全文获取类型
收费全文 | 1215篇 |
免费 | 34篇 |
国内免费 | 6篇 |
专业分类
化学 | 947篇 |
晶体学 | 7篇 |
力学 | 15篇 |
数学 | 110篇 |
物理学 | 176篇 |
出版年
2023年 | 3篇 |
2022年 | 11篇 |
2021年 | 16篇 |
2020年 | 19篇 |
2019年 | 18篇 |
2018年 | 13篇 |
2017年 | 6篇 |
2016年 | 28篇 |
2015年 | 19篇 |
2014年 | 31篇 |
2013年 | 54篇 |
2012年 | 42篇 |
2011年 | 77篇 |
2010年 | 43篇 |
2009年 | 36篇 |
2008年 | 77篇 |
2007年 | 95篇 |
2006年 | 75篇 |
2005年 | 102篇 |
2004年 | 78篇 |
2003年 | 59篇 |
2002年 | 59篇 |
2001年 | 27篇 |
2000年 | 31篇 |
1999年 | 18篇 |
1998年 | 7篇 |
1997年 | 18篇 |
1996年 | 14篇 |
1995年 | 9篇 |
1994年 | 15篇 |
1993年 | 12篇 |
1992年 | 12篇 |
1991年 | 15篇 |
1990年 | 10篇 |
1989年 | 4篇 |
1988年 | 7篇 |
1986年 | 4篇 |
1985年 | 15篇 |
1984年 | 11篇 |
1983年 | 3篇 |
1982年 | 11篇 |
1981年 | 5篇 |
1980年 | 9篇 |
1979年 | 7篇 |
1978年 | 6篇 |
1977年 | 4篇 |
1976年 | 8篇 |
1975年 | 2篇 |
1973年 | 2篇 |
1971年 | 2篇 |
排序方式: 共有1255条查询结果,搜索用时 15 毫秒
1.
The effect of Re addition on the microstructure and hardening behaviour of the dual two-phase Ni3Al (L12) and Ni3V (D022) intermetallic alloy was investigated by scanning electron microscopy, transmission electron microscopy and Vickers hardness test. The two-phase eutectoid microstructure accompanying the Re-rich precipitates were observed in the channel region of the alloys in which Re substituted for Ni but not in those in which Re substituted for Al and V. The concomitant addition of Nb (or Ta) with Re more stabilized the two-phase eutectoid microstructure and consequently more induced the fine precipitates in the channel region. The annealing at temperatures below the eutectoid temperature was necessary to induce the fine precipitates in the channel region and thereby result in the precipitation hardening. The fine precipitation in the channel region and related hardening was attributed to the alloying feature so that Re is soluble in the A1 (fcc) phase at high temperatures and becomes less soluble in the two intermetallic phases decomposed from the A1 phase at low temperatures. 相似文献
2.
Dr. Nozomi Mihara Dr. Yasuyuki Yamada Dr. Hikaru Takaya Prof. Yasutaka Kitagawa Dr. Kazunobu Igawa Prof. Katsuhiko Tomooka Prof. Hiroshi Fujii Prof. Kentaro Tanaka 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(13):3369-3375
Development of supramolecular methods to further activate a highly reactive intermediate is a fascinating strategy to create novel potent catalysts for activation of inert chemicals. Herein, a supramolecular approach to enhance the oxidizing ability of a high-valent oxo species of a nitrido-bridged iron porphyrinoid dimer that is a known potent molecular catalyst for light alkane oxidation is reported. For this purpose, a nitrido-bridged dinuclear iron complex of porphyrin-phthalocyanine heterodimer 3 5+, which is connected through a fourfold rotaxane, was prepared. Heterodimer 3 5+ catalyzed ethane oxidation in the presence of H2O2 at a relatively low temperature. The site-selective complexation of 3 5+ with an additional anionic porphyrin (TPPS4−) through π–π stacking and electrostatic interactions afforded a stable 1:1 complex. It was demonstrated that the supramolecular post-synthetic modification of 3 5+ enhances its catalytic activity efficiently. Moreover, supramolecular conjugates achieved higher catalytic ethane oxidation activity than nitrido-bridged iron phthalocyanine dimer, which is the most potent iron-oxo-based molecular catalyst for light-alkane oxidation reported so far. Electrochemical measurements proved that the electronic perturbation from TPPS4− to 3 5+ enhanced the catalytic activity. 相似文献
3.
