电站锅炉系统性能仿真模型的建立

1引言根据热力学第二定律，燃料中的化学拥将近一半损失在锅炉的燃烧与传热过程中。因此，优化锅炉性能对降低整个火电机组的煤耗率具有明显效果。完整的锅炉系统由磨煤机、送风机、一次风机、弓讯机、炉膛、汽包、过热器、再热器、省煤器、空气预热器等单元组成，这些单元之间的联结错综复杂。本文建立了锅炉系统中通用单元的性能模型，并在此基础上，对锅炉系统的结构特点进行了分析，利用过程系统工程中的序贯模块法建立了整个锅炉系统的性能模型。对单元的划分、回路的切断及断裂流股的收敛与迭代策略提出了自己的观点。最后根据生产厂…     

两相滴定法研究2-乙基己基膦酸单2-乙基己基酯从盐酸介质中萃取钕(Ⅲ)的动力学

本文利用两相滴定法作为分析手段,用恒界面池搅拌法考察了多种因素对2-乙基己基膦酸单2-乙基己基酯(HEHEHP,HA)从盐酸介质中萃取Nd(Ⅲ)动力学的影响,从实验结果推论出萃取过程为界面化学反应控制型机理。     

"Volatilizable" supports for high-throughput organic synthesis

The concepts and use of "volatilizable" solid supports are presented. Such supports, which are completely removed by volatilization following decomposition, improve the efficiency of the solid-phase synthesis of both individual and mixtures of low-molecular weight acyclic and heterocyclic compounds as well as peptides, peptidomimetics, and protected peptide fragments. The "volatilizable" silica-based solid supports and linkers used to illustrate this concept were found to be completely removed by their decomposition and ultimate "volatilization" during the final cleavage step of synthetic process to yield solely the desired synthetic product(s) in the final reaction vessel.     

富氮多孔有机聚合物催化制备α⁃氰基肉桂酸乙酯

α-氰基肉桂酸乙酯作为含多种官能团的缺电子烯烃, 是一种极具应用价值的有机合成反应底物, 主要通过催化Knoevenagel缩合反应获得. 本文以多聚甲醛和三聚氰胺为前驱体, 采用溶剂热法制备富氮多孔有机聚合物mPMF, 经K₂CO₃处理得到K₂CO₃-mPMF-X(X=1, 10, 50). 考察了mPMF在苯甲醛和氰乙酸乙酯Knoevenagel缩合反应中的催化性能, 通过mPMF与K₂CO₃-mPMF-X催化活性的比较, 探讨了碱性强弱对Knoevenagel缩合反应的影响, 并对催化反应机理进行了探索. 结果表明, 催化剂中丰富的氮物种为反应提供了碱性环境和大量的碱性活性位点, 催化剂碱性强弱的控制是催化合成α-氰基肉桂酸乙酯的关键因素. mPMF在甲醇溶剂中于60 ℃反应3 h后, 苯甲醛转化率为97%, 目标产物选择性在99.9%以上.     

Pressure-Suppressed Carrier Trapping Leads to Enhanced Emission in Two-Dimensional Perovskite (HA)2(GA)Pb2I7

A remarkable PL enhancement by 12 fold is achieved using pressure to modulate the structure of a recently developed 2D perovskite (HA)₂(GA)Pb₂I₇ (HA=n-hexylammonium, GA=guanidinium). This structure features a previously unattainable, extremely large cage. In situ structural, spectroscopic, and theoretical analyses reveal that lattice compression under a mild pressure within 1.6 GPa considerably suppresses the carrier trapping, leading to significantly enhanced emission. Further pressurization induces a non-luminescent amorphous yellow phase, which is retained and exhibits a continuously increasing band gap during decompression. When the pressure is released to 1.5 GPa, emission can be triggered by above-band gap laser irradiation, accompanied by a color change from yellow to orange. The obtained orange phase could be retained at ambient conditions and exhibits two-fold higher PL emission compared with the pristine (HA)₂(GA)Pb₂I₇.     

