non-linear trend. We study some related questions, like goodness-of-fit test and volatility estimation in these models. 相似文献
5.
Gaiane Panina 《Central European Journal of Mathematics》2006,4(2):270-293
Hyperbolic virtual polytopes arose originally as polytopal versions of counterexamples to the following A.D.Alexandrov’s uniqueness
conjecture: Let K ⊂ ℝ3
be a smooth convex body. If for a constant C, at every point of ∂K, we have R
1 ≤ C ≤ R
2
then K is a ball. (R
1
and R
2
stand for the principal curvature radii of ∂K.)
This paper gives a new (in comparison with the previous construction by Y.Martinez-Maure and by G.Panina) series of counterexamples
to the conjecture. In particular, a hyperbolic virtual polytope (and therefore, a hyperbolic hérisson) with odd an number
of horns is constructed.
Moreover, various properties of hyperbolic virtual polytopes and their fans are discussed. 相似文献
6.
7.
Lensovet Leningrad Technological Institute. Plastpolimer Okhta Scientific-Production Association. Translated from Zhurnal Strukturnoi Khimii, Vol. 32, No. 4, pp. 22–28, July–August, 1991. 相似文献
8.
V. I. Zheivot T. A. Nikoro V. N. Krivoruchko L. I. Panina L. G. Pinaeva L. A. Isupova 《Journal of Analytical Chemistry》2007,62(12):1170-1175
Peculiarities of the determination of nitrogen oxides and ammonia in the reaction products of ammonia oxidation are studied by gas chromatography. Particular attention was paid to the sampling problem. It is shown that in the course of the transportation of samples containing nitrogen(II) oxide and oxygen, the oxidation of nitrogen(II) oxide to nitrogen(IV) oxide takes place in the vapor phase. The conditions were found for suppressing or even eliminating the gas-phase reaction of NO oxidation to NO2. A procedure for the gas-chromatographic analysis of the reaction products in the catalytic oxidation of ammonia is proposed using several samples and packed columns, including the determination of NO with respect to NO2 formed in the gas-phase oxidation of NO. 相似文献
9.
Fabien Fontaine Evan Bolton Yulia Borodina Stephen H Bryant 《Chemistry Central journal》2007,1(1):12-14
Background
Large chemical databases require fast, efficient, and simple ways of looking for similar structures. Although such tasks are now fairly well resolved for graph-based similarity queries, they remain an issue for 3D approaches, particularly for those based on 3D shape overlays. Inspired by a recent technique developed to compare molecular shapes, we designed a hybrid methodology, alignment-recycling, that enables efficient retrieval and alignment of structures with similar 3D shapes. 相似文献10.
Panina N. S. Belyaev A. N. Simanova S. A. 《Russian Journal of General Chemistry》2003,73(12):1835-1838
The most stable hydrolysis products of cis-[Pt(NH3)2(H2O)2]2
+ were revealed by means of DFT quantum-chemical calculations of this complex and its deprotonated forms with full geometry optimization. The resulting force fields and normal mode vibrations were used to calculate thermodynamic characteristics for possible hydrolysis stages and equilibrium constants for proton-transfer processes in the gas phase and in aqueous solutions. The hydroxo-bridged dimers [Pt(NH3)2(-OH)]2
2
+ with short Pt+++Pt distances are the hydrolysis products of platinum(II) cis-diaquadiamminates in the aqueous medium. 相似文献