In this paper, we will propose algorithms for calculating a minimal ellipsoid circumscribing a polytope defined by a system
of linear inequalities. If we know all vertices of the polytope and its cardinality is not very large, we can solve the problem
in an efficient manner by a number of existent algorithms. However, when the polytope is defined by linear inequalities, these
algorithms may not work since the cardinality of vertices may be huge. Based on a fact that vertices determining an ellipsoid
are only a fraction of these vertices, we propose algorithms which iteratively calculate an ellipsoid which covers a subset
of vertices. Numerical experiment shows that these algorithms perform well for polytopes of dimension up to seven. 相似文献
4.
Yasuyuki Kawahigashi 《Communications in Mathematical Physics》2002,226(2):269-287
We study the recent construction of subfactors by Rehren which generalizes the Longo–Rehren subfactors. We prove that if
we apply this construction to a non-degenerately braided subfactor N⊂M and α±-induction, then the resulting subfactor is dual to the Longo–Rehren subfactor M⊗M
opp⊂R arising from the entire system of irreducible endomorphisms of M resulting from αplusmn;-induction. As a corollary, we solve a problem on existence of braiding raised by Rehren negatively. Furthermore, we generalize
our previous study with Longo and Müger on multi-interval subfactors arising from a completely rational conformal net of factors
on S
1 to a net of subfactors and show that the (generalized) Longo–Rehren subfactors and α-induction naturally appear in this context.
Received: 11 September 2001 / Accepted: 7 October 2001 相似文献
5.
Yasuyuki Agari Kiyofumi Sakai Yosikazu Kano Ryoki Nomura 《Journal of Polymer Science.Polymer Physics》2007,45(21):2972-2981
We prepared biodegradable poly(ethylene oxide) (PEO)/poly(L ‐lactic acid) (PLLA) graded blends by the dissolution–diffusion process, and discussed the biodegradability and tensile strength of the graded blends by comparing isotropic blend and PLLA only. All the graded blends were degraded more largely than the PLLA only and isotropic blend (PEO: 37.5 wt %), which had the same content as the total content of those graded blends. The graded blend having most excellent wide compositional gradient was degraded most largely with the enzyme. Thus, graded structure of the blends promoted their biodegradabilities large. It was considered that the dissolution of PEO with water increased the surface area attacked by the enzyme, while PEO caught PLLA oligomers to promote the biodegradation of PLLA. Then, the biodegradabilities of the graded blends were suppressed by the increasing crystallinity of PLLA. Furthermore, the strengths of all the graded blends were larger than those of the isotropic blend. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2972–2981, 2007 相似文献
6.
7.
Upper bounds for survival probability of the contact process 总被引:3,自引:0,他引:3
8.
Standard solutions (at 10(-5) M levels) of Cu(I)- and Fe(II)-cyanide complexes were stabilized for at least 5 h using 0.5 mM cyanide solution (around pH 9) as a medium. Complexes of Cu(I)- and Fe(III)-cyanide also could be stabilized without any dissociation by adding 1 mM cyanide to an acetonitrile-water (18:82, v/v) mobile phase (pH 7.0) containing 10 mM tetra-n-propylammonium salt (TPA). Under the optimal conditions, the six complexes of Cu(I)-, Ag(I)-, Ni(II)-, Fe(II)-, Fe(III)- and Au(I)-cyanides were resolved from their mixtures within about 45 min, with well-shaped chromatographic peaks. 相似文献
9.
This paper proposes a two step algorithm for solving a large scale semi-definite logit model, which is appreciated as a powerful
model in failure discriminant analysis. This problem has been successfully solved by a cutting plane (outer approximation)
algorithm. However, it requires much more computation time than the corresponding linear logit model. A two step algorithm
to be proposed in this paper is intended to reduce the amount of computation time by eliminating a certain portion of the
data based on the information obtained by solving an associated linear logit model. It will be shown that this algorithm can
generate a solution with almost the same quality as the solution obtained by solving the original large scale semi-definite
model within a fraction of computation time. 相似文献
10.