全文获取类型
收费全文 | 57篇 |
免费 | 3篇 |
国内免费 | 8篇 |
专业分类
化学 | 45篇 |
晶体学 | 1篇 |
力学 | 2篇 |
数学 | 12篇 |
物理学 | 8篇 |
出版年
2023年 | 4篇 |
2022年 | 5篇 |
2021年 | 2篇 |
2020年 | 4篇 |
2019年 | 8篇 |
2018年 | 5篇 |
2017年 | 1篇 |
2016年 | 1篇 |
2015年 | 7篇 |
2014年 | 3篇 |
2013年 | 2篇 |
2012年 | 2篇 |
2011年 | 5篇 |
2010年 | 4篇 |
2009年 | 1篇 |
2008年 | 2篇 |
2007年 | 1篇 |
2006年 | 2篇 |
2002年 | 1篇 |
2001年 | 1篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1990年 | 1篇 |
1984年 | 1篇 |
1982年 | 1篇 |
排序方式: 共有68条查询结果,搜索用时 31 毫秒
1.
Huwei Liu Shize Qi Yingnan Zhang Aijin Huang Yiliang Sun 《Journal of separation science》1997,20(4):242-244
A capillary zone clectrophoresis method was developed for the determination of IMP and GIMP, commonly used as flavor enhancers in poultry feed, in a real sample of complex composition. A baseline separation of inosine 5′-monophosphate and guanosine 5′-monophosphate was achieved within 10 min and the other components in the sample did not interfere with the separation. Quantitative results obtained from pig feed samples are presented. The separation conditions and experimental reproducibility are also discussed. 相似文献
2.
Dan Lu Weiyang Zhang Yingnan Jiang Yu Zhang Dabo Pan Dan Zhang 《Natural product research》2019,33(19):2789-2794
A new cycloartane triterpenoid, named gardenolic acid C (1), a new ursane triterpenoid, named 3β,16β,21β,23,24-pentahydroxy urs-12,18,20-trien-28-oic acid γ-lactone (2), together with three know triterpenoids, gardenolic acid A (3), gardenolic acid B (4), and 3α,16β,23,24-tetrahydroxy-28-nor-ursane-12,17,19,21-tetraen (5) were isolated from the fruits of Gardenia jasminoides Ellis. The structures of these compounds were elucidated by analyses of spectroscopic data. All isolates were evaluated for their neuroprotective effects in vitro.
3.
4.
本文引进发生函数矩阵与同构向量两个概念,利用它们讨论了与Scheffè单纯形—中心设计有关的0-1矩阵的一些性质。在I_(λ-)最优观测配置的分块算法的基础上,本文给出了q分量n阶广义单纯形—中心设计I_(λ-)最优观测频数的一般解析表达式。 相似文献
5.
Wang Y Dai Q Zou B Yu WW Liu B Zou G 《Langmuir : the ACS journal of surfaces and colloids》2010,26(24):19129-19135
In comparison to the previous lengthy approaches, we described a general and simple strategy for engineering the superlattice assembly of IV-VI semiconductor nanocrystals (NCs) with tunable sizes and morphologies. Not only the well-studied spherical NCs but also some special-shaped NCs, such as the quasi-cubic, cubic, truncated octahedral, and octahedral, could self-assemble into well-ordered patterns, as demonstrated in PbS, PbSe, and PbTe. These results extended our proposed model about the configuration of ligand chains in the superlattice assembly. This powerful capability of assembling superlattices was dominated by a heat-treatment process, providing a significant and extensive direction in the engineering of morphology-tunable NC superlattices. 相似文献
6.
7.
8.
In this paper, we analyze and characterize the cone of nonsymmetric positive semidefinite matrices (NS-psd). Firstly, we study basic properties of the geometry of the NS-psd cone and show that it is a hyperbolic but not homogeneous cone. Secondly, we prove that the NS-psd cone is a maximal convex subcone of P0-matrix cone which is not convex. But the interior of the NS-psd cone is not a maximal convex subcone of P-matrix cone. As the byproducts, some new sufficient and necessary conditions for a nonsymmetric matrix to be positive semidefinite are given. Finally, we present some properties of metric projection onto the NS-psd cone. 相似文献
9.
Yingjun Sun Dr. Yingjie Li Yingnan Qin Prof. Lei Wang Prof. Shaojun Guo 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(18):4032-4038
Searching for new anti-poisoning Pt-based catalysts with enhanced activity for alcohol oxidation is the key in direct alcohol fuel cells (DAFCs). However, in the traditional strategy for designing bimetallic or multimetallic alloy is still difficult to achieve a satisfactory heterogeneous electrocatalyst because the activity often depends on only the surface atoms. Herein, we fabricate the multicomponent active sites by creating a sulfide structure on 1D PtNiCo trimetallic nanowires (NWs), to give a PtNiCo/NiCoS interface NWs (IFNWs). Owing to the presence of sulfide interfaces, the PtNiCo/NiCoS IFNWs enable an impressive methanol/ethanol oxidation reaction (MOR/EOR) performance and excellent anti-CO poisoning tolerance. They have the MOR and EOR mass activities of 2.25 Amg-1Pt and 1.62 Amg-1Pt, around 1.26, 3.21 and 1.46, 2.96 times higher than those of PtNiCo NWs and commercial Pt/C, respectively. CO-stripping and XPS measurements further demonstrate that the new interfacial structure and optimal bonding of Pt−CO can result in accelerating the removal of surface adsorbed carbonaceous intermediates. Moreover, such a unique structure has also demonstrated a much-improved ability for the electrochemical detection of some important molecules (H2O2 and NH2NH2). 相似文献
10.
Multiresidue determination of 114 multiclass pesticides in flue‐cured tobacco by solid‐phase extraction coupled with gas chromatography and tandem mass spectrometry
下载免费PDF全文
![点击此处可从《Journal of separation science》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Jianmin Cao Weisong Yu Xueli Pang Yingnan Lin Jun Qiu 《Journal of separation science》2016,39(23):4629-4636
A sensitive and robust multiresidue method for the simultaneous analysis of 114 pesticides in tobacco was developed based on solid‐phase extraction coupled with gas chromatography and tandem mass spectrometry. In this strategy, tobacco samples were extracted with acetonitrile and cleaned up with a multilayer solid‐phase extraction cartridge Cleanert TPT using acetonitrile/toluene (3:1) as the elution solvent. Two internal standards of different polarity were used to meet simultaneous pesticides quantification demands in the tobacco matrix. Satisfactory linearity in the range of 10–500 ng/mL was obtained for all 114 pesticides with linear regression coefficients higher than 0.994. The limit of detection and limit of quantification values were 0.02–5.27 and 0.06–17.6 ng/g, respectively. For most of the pesticides, acceptable recoveries in the range of 70–120% and repeatabilities (relative standard deviation) of <11% were achieved at spiking levels of 20, 100, and 400 ng/g. Compared with the reported multiresidue analytical method, the proposed method provided a cleaner test solution with smaller amounts of pigments, fatty acids as well as other undesirable interferences. The development and validation of the high sensitivity, high selectivity, easy automation, and high‐throughput analytical method meant that it could be successfully used for the determination of pesticides in tobacco samples. 相似文献