首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   742篇
  免费   14篇
  国内免费   4篇
化学   553篇
晶体学   3篇
力学   35篇
数学   53篇
物理学   116篇
  2023年   7篇
  2022年   20篇
  2021年   36篇
  2020年   28篇
  2019年   17篇
  2018年   10篇
  2017年   18篇
  2016年   20篇
  2015年   15篇
  2014年   23篇
  2013年   62篇
  2012年   32篇
  2011年   34篇
  2010年   21篇
  2009年   24篇
  2008年   22篇
  2007年   29篇
  2006年   32篇
  2005年   25篇
  2004年   20篇
  2003年   17篇
  2002年   15篇
  2001年   12篇
  2000年   6篇
  1999年   7篇
  1998年   6篇
  1997年   10篇
  1996年   11篇
  1995年   8篇
  1993年   6篇
  1992年   8篇
  1991年   10篇
  1990年   11篇
  1989年   10篇
  1988年   9篇
  1987年   11篇
  1986年   11篇
  1985年   7篇
  1984年   8篇
  1983年   7篇
  1982年   11篇
  1981年   7篇
  1980年   9篇
  1979年   11篇
  1978年   5篇
  1977年   5篇
  1975年   6篇
  1973年   3篇
  1971年   3篇
  1965年   3篇
排序方式: 共有760条查询结果,搜索用时 15 毫秒
1.
The fractional order evolutionary integral equations have been considered by the first author in [6], the existence, uniqueness and some other properties of the solution have been proved. Here we study the continuation of the solution and its fractional order derivative. Also we study the generality of this problem and prove that the fractional order diffusion problem, the fractional order wave problem and the initial value problem of the equation of evolution are special cases of it. The abstract diffusion-wave problem will be given also as an application.  相似文献   
2.
The shortest-paths problem is a fundamental problem in graph theory and finds diverse applications in various fields. This is why shortest path algorithms have been designed more thoroughly than any other algorithm in graph theory. A large number of optimization problems are mathematically equivalent to the problem of finding shortest paths in a graph. The shortest-path between a pair of vertices is defined as the path with shortest length between the pair of vertices. The shortest path from one vertex to another often gives the best way to route a message between the vertices. This paper presents anO(n 2) time sequential algorithm and anO(n 2/p+logn) time parallel algorithm on EREW PRAM model for solving all pairs shortest paths problem on circular-arc graphs, wherep andn represent respectively the number of processors and the number of vertices of the circular-arc graph.  相似文献   
3.
The systematics of hyperfine magnetic fields at sp impurities on the Z-sites in Co based Heusler alloys are investigated. New TDPAC measurements of Cd hyperfine fields are reported.  相似文献   
4.
Thin films of samples of the glassy SxSe100−x system with 0 ≤ x ≤ 7.28 have been prepared by thermal evaporation technique at room temperature (300 K). X-ray investigations show that the structure of pure selenium (Se) does change seriously by the addition of small amount of sulphur S ≤7.28%. The lattice parameters were determined as a function of sulphur content. Results of differential thermal analysis (DTA) of the glassy compositions of the system SxSe100−x were discussed. The characteristic temperatures (Tg, Tc and Tm) were evaluated. Dark electrical resistivities, ρ, of SxSe100−x thin films with different thicknesses from 100 to 500 nm, were measured in the temperature range from 300 to 423 K. Two distinct linear parts with different activation energies were observed. The variation of electrical resistivity of examined compositions has been discussed as a function of the film thickness, temperature and the sulphur content. The application of Mott model for the phonon assisted hopping of small polarons gave the same two activation energies obtained from the resistivity temperature calculations.  相似文献   
5.
