A NOVEL EOR POLYMER (Ⅱ)——INVESTIGATION ON IN-SITU GELATION OF SMRF SYSTEM IN BEREA CORE

In-situ gelation of aqueous sulfomethylated resorcinol formaldehyde (SMRF) system inBerea core has been investigated. Two sets of displacement experiments were conducted with thissystem (containing 5% NaCl, 0. 036% CaCl_2. 2H_2O). The brine permeabilities of the coreswere reduced significantly from about 600 to 0.1 md. The in-situ gelation in Berea core occurreda little bit earlier than gelation anticipated from bulk test in the experiments. The gel time waseasier to control at initial pH between 6 and 8. During injection of SMRF system, the apparentviscosity was less than 1 mPa·s at 41℃.     

Unbridged bidentate aluminum complexes supported by diaroylhydrazone ligands: Synthesis,structure and catalysis in polymerization of ε-caprolactone and lactides

A series of novel diaroylhydrazone aluminum complexes have been synthesized and well-defined structurally, and their catalytic performance in the polymerization of ε-caprolactone and lactides have also been evaluated. Complexes [(L^1–4)₂AlMe] ( 1 – 4 ) {[L¹ = (3,5-^tBu₂–2-OMe-C₆H₂)CH=NNCOC₆H₅], [L² = (3,5-^tBu₂–2-OMe-C₆H₂)CH=NNCO(C₆H₄–4-OCH₃)], [L³ = (3,5-^tBu₂–2-OMe-C₆H₂)CH=NNCO(C₆H₄–4-Br)] and [L⁴ = (2-OMe-C₆H₄)CH=NNCO(C₆H₄–4-^tBu)]} were prepared through treatment of AlMe₃ with the corresponding proligands L^1–4H in molar ratios of 1: 1 or 1: 2. Chemical structures of all the complexes were well-defined by elemental analysis, NMR spectra as well as single-crystal X-ray study. Complexes [(L^1–4)₂AlMe] ( 1 – 4 ) in this work represent the first examples of aluminum complexes of aroylhydrazone ligands with crystallographic characterization. Specifically, they are all in monomeric form with a penta-coordinated aluminum center, including two approximately co-planar five-membered metallacycles with aluminum. Introduced bulky tert-butyl substituents in aroylhydrazone ligands could affect the geometry around the central metal which is a distorted square-based pyramid in complexes 1 – 3 while being a trigonal bipyramidal in complex 4 , thus affecting their catalytic behaviors. The complexes can successfully catalyze the ring-opening polymerization of ε-caprolactone and _L-lactide under mild conditions without any activator. In addition, complexes 1 – 4 could also polymerize rac-lactide, affording atactic polylactides with high conversions and good controllability in relatively short reaction time.     

旋光性高分子的合成（下）

旋光性高分子的合成（下）刘引烽，华家栋（上海科技大学化学系，上海，２０１８００）４不对称聚合由外消旋手性单体制备旋光性高分子必须通过选择性聚合才能实现。选择性聚合是指外消旋的两个对映异构单体进行聚合时，由于体系中存在着某种不对称的诱导因素，其中之一比...     

A new feruloyl amide derivative from the fruits of Tribulus terrestris

A new feruloyl amide derivative, named tribulusamide C, was isolated from the fruits of Tribulus terrestris. Its structure was determined on the basis of spectroscopic analysis including IR, 1-D-, 2-D-NMR and HR-ESI-MS. The structure of tribulusamide C was characterised by a unit of pyrrolidine-2,5-dione, which distinguished it from other lignanamides previously isolated from the fruits of T. terrestris.     

A higher‐order accuracy lattice Boltzmann model for the wave equation

A lattice Boltzmann model with higher‐order accuracy for the wave motion is proposed. The new model is based on the technique of the higher‐order moment of equilibrium distribution functions and a series of lattice Boltzmann equations in different time scales. The forms of moments are derived from the binary wave equation by designing the higher‐order dissipation and dispersion terms. The numerical results agree well with classical ones. Copyright © 2008 John Wiley & Sons, Ltd.     

On consistency measures of linguistic preference relations

Inspired by the concept of deviation measure between two linguistic preference relations, this paper further defines the deviation measure of a linguistic preference relation to the set of consistent linguistic preference relations. Based on this, we present a consistency index of linguistic preference relations and develop a consistency measure method for linguistic preference relations. This method is performed to ensure that the decision maker is being neither random nor illogical in his or her pairwise comparisons using the linguistic label set. Using this consistency measure, we discuss how to deal with inconsistency in linguistic preference relations, and also investigate the consistency properties of collective linguistic preference relations. These results are of vital importance for group decision making with linguistic preference relations.     

A lattice Boltzmann model for the compressible Euler equations with second‐order accuracy

In this paper, we propose a new lattice Boltzmann model for the compressible Euler equations. The model is based on a three‐energy‐level and three‐speed lattice Boltzmann equation by using a method of higher moments of the equilibrium distribution functions. In order to obtain second‐order accuracy, we employ the ghost field distribution functions to remove the non‐physical viscous parts. We also use the conditions of the higher moment of the ghost field equilibrium distribution functions to obtain the equilibrium distribution functions. In the numerical examples, we compare the numerical results of this scheme with those obtained by other lattice Boltzmann models for the compressible Euler equations. Copyright © 2008 John Wiley & Sons, Ltd.     

Synthesis and Characterization of a Novel Two‐Dimensional Network Polymer Containing 18‐ and 26‐Membered Organotin Macrocycles

The reaction of 4‐mercaptophenylacetic acid with dimethyltin dichloride in the presence of sodium ethoxide in ethanol affords a novel two‐dimensional organotin network structure compound 1, which is an unusual network containing dinuclear 18‐membered and tetranuclear 26‐membered organotin macrocycles. The compound has been characterized by elemental analysis, IR, and ¹H, ¹³C, and ¹¹⁹Sn NMR spectroscopy. Furthermore, we have also characterized the compound by X‐ray crystallography.     

EAST外杜瓦协同仿真技术的研究

为验证EAST(Experimental and Advanced Superconducting Tokamak)外杜瓦工程设计的可靠性,借助三维设计软件CATIA和有限元分析软件ANSYS,基于协同仿真技术对其进行了研究,结果与EAST运行过程中外杜瓦的实验数据较好的吻合,进行的研究为同类装置外杜瓦的研发提供了有益的参考。     

迫流冷却二极NbTi超导磁体的研究

首先介绍了导体的测试结果;其次,为评估迫流冷却的二极NbTi超导磁体正常工况下对液氦产生的低温热负荷,基于surf152表面效应单元对线圈盒进行了辐射传热分析;此外,为减小通过线圈盒支撑的传导热负荷并且提高其机械强度,依据线圈盒支撑杆的设计尺寸,提出使用玻璃纤维经过三维编织的各向异性复合材料-G10制作线圈盒支撑杆,从...