全文获取类型
收费全文 | 1677篇 |
免费 | 136篇 |
国内免费 | 100篇 |
专业分类
化学 | 1205篇 |
晶体学 | 36篇 |
力学 | 60篇 |
综合类 | 4篇 |
数学 | 181篇 |
物理学 | 427篇 |
出版年
2023年 | 18篇 |
2022年 | 35篇 |
2021年 | 42篇 |
2020年 | 37篇 |
2019年 | 43篇 |
2018年 | 38篇 |
2017年 | 33篇 |
2016年 | 50篇 |
2015年 | 57篇 |
2014年 | 80篇 |
2013年 | 114篇 |
2012年 | 122篇 |
2011年 | 132篇 |
2010年 | 91篇 |
2009年 | 57篇 |
2008年 | 94篇 |
2007年 | 94篇 |
2006年 | 94篇 |
2005年 | 76篇 |
2004年 | 77篇 |
2003年 | 51篇 |
2002年 | 48篇 |
2001年 | 29篇 |
2000年 | 31篇 |
1999年 | 22篇 |
1998年 | 17篇 |
1997年 | 25篇 |
1996年 | 21篇 |
1995年 | 18篇 |
1994年 | 14篇 |
1993年 | 13篇 |
1992年 | 18篇 |
1991年 | 11篇 |
1990年 | 15篇 |
1989年 | 12篇 |
1988年 | 10篇 |
1987年 | 6篇 |
1986年 | 9篇 |
1985年 | 13篇 |
1984年 | 13篇 |
1983年 | 6篇 |
1982年 | 12篇 |
1981年 | 16篇 |
1980年 | 28篇 |
1979年 | 11篇 |
1978年 | 5篇 |
1977年 | 10篇 |
1976年 | 5篇 |
1974年 | 7篇 |
1973年 | 7篇 |
排序方式: 共有1913条查询结果,搜索用时 46 毫秒
1.
2.
3.
Kan Wakamatsu 《Tetrahedron letters》2004,45(24):4627-4630
Photochemical [2+2]cycloaddition between electron-donating aryl isocyanates and chloranil was observed in acetonitrile or benzene, and the following elimination of carbon dioxide resulted in the formation of the corresponding quinone imine dyes. This new route for synthesis of quinone imine was investigated by product analyses, laser flash photolyses, and molecular orbital calculation. 相似文献
4.
5.
6.
Kan Hachiya 《Journal of Non》2003,321(3):217-224
First-principles calculations of the electronic structures of the wrong bonds were performed for amorphous germanium sulphides in order to explain their compositional dependence. Model cluster calculations of the density of states using a set of geometry similar to the crystalline-GeS2 coordination can reproduce the peak structure of the experimental valence band photoemission spectra. The bonding and anti-bonding states of the covalent Ge-S bonds form valence and conduction band respectively, and the top of the valence band is occupied with S 3p lone-pair states. The bonding states are modified by S-S bonds and the anti-bonding states are modified by Ge-Ge bonds, mainly through their hybridization with the wrong-bond states between p-orbitals. The lone-pair states do not interact either of them to form a different band, and obscure the modification induced by the S-S wrong bonds. Therefore, we can conclude that the narrowing of the bandgap with increasing Ge content from GeS2 composition is due to that of the conduction-band bottom with increasing germanium wrong bonds, though the narrowing with increasing S content is moderate due to the presence of the lone-pair states at the valence-band top. 相似文献
7.
Photochemical deprotection of nitro-substituted benzenesulfenates via photoinduced electron transfer
Kan Wakamatsu Mitsuru Kouda Kazuyoshi Shimaoka Haruo Yamada 《Tetrahedron letters》2004,45(34):6395-6398
The photochemical deprotection of alkyl 2,4-dinitrobenzenesulfenate or alkyl 2-nitrobenzenesulfenate was successfully achieved by addition of triethylamine, while it was unsuccessful without triethylamine. The sulfur-oxygen bond cleavage is thought to occur heterolytically in the sulfenate anion radical produced by photoinduced electron transfer with triethylamine. 相似文献
8.