Transient creep of Cd-2 wt. % Zn and Cd-17·4 wt. % Zn alloys has been studied under different constant stresses ranging from 6·4 MPa to 12·7 MPa near the transformation temperature. The results of both compositions showed two transient deformation regions, the low temperature region (below 483 K) and the high temperature region (above 483 K). From the transient creep described by the equation tr=Bt n, where tr andt are the transient creep strain and time. The parametersB andn were calculated. The parameterB was found to change with the applied stress from 0·3×10–4 to 3×10–4 and from 0·6×10–4 to 18×10–4 for Cd-2 wt. % Zn and Cd-17·4 wt. % Zn, respectively. The exponentn was found to change from 0·8 to 0·95 for both alloys. The parameterB was related to the steady state creep rate through the equation , the exponent was found to be 0·5 for Cd-2 wt. % Zn and 0·6 for the eutectic composition. The activation energies of transient creep in the vicinity of the transformation regions (above 483 K) were found to be 50·2 kJ/mole for Cd-2 wt. % Zn and 104·7 kJ/mole for the eutectic composition characterizing the mechanisms of grain boundary diffusion and volume diffusion in Cd, respectively.  相似文献   
6.
7.
The reaction of piperidine, morpholine, piperazine or dimethylamine with several coumarins, 3-bromocoumarin, 4,6-diaryl-2H-pyran-2-ones and 3-bromo-4,6-diaryl-2H-thiopyran-2-ones gave o-hydroxycinnamic acid amides, benzofurans, open-chain δ-oxoamides and thiophene derivatives, respectively.  相似文献   
8.
Mupirocin, a polyketide-derived antibiotic from Pseudomonas fluorescens NCIMB10586, is a mixture of pseudomonic acids (PA) that target isoleucyl-tRNA synthase. The mup gene cluster encodes both type I polyketide synthases and monofunctional enzymes that should play a role during the conversion of the product of the polyketide synthase into the active antibiotic (tailoring). By in-frame deletion analysis of selected tailoring open-reading frames we show that mupQ, mupS, mupT, and mupW are essential for mupirocin production, whereas mupO, mupU, mupV, and macpE are essential for production of PA-A but not PA-B. Therefore, PA-B is not simply produced by hydroxylation of PA-A but is either a precursor of PA-A or a shunt product. In the mupW mutant, a new metabolite lacking the tetrahydropyran ring is produced, implicating mupW in oxidation of the 16-methyl group.  相似文献   
9.
Summary. The magnetic and microstructure properties of Fe2O3–0.4NiO–0.6ZnO–B2O3 glass system, which was subjected to heat treatment in order to induce a magnetic crystalline phase (Ni0.4Zn0.6-Fe2O4 crystals) within the glass matrix, were investigated. DSC measurement was performed to reveal the crystallization temperature of the prepared glass sample. The obtained samples, produced by heat treatment at 765°C for various times (1, 1.5, 2, and 3 h), were characterized by X-ray diffraction, IR spectra, transmission electron microscopy, and vibrating sample magnetometer. The results indicated the formation of spinel Ni–Zn ferrite in the glass matrix. Particles of the ferrite with sizes ranging from 28 to 120 nm depending on the sintering time were observed. The coercivity values for different heat-treatment samples were found to be in the range from 15.2 to 100 Oe. The combination of zinc content and sintering times leads to samples with saturation magnetization ranging from 12.25 to 17.82 emu/g.  相似文献   
10.
In bicelle bacteriorhodopsin (bcbR) crystals, the protein has a different structure from both native bacteriorhodopsin (bR) and in-cubo bR (cbR) crystals. Recently, we studied the ability of bcbR crystals to undergo the photocycle upon laser excitation, characterized by the appearance of the M intermediate by single crystal resonance Raman spectroscopy. Calculation of the M lifetime by flash photolysis experiments demonstrated that in our bcbR crystals, the M rise time is much faster than in the native or cbR crystals, with a decay time that is much slower than these other two forms. Although it is now known that the bcbR crystals are capable of photochemical deprotonation, it is not known whether photochemical deprotonation is the only way to create the deprotonated Schiff base in the bcbR crystals. We measured both the visible and Raman spectra of crystals dried under ambient lighting and dried in the dark in order to determine whether the retinal Schiff base is able to thermally deprotonate in the dark. In addition, changes in the visible spectrum of single bcbR crystals under varying degrees of hydration and light exposure were examined to better understand the retinal binding environment.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号