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1.
Nanostructured LiCoO2 fibers were prepared by the sol-gel related electrospinning technique using metal acetate and citric acid as starting materials. The transformation from the xerogel fibers to the LiCoO2 fibers and the nanostructure of LiCoO2 fibers have been investigated in detail. The LiCoO2 fibers with 500 nm to 2 mum in diameter were composed of polycrystalline nanoparticles in sizes of 20-35 nm. Cyclic voltammetry and charge-discharge experiments were applied to characterize the electrochemical properties of the fibers as cathode materials for lithium-ion batteries. The cyclic voltammogram curves indicated faster diffusion and migration of Li+ cations in the nanostructured LiCoO2 fiber electrode. In the first charge-discharge process, the LiCoO2 fibers showed the initial charge and discharge capacities of 216 and 182 (mA.h)/g, respectively. After the 20th cycle, the discharge capacity decreased to 123 (mA.h)/g. The X-ray diffraction and high-resolution transmission electron microscopy analyses indicated that the large loss of capacity of fiber electrode during the charge-discharge process might mainly result from the dissolution of cobalt and lithium cations escaping from LiCoO2 to form the crystalline Li2CO3 and CoF2 impurities. 相似文献
2.
用恒电位电流衰减法及激光扫描光电化学显微技术研究了在于PH=12.5及13.8的模拟混凝土孔溶液中钢筋钝化化膜的生长动力学及相应的破坏过程,实验结果表明,钢筋钝化膜的生长过程存在两个主要阶段,各阶段膜厚均与生长时间存在正比对数关系,但当t<30秒和t>30秒时,膜的生长表出出不同的动力学特征,在钝化发生点蚀前,钝化膜的微区光电流一定的预兆,腐蚀抑制剂NaNO2影响膜的生长过程及膜厚,能提高钢筋的抗 相似文献
3.
An expeditious cascade protocol for the synthesis of functionalized imidazo[1,2-a]pyridin-3-ols was developed based on the Petasis reaction. With the availability of commercial reagents and high efficiency in expanding molecule diversity, this methodology is superior to the existing procedures for the synthesis of imidazo-pyridin-3-ol analogues. 相似文献
4.
Kernel based visual tracking with scale invariant features 总被引:1,自引:0,他引:1
5.
An effective one-pot synthesis of quinolines bearing diverse C3-piperazinyl functions was developed by using a modified Friedl?nder's protocol. The method not only enables the synthesis of our early reported c-Met inhibitor on a large scale, but also provides a way to generate novel multi-substituted quinolines for further structure-activity relationship (SAR) study. 相似文献
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Yuanxiang Gu Fangfang Jian Wei Yi Jing Wang 《Journal of Macromolecular Science: Physics》2013,52(1):179-187
One-dimensional (1D) fiber structures of simple amphiphilic molecules were prepared through a facile precipitation route. The self-assembly process was studied by ultraviolet-visible absorption and Fourier transform infrared) spectroscopy, which indicated that hydrogen bonding interactions played a role in the1D growth along the axis of the fiber. The water content, self-assembling temperature, and concentration of 1,5-bis-(1-(pyridin-2-yl)ethylidene)thiocarbonohydrazide molecules in the solution had obvious effects on the size and morphology of the self-assembled products. The formation of1D superstructures is not only of a hot subject in the process of nanoscience but also opens a new venue for conveniently controlling self-assembled structures of similar organic molecules. 相似文献
9.
Xiao Yuanxiang Shen Guokang Zheng Weishi Fu Jiajia Fu Feiya Hu Xinyue Jin Ziyi Liu Xiangdong 《Cellulose (London, England)》2022,29(2):1003-1015
Cellulose - We report here a simple and effective method applying a combination of chitosan (Cs) and Cu(II) ion to fabricate antibacterial cotton fabric with a remarkable durability against... 相似文献
10.
Xie Yuanxiang Xu Shuwei Guo Yingxiang Ma Ruichang Ge Yuanxiu Li Zhankui Wang Chunfang Guo Bin Xing Jianping Zhang Tianmei Zhu Shaofei Xu Wang 《中国物理C(英文版)》1997,21(4):289-291
209Fr has been produced by irradiation of 197Au with 16O from SFC accelarator uia the fusion-evaporation 4n channel.The(EC+β+)decay of 209Fr has been studied by a He-jet tape transport system.The decay scheme is proposed for the first time based on γ-t,X-γ-t,γ-γ-t coincidece and γ-γ delay coincidence measurements,which takes account of 20 observed γ ray.Five members of low-lying states in 209Rn can be explained by the multi-plet [(210Rn2+)(νf5/2)-1].The branching ratio for(EC+β+) decay of 209Fr has been estimated experimentaly to be(3.0±1.5)%. 相似文献