Thiraporn Charoenraks Suchada Chuanuwatanakul Kensuke Honda Yoko Yamaguchi Orawon Chailapakul 《Analytical sciences》2005,21(3):241-245
The analysis of tetracycline, oxytetracyline, chlortetracycline and doxycycline by high-performance liquid chromatography with pulsed amperometric detection using an anodized boron-doped diamond thin film (BDD) electrode is originally reported. The analyses were carried out using the mobile phase, phosphate buffer (0.01 M, pH 2.5)-acetonitrile (80:20; v/v), on a C18 column (250 x 4.6 mm i.d., 5 microm) at a flow rate of 1.0 mL/min. The optimal PAD waveform parameters at the anodized BDD were 1.5 V (versus Ag/AgCl) detection potential (E(det)) for 290 ms (200 ms delay time and 90 ms integration time), 2.0 V (versus Ag/AgCl) oxidation potential (E(oxd)) for 200 ms oxidation time (t(oxd)) and 0.4 V (versus Ag/AgCI) reduction potential (E(red)) for 200 ms reduction time (t(red)). The proposed method showed the simultaneous determination of tetracycline, oxytetracyline, chlortetracycline and doxycycline with a linear range of 0.1 - 100 microg/mL, detection limits of 0.05 - 0.1 microg/mL and recoveries of 70.8 - 96.0%. The application of this method to real samples was demonstrated and validated using a shrimp sample. 相似文献
9.
Kan‐Yi Pu Yi Chen Xiao‐Ying Qi Chun‐Yang Qin Qing‐Quan Chen Hong‐Yu Wang Yun Deng Qu‐Li Fan Yan‐Qin Huang Shu‐Juan Liu Wei Wei Bo Peng Wei Huang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(16):3776-3787
In this contribution, we demonstrate a new effective methodology for constructing highly efficient and durable poly(p‐phenyleneethynylene) (PPE) containing emissive material with nonaggregating and hole‐facilitating properties through the introduction of hole‐transporting blocks into the PPE system as the grafting coils as well as building the energy donor–acceptor architecture between the grafting coils and the PPE backbone. Poly(2‐(carbazol‐9‐yl)ethyl methacrylate) (PCzEMA), herein, is chosen as the hole‐transporting blocks, and incorporated into the PPE system as the grafting coils via atom transfer radical polymerization. The chemical structure of the resultant copolymer, PPE‐g‐PCzEMA, was characterized by NMR and gel permeation chromatography, showing that the desirable copolymer was obtained with the narrow polydispersity. The increased thermal stability of PPE‐g‐PCzEMA was confirmed by thermogravimetric analysis and differential scanning calorimetry along with its macroinitiator. The optoelectronic properties of this copolymer were studied in detail by ultraviolet‐visible absorption, photoluminescence emission and excitation spectra, and cyclic voltammogram (CV). The results indicate that PPE‐g‐PCzEMA exhibits the solid‐state luminescent property dominated by individual lumophores, and also the energy transfer process from the PCzEMA blocks to the PPE backbone with a relatively higher energy transfer efficiency in the solid‐state compared to that of the solution state. Additionally, the hole‐injection property is greatly facilitated due to the presence of PCzEMA, as confirmed by CV profiles. All these data indicate that PPE‐g‐PCzEMA is a good candidate for use in optoelectronic devices. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3776–3787, 2007 相似文献
10.
According to the concept of the recognized visual space of illumination (RVSI) the lightness of an object surface is perceived in relation to its conceptualized size. To prove this proposition the lightness of gray test patches was judged when they were located at various positions inside an illuminated space composed of two rooms in the depth direction from a subject. No retinal image arrangement was changed in the test patch and its immediate surroundings, but the front room had walls, floors and furniture lower in lightness by the amount of N1.5 than the back room to make the RVSI of the former smaller despite the illuminance in the entire space being the same. The results showed that the apparent lightness of the patches was perceived higher by amount of about 13 in L units for the N4 test patch and about 20 for N6 when the patches were located in the front room, in accordance with the prediction. It was stressed that the experiment of lightness judgment should be conducted in a three dimensional space rather than two dimensional plane as done by several investigators. 相似文献