全文获取类型
收费全文 | 116篇 |
免费 | 19篇 |
国内免费 | 19篇 |
专业分类
化学 | 99篇 |
晶体学 | 1篇 |
力学 | 3篇 |
综合类 | 3篇 |
数学 | 13篇 |
物理学 | 35篇 |
出版年
2023年 | 7篇 |
2022年 | 9篇 |
2021年 | 7篇 |
2020年 | 7篇 |
2019年 | 10篇 |
2018年 | 6篇 |
2017年 | 11篇 |
2016年 | 8篇 |
2015年 | 5篇 |
2014年 | 8篇 |
2013年 | 10篇 |
2012年 | 12篇 |
2011年 | 16篇 |
2010年 | 9篇 |
2009年 | 7篇 |
2008年 | 2篇 |
2007年 | 4篇 |
2006年 | 1篇 |
2005年 | 4篇 |
2003年 | 2篇 |
2002年 | 3篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1993年 | 1篇 |
1989年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
排序方式: 共有154条查询结果,搜索用时 15 毫秒
1.
2.
Yuhong Chen Qishuai Jiao Liang Wang Yawei Hu Na Sun Yushuang Shen Yuhua Wang 《Comptes Rendus Chimie》2013,16(9):845-849
In order to improve the thermal stability and dynamic performance of LiCo1/3Ni1/3Mn1/3O2 materials, Cl-doped and Br-doped materials were synthesized via the co-precipitation method. The morphology, structure, electrochemical performance and thermal stability were characterized by environment scanning electron microscopy (ESEM), X-ray diffraction (XRD), electrochemical impedance spectroscopy (EIS), charge–discharge cycling and differential scanning calorimetry (DSC). Results show that all materials had a stable layered structure with α-NaFeO2 and that Cl-doping slightly increased the size of grains. Both Cl-doping and Br-doping improved the high rate of discharge capacity, cycle-life performance and thermal stability, but Cl-doping was better than Br-doping in improving the material structure stability, dynamic performance and thermal stability. 相似文献
3.
A sensitively electrochemical aptasensor was developed to detect zearalenone, utilizing DNA assembly based on hybridization chain reaction to amplify the signal current and exonuclease III to reduce the background current. The linear range 5.0×10−5 ng/mL-50 ng/mL, and the limit of detection is 0.013 pg/mL. The fabricated aptasensor showed the high specificity toward aflatoxin B1 (AFB1), fumonisin B1 (FB1) and ochratoxin A (OTA), good repeatability and reproducibility. In addition, the average recoveries of spiked corn and beer samples were in the range of 89 % to 102 %. The established method is of great significance in the field of food safety detection. 相似文献
4.
Yulin Jie Xiaojing Liu Zhanwu Lei Shiyang Wang Yawei Chen Fanyang Huang Ruiguo Cao Genqiang Zhang Shuhong Jiao 《Angewandte Chemie (International ed. in English)》2020,59(9):3505-3510
Lithium metal is an ideal electrode material for future rechargeable lithium metal batteries. However, the widespread deployment of metallic lithium anode is significantly hindered by its dendritic growth and low Coulombic efficiency, especially in ester solvents. Herein, by rationally manipulating the electrolyte solvation structure with a high donor number solvent, enhancement of the solubility of lithium nitrate in an ester‐based electrolyte is successfully demonstrated, which enables high‐voltage lithium metal batteries. Remarkably, the electrolyte with a high concentration of LiNO3 additive presents an excellent Coulombic efficiency up to 98.8 % during stable galvanostatic lithium plating/stripping cycles. A full‐cell lithium metal battery with a lithium nickel manganese cobalt oxide cathode exhibits a stable cycling performance showing limited capacity decay. This approach provides an effective electrolyte manipulation strategy to develop high‐voltage lithium metal batteries. 相似文献
5.
电子垃圾拆解所引起的环境问题已经受到广泛关注,根据联合国环境规划署统计,全球约70%的电子垃圾通过各种途径进入我国,而我国自身也产生大量的电子垃圾。我国电子垃圾拆解活动采用的工艺较为原始,位于广东的贵屿和浙江的台州是我国最大的两个电子垃圾拆解地,拆解过程中电子垃圾本身含有和不当处置所产生的大量持久性有毒化学污染物(如重金属、二 NFDA1 英类、溴代阻燃剂等)释放到环境中,对拆解地生态系统及居民健康造成严重的威胁。本文重点针对我国电子垃圾拆解所造成的持久性有毒污染物(PTS)污染现状、管理措施和法规、拆解区居民所面临的持久性有毒污染物暴露健康风险及其相关研究最新进展进行了分析和概括,并对电子垃圾拆解区域持久性有毒污染物及新型环境污染物研究和发展方向作了展望。 相似文献
6.
在传递路径分析理论研究中,经典传递路径分析要求在传递函数测量时拆卸激励源,为了减少工作量,设计一套面向传递路径分析方法研究的实验系统。以简化发动机模型作为激励源,真实汽车发动机悬置作为传递路径,简化车身内的响应为目标响应,建立一套完整的传递路径分析模型。在保留主要激励特征情况下简化发动机机体结构,将NI Compact RIO作为控制核心,激振器作为激励施加装置,以缸压信号和机体振动信号为激励信号对机体加载,实现发动机激励特征的模拟。最终验证该实验系统可模拟出发动机的结构噪声,采集信号中阶次成分明显,主要噪声频段基本吻合,可从阶次信号中提取对应转速信息。整个实验系统结构简单,可作为载体用于传递路径分析方法的研究。 相似文献
7.
8.
9.
The aim of this paper is to show some rigidity results for complete Riemannian manifolds with parallel Cotton tensor. In particular, we prove that any compact manifold of dimension \(n\ge 3\) with parallel Cotton tensor and positive constant scalar curvature is isometric to a finite quotient of \({\mathbb {S}}^n\) under a pointwise or integral pinching condition. Moreover, a rigidity theorem for stochastically complete manifolds with parallel Cotton tensor is also given. The proofs rely mainly on curvature elliptic estimates and the weak maximum principle. 相似文献
10.
In high-energy (keV) CID experiments, oxygen has the unique ability to enhance specific ion fragmentation pathways that lie
within a relatively narrow band of activation energy. It has been previously proposed that this oxygen-enhanced dissociation
phenomenon is due to the participation of the O2 B 3Su + - X 3Sg - {{\hbox{O}}_{{2}}}\;{\hbox{B}}{\,^{{3}}}{\Sigma_{\rm{u}}}^{ + } - {\hbox{X}}{\,^{{3}}}{\Sigma_{\rm{g}}}^{ - } (Schumann–Runge) system in the collision complex. During the collision, oxygen is first excited to its B 3Su + {\hbox{B}}{\,^{{3}}}{\Sigma_{\rm{u}}}^{ + } state before it returns this energy to the projectile ion. This energy drives the nonstatistical dissociation of the projectile
provided there is an energetically accessible pathway in resonance with the absorbed radiation. To probe the validity of this
hypothesis, a modified VG-ZAB mass spectrometer was used to observe the photon emissions from keV collisions of a selection
of projectile ions with O2 target gas. By studying the resulting collision-induced emission (CIE) spectra, a second potential mechanism came to light,
one that involves the near-isoenergetic O2
+. A 2Πu→X 2 Πg state transition. 相似文献