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1.
A simple pre-irradiation procedure for the separation of iodine from soil has been developed. A soil sample was heated in a quartz tube for 15 min at about 900 °C. The evaporated iodine was collected in activated charcoal, which was produced from phenol resin with low impurities. The charcoal, with sorbed iodine, was irradiated by neutrons and the128I produced was measured. A successful elimination of the background radioactivity due to the matrix elements was possible with this separation procedure. The detection limit by this method for soil samples was about 0.1 mg/kg (dry). The method has been applied to analyze selected soil samples. 相似文献
2.
3.
Masakazu Muramatsu 《Mathematical Programming》1998,83(1-3):393-406
In this paper, we introduce an affine scaling algorithm for semidefinite programming (SDP), and give an example of a semidefinite
program such that the affine scaling algorithm converges to a non-optimal point. Both our program and its dual have interior
feasible solutions and unique optimal solutions which satisfy strict complementarity, and they are non-degenerate everywhere. 相似文献
4.
In this paper, we treat a domain optimization problem in which the boundary-value problem is a Neumann problem. In the case where the domain is in a three-dimensional Euclidean space, the first-order and the second-order necessary conditions which the optimal domain must satisfy are derived under a constraint which is the generalization of the requisite of constant volume.Portions of this paper were presented at the 13th IFIP Conference on System Modelling and Optimization, Tokyo, Japan, 1987. 相似文献
5.
6.
A novel type of heterogenized CuCl2 catalysts was designed for the oxidative carbonylation of methanol to dimethyl carbonate (DMC) taking account of the plausible reaction mechanism and intermediates. To prevent severe corrosion of the reaction equipment materials due to Cl– while keeping the catalytic activity of the homogeneous CuCl2 catalyst, we adopted, as supports (or ligands) of CuCl2, four polymers, bearing a 2,2-bipyridine (bpy) or pyridine (py) unit, namely, poly(2,2-bipyridine-5,5-diyl) (Pbpy), poly(pyridine-2,5-diyl) (Ppy), poly(N,N-bisphenylene-2,2-bipyridine-4,4-dicarboxylic amide) (Bpya), and poly(4-methyl-4-vinyl-2,2-bipyridine) (Pvbpy), together with one chelate compound, 8-quinolinol. The catalytic activity, stability of heterogenized CuCl2 and their corrosivities to stainless steels were examined in the liquid-phase reaction of the oxidative carbonylation of methanol. These polymer-supported catalysts showed considerable catalytic activity and stability for the DMC synthesis. In particular, the Pbpy-CuCl2 and Ppy-CuCl2 catalysts exhibited high DMC yields and selectivity comparable to those of the homogeneous CuCl2 catalyst. This high activity appears to be associated with the presence of the -conjugated system in the polymers, which affect the redox reactions of Cu involved in the catalytic reaction. All of the polymer-supported CuCl2 catalysts could be easily recycled after filtration, and the initial catalytic activity was maintained after three times of use. The corrosive characters of the catalysts were closely related to CuCl2 leaching from the supports, which reflects the ability of supports to coordinate Cu. These experimental results suggest that both the electronic structure and the coordination ability of the polymer supports are key factors for the development of an effective catalytic system. 相似文献
7.
In order to assess the levels and behavior of129I (half-life: 1.6×107 y) and127I (stable) in the environment, we have developed analytical procedures involving neutron activation analysis (NAA). Environmental samples collected around Tokaimura, Ibaraki Prefecture, Japan, have been analyzed using this method. Ranges of129I and127I concentrations in surface soil were 0.9–180 mBq kg–1 and 1–60 mg kg–1, respectively. Higher129I concentrations were found in soil samples collected from coniferous forests, suggesting a contribution from tree canopies in the deposition of this nuclide. Most of the129I in soil, was found to be retained in the first 10 cm. The129I/127I ratios in wheat fields were lower than those in rice paddy fields.A soil sample collected by IAEA from an area contaminated by the Chemobyl accident was also determined. The129I concentration and the129I/127I ratio were 1.6 mBq kg–1 and 1.7×10–7, respectively. The129I level in this sample was higher than the values obtained in areas far from nuclear facilities in Japan. It was suggested that the analysis of129I in soils in the Chernobyl area may be useful in evaluating the131I levels at the time of the accident.Analyses of129I and127I by ICP-MS in water samples were also made. The analytical speed of this method was very high, i.e., 3 minutes for a sample. However, there is a sensitivity limitation for129I detection due to interference from129Xe with the129I peak. The detection limits for129I and127I in water samples were about 0.5 mBq ml–1 and 0.1 ng ml–1, respectively. 相似文献
8.
Y. Muramatsu Y. Ohmomo D. Christoffers 《Journal of Radioanalytical and Nuclear Chemistry》1984,82(2):353-361
The possibilities of reactor induced (n, p) reactions as a tool for neutron activation analysis of titanium in geological samples are discussed. The interference of calcium and scandium is experimentally evaluated. Results for Ti, Ca and Sc in GSP-1 and PCC-1 standard rocks are presented. On the basis of the experimental values, it is concluded that the47Ti(n, p)47Sc reaction is the most favourable for titanium determination. 相似文献
9.
(Z)- and (E)-2-Ethoxyperfluoro-2-(phenylselenenyl)alk-2-enenitriles 2-4 prepared by our original method underwent transmetalation on treatment with n-BuLi or EtMgBr, and the successive reaction with aldehyde and ketones afforded the corresponding allylic alcohols 10a-f, 9a, and 11a,b in good to high yields. Hydrolysis of the alcohols gave alpha-cyano-alpha,beta-unsaturated perfluoroalkyl ketones 13a-c, 13e, 12a, and 15a. alpha-Cyanoperfluoroalkyl ketones were easily converted to alpha,beta-unsaturated 3-aryl-2-cyanoallylic alcohols 18-22 having interesting biological activities and chemical reactivities. 相似文献
10.
Acetophenone photo-sensitized addition of indene to cyclic fluoro-olefins (1,2-dichlorohexafluorocyclopentene-1, 1,2-dichlorotetrafluorocyclobutene-1 and hexafluorocyclobutene) gave the corresponding cycloadducts in satisfactory yields. The cycloadducts obtained predominantly had exo configuration.Some reactions such as reduction, oxidation, dechlorination and halogenation, of the cycloadducts were also studied. 相似文献