A Low‐Cost and Environmentally Friendly Mixed Polyanionic Cathode for Sodium‐Ion Storage

Sodium‐ion batteries (NIBs) are the most promising alternatives to lithium‐ion batteries in the development of renewable energy sources. The advancement of NIBs depends on the exploration of new electrode materials and fundamental understanding of working mechanisms. Herein, via experimental and simulation methods, we develop a mixed polyanionic compound, Na₂Fe(C₂O₄)SO₄?H₂O, as a cathode for NIBs. Thanks to its rigid three dimensional framework and the combined inductive effects from oxalate and sulfate, it delivered reversible Na insertion/desertion at average discharging voltages of 3.5 and 3.1 V for 500 cycles with Coulombic efficiencies of ca. 99 %. In situ synchrotron X‐ray measurements and DFT calculations demonstrate the Fe²⁺/Fe³⁺ redox reactions contribute to electron compensation during Na⁺ desertion/insertion. The study suggests mixed polyanionic frameworks may provide promising materials for Na ion storage with the merits of low cost and environmental friendliness.     

Optimization of Flavonoid Extraction from Xanthoceras sorbifolia Bunge Flowers,and the Antioxidant and Antibacterial Capacity of the Extract

In the present work, the extraction process of total flavonoids (TFs) from X. sorbifolia flowers by ultrasound-assisted extraction was optimized under the response surface methodology (RSM) on the basis of single-factor experiments. The optimal extraction conditions were as follows: ethanol concentration of 80%, solid–liquid ratio of 1:37 (g/mL), temperature of 84 °C, and extraction time of 1 h. Under the optimized conditions, the extraction yield of the TFs was 3.956 ± 0.04%. The radical scavenging capacities of TFs against 2,2-diphenyl-1-picrylhydrazyl (DPPH) and 2,2-azino-bis(3-ethylbenzothiazoline-6-sulphonic acid) (ABTS) were much greater than that of rutin. The results of antibacterial experiments indicated that the TFs displayed strong inhibitory activities on E. coli, S. aureus and Bacillus subtilis. Therefore, X. sorbifolia flowers can be used as a novel source of natural flavonoids, and the TFs have potential applications as natural antioxidants or antibacterial agents in the food and pharmaceutical industries.     

含非完整界面的功能梯度压电材料Ⅲ型裂纹问题

本文研究了含非完整界面的功能梯度压电复合材料的Ⅲ型裂纹问题．此裂纹垂直于非完整界面,采用弹簧型力电耦合界面模型模拟非完整界面．界面两侧材料的性质,如弹性模量、压电常数和介电常数均假定呈指数函数形式且沿着裂纹方向变化．运用积分变换法将裂纹面条件转换为奇异积分方程,并使用Gauss-Chebyshev方法对其进行数值求解．根据算例结果讨论了一些退化问题并分析了裂纹尖端强度因子与材料的非均匀系数和非完整界面参数的关系．     

功能铁磁材料的变形与断裂的研究进展

综述了近几十年, 特别是近十几年来铁磁材料的力磁耦合变形与断裂行为的研究概况. 传统铁磁弹性问题的研究已经有较长时间的积累, 文献中已有大量的研究结果发表. 近些年 来, 随着智能材料及结构应用与研究的兴起, 功能铁磁材料如稀土超磁致伸缩材料、铁磁相 变材料以及铁磁复合材料等的力学行为越来越受到重视, 人们在功能铁磁材料的变形与断裂 以及铁磁复合材料的有效性质等方面开展了大量的研究工作. 本文在简单介绍了经典铁磁弹 性和传统铁磁结构的力磁性能的研究背景基础上, 结合作者近年来在铁磁材料变形与断裂方 面所开展的工作, 着重评述了功能软铁磁材料在变形与断裂的实验研究,如实验设备和技术, 以及铁磁复合材料细观力学、软铁磁材料、铁磁功能材料的变形与断裂理论等方面的研究进 展, 并指出了需要进一步研究的方向.